1. An imaging layer comprising:
a matrix;
a radiation absorbing compound dissolved in the matrix;
at least two activators substantially dissolved in the matrix, wherein a primary activator has a higher acidity than a secondary activator, and wherein the primary activator has a lower solubility in the matrix than the secondary activator; and
a color former that is substantially insoluble in the matrix at ambient conditions and is substantially uniformly distributed in the matrix.
2. The imaging layer of claim 1, wherein the primary activator is from about 0.1 wt % to 15 wt % of the two-phase layer, and wherein the secondary activator is from about 0.1 wt % to about 25 wt % of the two-phase layer.
3. The imaging layer of claim 2, wherein the primary activator is selected from compounds having a pKa of less than 8, and wherein the secondary activator is selected from compounds having a pKa greater than the primary activator.
4. The imaging layer of claim 1, wherein the primary activator is selected from compounds having a pKa of less than 8, and wherein the secondary activator is selected from compounds having a pKa greater than the primary activator.
5. The imaging layer of claim 1, wherein a primary activator is a highly acidic phenol compound and a secondary activator is a low acidic phenol compound.
6. The imaging layer of claim 1, wherein the primary activator is selected from 4-hydroxyphenyl sulfone, 2,4\u2032-dihydroxydiphenyl sulfone, Bis(4-hydroxy-3-allylphenyl) sulfone and 2,2\u2032,5,5\u2032-tetrahydroxy diphenyl sulfone and wherein the secondary activator is selected from 4-hydroxyphenyl-4\u2032-isopropoxyphenyl sulfone and 2,2-Bis(4-hydroxyphenyl)propane.
7. The imaging layer of claim 6, wherein the primary activator is from about 0.1 wt % to 15 wt % of the two-phase layer, arid wherein the secondary activator is from about 0.1 wt % to about 25 wt % of the two-phase layer.
8. The imaging layer of claim 1 wherein the color former comprises at least one compound is selected from a leuco dye and a phthalide dye.
9. The imaging layer of claim 1 wherein the matrix is selected from an ultraviolet curable monomers, ultraviolet oligomers, pre-polymers of ultraviolet polymers, and combinations thereof.
10. The imaging layer of claim 1 wherein the a radiation absorbing compound comprises at least one of the compounds chosen from the group consisting of quinone, phthalocyanine, naphthalocyanine, metal complexes, azo, croconium, squarilium dyes, hexafunctional polyester oligomers, and the compounds represented by the following formulae:
11. An image recording medium comprising:
a substrate having a two-phase layer disposed thereon, wherein the two-phase layer includes:
a matrix,
a radiation absorbing compound dissolved in the matrix,
at least two activators substantially dissolved in the matrix, wherein a primary activator is a highly acidic phenol compound and a secondary activator is a low acidic phenol compound, and
a color former that is substantially insoluble in the matrix at ambient conditions and is substantially uniformly distributed in the matrix.
12. The image recording medium of claim 11, wherein the substrate is selected from a paper medium, a transparency, a compact disk (CD), and a digital video disk (DVD).
13. The image recording medium of claim 11, wherein the substrate is selected from a CD-RRWROM and DVD-RRWROM.
14. The image recording medium of claim 11, wherein the primary activator has at least one of a characteristic selected from a higher acidity than the second activator and more acidic groups per molecule than the secondary activator.
15. The image recording medium of claim 11, wherein the primary activator has a lower solubility in the matrix than the secondary activator, wherein the primary activator has a pKa of less than 8, and wherein the secondary activator has a pKa greater than the primary activator.
16. The image recording medium of claim 11, wherein the primary activator is selected from 4-hydroxyphenyl sulfone, 2,4\u2032-dihydroxydiphenyl sulfone, Bis(4-hydroxy-3-allylphenyl) sulfone and 2,2\u2032,5,5\u2032-tetrahydroxy diphenyl sulfone and wherein the secondary activator is selected from 4-hydroxyphenyl-4\u2032-isopropoxyphenyl sulfone and 2,2-Bis(4-hydroxyphenyl)propane.
17. The image recording medium of claim 11, wherein the primary activator is from about 0.1 wt % to 15 wt % of the two-phase layer, and wherein the secondary activator is from about 0.1 wt % to about 25 wt % of the two-phase layer.
18. A method for preparing an imaging material, the method comprising:
providing a matrix, a radiation absorbing compound, a color former, and at least one activator, wherein the activator includes a primary activator and a secondary activator, wherein the primary activator has a lower solubility in the matrix than the secondary activator;
dissolving the radiation absorbing compound, the primary activator, and the secondary activator, substantially in the matrix; and
distributing the color former substantially uniformly in the matrix, wherein the color former is substantially insoluble in the matrix at ambient conditions.
19. The method of claim 18, further comprising:
disposing the direct imaging material onto a substrate, wherein the substrate is selected from a paper media, a transparency, a compact disk (CD), and a digital video disk (DVD).
20. The method of claim 18, wherein the primary activator is from about 0.1 wt % to 15 wt % of the two-phase layer, and wherein the secondary activator is from about 0.1 wt % to about 25 wt % of the two-phase layer.
21. The method of claim 17, wherein the primary activator is selected from 4-hydroxyphenyl sulfone, 2,4\u2032-dihydroxydiphenyl sulfone, and Bis(4-hydroxy-3-allylphenyl) sulfone and 2,2\u20325,5\u2032-tetrahydroxy diphenyl sulfone and wherein the secondary activator is selected from 4-hydroxyphenyl-4\u2032-isopropoxyphenyl sulfone and 2,2-Bis(4-hydroxyphenyl)propane.
22. An image recording medium made by the method of claim 18.
23. An imaging means, the means comprising:
means for absorbing energy;
means for forming color;
at least one activator, wherein the activator includes a primary activator that is a highly acidic phenol compound and a secondary activator that is a low acidic phenol compound; and
means for binding the means for absorbing energy and the primary and secondary activators, wherein the means for absorbing energy and the primary and secondary activators are substantially dissolved in the means for binding, wherein the means for forming color is substantially insoluble in the means for binding at ambient conditions, and wherein the means for forming color is substantially uniformly distributed in the means for binding.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
1. An integrated circuit die to communicate data over a plurality of communication channels, the integrated circuit die comprising:
a. a current source having a plurality of calibration-current output nodes providing a corresponding plurality of calibration currents;
b. a plurality of pads to connect to the communication channels; and
c. a plurality of communication circuits to communicate the data over the communication channels via the pads, each communication circuit including:
i. a first calibration-circuit input node coupled to a respective one of the calibration-current output nodes and receiving one of the calibration currents;
ii. a second calibration-circuit input node coupled to a reference resistor;
iii. a calibration-circuit output port providing a termination-control signal; and
iv. a termination element exhibiting a termination characteristic and including a termination control port coupled to the calibration-circuit output port and receiving the termination-control signal.
2. The integrated circuit die of claim 1, wherein the termination characteristic comprises termination resfstance.
3. The integrated circuit die of claim 1, further comprising a control system deriving a reference current from a reference voltage and a reference resistance, wherein the current source derives the calibration currents from the reference current.
4. The integrated circuit die of claim 1, further comprising a plurality of differential signal-line pairs that extend between the communication circuits and the pads, each signal-line pair including a first signal line coupled to the termination element.
5. The integrated circuit die of claim 1, wherein each communication channel comprises a signal-line pair.
6. The integrated circuit die of claim 1, wherein each of the communication circuits comprises a multi-channel transmitter.
7. The integrated circuit die of claim 1, wherein each of the communication circuits comprises a multi-channel receiver.
8. An integrated circuit comprising:
a. a current source having a plurality of calibration-current output nodes to provide a corresponding plurality of calibration currents;
b. a plurality of reference pads to couple to external reference impedances;
c. a plurality of calibration circuits, each calibration circuit coupled to one of the calibration-current output nodes, to receive the corresponding one of the calibration currents, and one of the external reference impedances, wherein each calibration circuit is adapted to derive a termination control signal from the one of the calibration currents and the one external reference impedance; and
d. a plurality of termination elements, each termination element including a termination control port coupled to one of the calibration circuits to receive the respective termination control signal.
9. The integrated circuit of claim 8, wherein the current source includes a reference node to connect to an external reference voltage.
10. The integrated circuit of claim 8, wherein the current source includes a reference node to connect to a second external reference impedance.
11. An integrated circuit comprising:
a. a plurality of communication circuits, each communication circuit including a termination-calibration circuit;
b. a plurality of pads to connect each of the tennination-calibration circuits to respective external reference resistors; and
c. a current source having a plurality of calibration-current output nodes, each output node coupled to a respective one of the termination-calibration circuits.
12. The integrated circuit of claim 11, further comprising an additional pad to connect to an additional external resistor to the current source, wherein each of the calibration-current output nodes provides a calibration current proportional to a resistance of the additional external resistor.
13. The integrated circuit of claim 12, wherein each of the calibration current is proportional to an external reference voltage.
14. The integrated circuit of claim 11, wherein each communication circuit is a transmitter.
15. The integrated circuit of claim 11, wherein each communication circuit is a multi-channel communication circuit having multiple termination elements coupled to the termination-calibration circuit.
16. A method of calibrating a plurality of termination elements on an integrated-circuit die, the method comprising:
a. providing a first calibration current to each of a plurality of communication circuits; and
b. for each of the plurality of communication circuits:
i. producing a second calibration current proportional to the first calibration current;
ii. producing a third calibration current proportional to the first calibration current;
iii. drawing the second calibration current through a reference resistor external to the die to develop a first reference voltage;
iv. drawing the third calibration current through an adjustable reference on-die-termination (ODT) resistor on the die to develop an ODT voltage;
v. comparing the first reference voltage to the ODT voltage; and
vi. adjusting at least one of the plurality of termination elements in response to the comparing.
17. The method of claim 16, further comprising connecting an external voltage reference to the die, connecting an external reference resistor to the die, and deriving the first calibration currents using the voltage reference and the external reference resistor.
18. The method of claim 16, further comprising adjusting the adjustable reference ODT resistor in response to the comparing.
19. The method of claim 18, wherein adjusting the reference ODT resistor comprises conveying a termination control signal to the reference ODT resistor and termination elements.
20. A signal communication system comprising:
a. a plurality of communication circuits to communicate data over a plurality of communication channels, each communication circuit receiving a supply voltage and including at least one termination element, exhibiting a termination characteristic, and a local reference element; and
b. a termination calibration system including:
i. means for distributing each of a plurality of calibration currents to respective ones of the communication circuits, wherein each of the calibration currents is independent of temperature and the supply voltage; and
ii. means for calibrating the termination characteristic of the at least one termination element in each of the plurality of communication circuits using the respective calibration current to maintain the termination characteristic independent of the temperature and the supply voltage.
21. The signal communication system of claim 20, wherein the means for calibrating the at least one termination element in each of the plurality of communication circuits includes a current mirror receiving the respective calibration current.
22. The signal communication system of claim 21, wherein the current mirror includes a reference termination resistor, and wherein the current mirror derives from the respective calibration current a third calibration current through the reference termination resistor.