1. A system, comprising:
a rolling bearing element assembly configured to enable rotation of a rotary element relative to a stationary element, the rotation being about a bearing system axis of the rolling bearing element assembly;
wherein the rolling bearing element assembly comprises an inner race, an outer race, a plurality of rolling bearing elements disposed between the inner and outer races, and a bearing cage configured to hold the rolling bearing elements such that the rolling bearing elements are circumferentially spaced about the bearing system axis;
wherein the rolling bearing element assembly is configured to facilitate oscillatory motion of the rotary element relative to the stationary element such that, when the rotary element rotates in a first direction about the bearing system axis, the rolling bearing elements revolve about the bearing system axis in the first direction, and when the rotary element rotates in a second direction opposite the first direction about the bearing system axis, revolution of the rolling bearing elements about the bearing system axis in the second direction is resisted or prevented.
2. The system of claim 1, wherein the rotary element is coupled to the inner race, and wherein the stationary element is coupled to the outer race.
3. The system of claim 1, wherein the rotary element is coupled to the outer race, and wherein the stationary element is coupled to the inner race.
4. The system of claim 1, wherein the rolling bearing element assembly comprises a spring-loaded indexing element configured to engage with a contact surface to allow revolution of the rolling bearing elements about the bearing system axis when the rotary element is rotating in the first direction and to resist revolution of the rolling bearing elements about the bearing system axis in the second direction when the rotary element is rotating in the second direction.
5. The system of claim 4, wherein the indexing element is coupled to the rolling bearing elements via the bearing cage, and wherein the contact surface is disposed on the inner race.
6. The system of claim 4, wherein the indexing element is coupled to the rolling bearing elements via the bearing cage, and wherein the contact surface is disposed on the outer race.
7. The system of claim 4, wherein the indexing element is coupled to a seal disposed between the inner and outer races, and wherein the contact surface comprises a surface of a bearing cage coupled to the plurality of rolling bearing elements.
8. The system of claim 4, wherein the indexing element and the contact surface are configured such that a frictional force between the indexing element and the contact surface holds the indexing element and the contact surface in engagement.
9. The system of claim 4, wherein the contact surface comprises ratchet teeth.
10. The system of claim 4, wherein the indexing element comprises a leading edge rotatably coupled to a component of the rolling bearing element assembly and a trailing edge configured to engage the contact surface.
11. The system of claim 4, wherein the indexing element is configured to slide relative to the contact surface when the rotary element is rotating in the second direction.
12. The system of claim 1, wherein the rolling bearing element assembly comprises a sealed rolling bearing element assembly.
13. A bearing system, comprising:
an outer race disposed in alignment with a bearing system axis;
an inner race concentric with the outer race and having an outer diameter less than an inner diameter of the outer race, wherein the inner race is configured to rotate relative to the outer race about the bearing system axis;
a rotary element coupled to one of the inner race or the outer race;
a plurality of rolling bearing elements disposed between and in rolling contact with the inner race and the outer race;
a bearing cage coupled to the plurality of rolling bearing elements, wherein the bearing cage is configured to keep the plurality of rolling bearing elements circumferentially spaced about the bearing system axis;
a spring loaded indexing element with a first end rotatably coupled to the bearing cage and a second end in contact with a contact surface of the inner race or the outer race;
wherein the indexing element is configured to engage the contact surface via the second end to enable rotation of the bearing cage in a first direction about the bearing system axis when the rotary element is rotating in the first direction, and wherein the indexing element is configured to slide relative to the contact surface to prevent or resist rotation of the bearing cage in a second direction about the bearing system axis when the rotary element is rotating in the second direction opposite the first direction.
14. The bearing system of claim 13, wherein a frictional force between the second end of the indexing element and the contact surface allows rotation of the bearing cage and the plurality of rolling bearing elements in the first direction when the rotary element is rotating in the first direction.
15. The bearing system of claim 13, wherein the contact surface comprises ratchet teeth, and wherein the indexing element is spring-loaded to interlock with the teeth when the rotary element is rotating in the first direction.
16. The bearing system of claim 13, comprising a plurality of spring-loaded indexing elements each coupled to the bearing cage and disposed circumferentially about the bearing system axis.
17. The bearing system of claim 13, wherein the indexing element comprises an asymmetric shape wherein the first end comprises a rounded leading edge and the second end comprises a trailing edge configured to engage the inner race.
18. The bearing system of claim 13, wherein the rotary element is coupled to the inner race and wherein the inner race comprises the contact surface.
19. The bearing system of claim 13, wherein the rotary element is coupled to the outer race and wherein the outer race comprises the contact surface.
20. A method, comprising:
facilitating oscillatory rotation of a rotary element about a bearing system axis and relative to a stationary element via a rolling bearing element assembly, wherein the rolling bearing element assembly comprises an inner race coupled to the rotary element, an outer race coupled to the stationary element, and a plurality of rolling bearing elements disposed between the inner and outer races;
allowing the rolling bearing elements to revolve about the bearing system axis in a first direction when the rotary element rotates in the first direction about the bearing system axis; and
preventing or resisting revolution of the rolling bearing elements about the bearing system axis in a second direction when the rotary element rotates in the second direction about the bearing system axis.
21. The method of claim 20, wherein allowing the rolling bearing elements to revolve about the bearing system axis in the first direction comprises engaging a spring-loaded indexing element coupled to the rolling bearing elements with a contact surface of the inner race when the rotary element rotates in the first direction, and wherein preventing or resisting the rolling bearing elements from revolving in the second direction comprises sliding the contact surface of the inner race relative to the indexing element when the rotary element rotates in the second direction.
22. The method of claim 20, wherein allowing the rolling bearing elements to revolve about the bearing system axis in the first direction comprises engaging a spring-loaded indexing element coupled to the rolling bearing elements with a contact surface of the outer race when the rotary element rotates in the first direction, and wherein preventing or resisting the rolling bearing elements from revolving in the second direction comprises sliding the contact surface of the outer race relative to the indexing element when the rotary element rotates in the second direction.
23. The method of claim 20, comprising engaging the rolling bearing elements with the inner race when the rotary element rotates in the first direction, and allowing the rolling bearing elements to slide relative to the inner race when the rotary element rotates in the second direction.
The claims below are in addition to those above.
All refrences to claims which appear below refer to the numbering after this setence.
What is claimed is:
1. A pearl luster pigment comprising:
a platelet-shaped substrate coated with at least metal oxide, and a top layer located on the metal oxide layer, wherein the top layer comprises:
a first layer, comprising a hydroxide or an oxide hydrate of aluminum or silicon;
a second layer, comprising at least one hydroxide or oxide hydrate of aluminum, silicon, cerium or zirconium, with the exception of the hydroxide or oxide hydrate of the first layer; and
a third layer, comprising at least one organic hydrophobic coupling agent.
2. A pearl luster pigment according to claim 1, wherein the coupling reagent is a silane and has at least one functional group of a straight-chain or a branched alkyl group having 3 to 18 carbon atoms, unsubstituted or substituted by fluorine, and an aryl group, unsubstituted or substituted by fluorine, and an aryl group, unsubstituted or substituted by C1-C10 alkyl group andor a nitro group.
3. A process for preparing a pearl luster pigment according to claim 1, comprising:
suspending the substrate coated with a metal oxide in water, heated at 30-100 C.,
adjusting the suspension to a pH of 3-9,
adding at least water-soluble metal salt,
depositing these salts in whole or in part as a metal hydroxide andor a metal oxide hydrate by adding at least one water-soluble silicate, aluminum salt, cerium salt andor zirconium salt at a pH of 3-9,
depositing corresponding hydroxide or oxide hydrate thereof; and
adding at least one organic hydrophobic coupling agent that binds to the deposited oxide hydrate layer at a pH of 3-9.
4. A process according to claim 3, further comprising separating by sedimentation, washing, filtering, drying at 80-160 C. the pigment after adding at least one organic hydrophobic coupling agent.
5. A process according to claim 3, wherein the metal hydroxide andor metal oxide hydrate is a hydroxide andor oxide hydrate of aluminum or silicon.
6. A process according to claim 3, wherein the coupling reagent is a silane and has at least one functional group of a straight-chain or a branched alkyl group having 3 to 18 carbon atoms, unsubstituted or substituted by fluorine, and an aryl group, unsubstituted or substituted by C1-C10 alkyl group andor a nitro group.
7. A method of pigmenting a paint, an ink, a plastic, a coating or a cosmetic by incorporating a pearl luster pigment according to claim 1 therein.
8. A paint, an ink, a plastic, a coating or a cosmetic pigmented with a pearl luster pigment according to claim 1.
9. A process according to claim 3, wherein suspending the substrate coated with a metal oxide in water is heated at 40-75 C. and adjusted to a pH of 6-7.
10. A process according to claim 3, wherein depositing these salts is at a pH of 6-7.
11. A process according to claim 3, wherein the adding of at least one organic hydrophobic coupling agent is at a pH of 6-8.
12. A process according to claim 4, wherein the drying is at 120-160 C.
13. A process for preparing a pearl luster pigment comprising adding a coupling reagent that binds to a metal hydroxide andor metal oxide hydrate layer and forms a layer thereon.