1. A heterocyclic compound represented by formula (1):
wherein:
each of A1 to A3 independently represents a saturated or unsaturated ring and each of A1 to A3 may independently have a substituent;
each of X1 to X3 independently represents a linking group represented by any of formulae (2) to (5), provided that one or two of X1 to X3 are represented by formula (2) and the rest is represented by any of formulae (3) to (5):
wherein each of Y1 to Y3 independently represents a hydrogen atom or a substituent; Y2 and Y3 may be bonded to each other to form a ring structure; each of Y1 to Y3 may be bonded to the substituent of each of A1 to A3 to form a ring structure; and when X2 is represented by formula (2) or (3) and X3 is represented by (2) or (3), Y1 to Y3 in X2 and X3 may be bonded to each other to form a ring structure.
2. The heterocyclic compound according to claim 1, wherein each of A1 to A3 independently represents a substituted or unsubstituted 5-, 6- or 7-membered ring.
3. The heterocyclic compound according to claim 1,
wherein the heterocyclic compound is represented by formula (6):
wherein:
X1 to X3 are as defined above;
each of Z1 to Z12 independently represents C(R) or a nitrogen atom;
each R independently represents a hydrogen atom or a substituent; and
when two or more of Z1 to Z12 have substituents, the substituents may be bonded to each other to form a ring structure.
4. The heterocyclic compound according to claim 1, wherein the substituent referred to in formulae (1) to (3) is independently selected from a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms; a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms; a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms; a substituted or unsubstituted aralkyl group having 7 to 51 carbon atoms; an amino group; a mono- or disubstituted amino group having a substituent selected from a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms and a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms; a substituted or unsubstituted alkoxy group having 1 to 50 carbon atoms; a substituted or unsubstituted aryloxy group having 6 to 50 ring carbon atoms; a mono-, di-, or trisubstituted silyl group having a substituent selected from a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms and a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms; a substituted or unsubstituted heteroaryl group having 5 to 50 ring atoms; a substituted or unsubstituted haloalkyl group having 1 to 50 carbon atoms; a halogen atom; a cyano group; a nitro group; a sulfonyl group having a substituent selected from a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms and a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms; a disubstituted phosphoryl group having a substituent selected from a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms and a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms; an alkylsulfonyloxy group; an arylsulfonyloxy group; an alkylcarbonyloxy group; an arylcarbonyloxy group; a boron-containing group; a zinc-containing group; a tin-containing group; a silicon-containing group; a magnesium-containing group; a lithium-containing group; a hydroxyl group; an alkyl- or aryl-substituted carbonyl group; a carboxyl group; a vinyl group; a (meth)acryloyl group; an epoxy group; and an oxetanyl group.
5. The heterocyclic compound according to claim 4, wherein R of formula (6) is independently selected from a hydrogen atom; a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms; a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms; a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms; a substituted or unsubstituted aralkyl group having 7 to 51 carbon atoms; an amino group; a mono- or disubstituted amino group having a substituent selected from a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms and a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms; a substituted or unsubstituted alkoxy group having 1 to 50 carbon atoms; a substituted or unsubstituted aryloxy group having 6 to 50 ring carbon atoms; a mono-, di-, or trisubstituted silyl group having a substituent selected from a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms and a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms; a substituted or unsubstituted heteroaryl group having 5 to 50 ring atoms; a substituted or unsubstituted haloalkyl group having 1 to 50 carbon atoms; a halogen atom; a cyano group; a nitro group; a sulfonyl group having a substituent selected from a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms and a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms; a disubstituted phosphoryl group having a substituent selected from a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms and a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms; an alkylsulfonyloxy group; an arylsulfonyloxy group; an alkylcarbonyloxy group; an arylcarbonyloxy group; a boron-containing group; a zinc-containing group; a tin-containing group; a silicon-containing group; a magnesium-containing group; a lithium-containing group; a hydroxyl group; an alkyl- or aryl-substituted carbonyl group; a carboxyl group; a vinyl group; a (meth)acryloyl group; an epoxy group; and an oxetanyl group.
6. The heterocyclic compound according to claim 5, wherein R of formula (6) is independently selected from a hydrogen atom; a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms; a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms; a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms; a substituted or unsubstituted aralkyl group having 7 to 51 carbon atoms; an amino group; a mono- or disubstituted amino group having a substituent selected from a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms and a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms; a substituted or unsubstituted alkoxy group having 1 to 50 carbon atoms; a substituted or unsubstituted aryloxy group having 6 to 50 ring carbon atoms; a mono-, di-, or trisubstituted silyl group having a substituent selected from a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms and a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms; a substituted or unsubstituted heteroaryl group having 5 to 50 ring atoms; a substituted or unsubstituted haloalkyl group having 1 to 50 carbon atoms; a halogen atom; a cyano group; a nitro group; a sulfonyl group having a substituent selected from a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms and a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms; and a disubstituted phosphoryl group having a substituent selected from a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms and a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms.
7. The heterocyclic compound according to claim 6, wherein R of formula (6) is independently selected from a hydrogen atom; a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms; a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms; a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms; a substituted or unsubstituted aralkyl group having 7 to 51 carbon atoms; an amino group; a mono- or disubstituted amino group having a substituent selected from a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms and a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms; a substituted or unsubstituted alkoxy group having 1 to 50 carbon atoms; a substituted or unsubstituted aryloxy group having 6 to 50 ring carbon atoms; a mono-, di-, or trisubstituted silyl group having a substituent selected from a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms and a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms; a substituted or unsubstituted heteroaryl group having 5 to 50 ring atoms; a substituted or unsubstituted haloalkyl group having 1 to 50 carbon atoms; a halogen atom; a cyano group; and a nitro group.
8. The heterocyclic compound according to claim 1, wherein each of Y2 and Y3 of formula (3) is independently selected from a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, and a substituted or unsubstituted heteroaryl group having 5 to 50 ring atoms.
9. The heterocyclic compound according to claim 1, wherein Y1 of formula (2) is selected from a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, a substituted or unsubstituted aryl group having 6 to 50 ring carbon atoms, and a substituted or unsubstituted heteroaryl group having 5 to 50 ring atoms.
10. The heterocyclic compound according to claim 1, wherein one of X1 to X3 is represented by formula (2), and the other two are represented by any of formulae (3) to (5).
11. The heterocyclic compound according to claim 1, wherein two of X1 to X3 are represented by formula (2), and the other one is represented by any of formulae (3) to (5).
12. The heterocyclic compound according to claim 1, wherein at least one of X1 to X3 is represented by formula (4).
13. The heterocyclic compound according to claim 1, wherein at least one of X1 to X3 is represented by formula (5).
14. A material for organic electroluminescence devices which comprises the heterocyclic compound according to claim 1.
15. An organic electroluminescence device which comprises an organic thin film layer between a cathode and an anode, wherein the organic thin film layer comprises one or more layers and comprises a light emitting layer, and at least one layer of the organic thin film layer comprises the heterocyclic compound according to claim 1.
16. The organic electroluminescence device according to claim 15, wherein the light emitting layer comprises the heterocyclic compound.
17. The organic electroluminescence device according to claim 15, wherein the organic electroluminescence device further comprises an anode-side organic thin film layer between the anode and the light emitting layer, and the anode-side organic thin film layer comprises the heterocyclic compound.
18. The organic electroluminescence device according to claim 15, wherein the organic electroluminescence device further comprises a cathode-side organic thin film layer between the cathode and the light emitting layer, and the cathode-side organic thin film layer comprises the heterocyclic compound.
19. The organic electroluminescence device according to claim 15, wherein the light emitting layer comprises a phosphorescent material.
20. The organic electroluminescence device according to claim 15, wherein the light emitting layer comprises a fluorescent material.
21. The organic electroluminescence device according to claim 19, wherein the phosphorescent material is an ortho-metallated complex comprising a metal atom selected from iridium (Ir), osmium (Os) and platinum (Pt).
22. An electronic equipment comprising the organic electroluminescence device according to claim 15.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
1. A focal plane shutter for a camera comprising:
a driving mechanism for a leading blade, having
a first driving member for the leading blade, which drives a leading blade group in a direction of closing an exposure opening, through rotation by a biasing force of a set spring, and
a second driving member for the leading blade, which drives the leading blade group in a direction of opening the exposure opening, through pushing the first driving member against the biasing force of the set spring through rotation through a biasing force of a driving spring for the leading blade; and
a switching mechanism that switches between imaging in a normally open system, in which an image frame is opened during standby after an exposing operation, and imaging in a normally closed system, in which the image frame is closed during standby after the exposing operation, through switching between stopping and releasing of the stopping, by the first driving member, of rotation in the direction of closing the exposure opening by the leading blade, wherein:
the switching mechanism has
an electromagnet to which an electric current is applied in only a single direction, and
a stopping member having
an engaging portion able to lock an engagement portion that is provided in the first driving member for the leading edge, and
an operating portion wherein a direction of a force, in relation to the electromagnet, switches, in accordance with switching between an application and removal of an electric current in the single direction to the electromagnet, so as to move the engaging portion to a position wherein it is able to release locking of the engagement portion when the electric current is applied, and to move the engaging portion to a position wherein it is able to lock the engagement portion when the electric current is removed; and
the rotation of the first driving member for the leading blade in the direction, in which the leading blade closes the exposure opening, is switched between being stopped, and released from the stop, depending on the locking, or the release of the locking, of the engagement portion by the engaging portion after the exposing operation and prior to the standby.
2. The focal plane shutter for a camera as set forth in claim 1 wherein:
the stopping member rotates centered on a shaft, and has
the engaging portion on one end and
a first permanent magnet on another end;
the operating portion is made from the first permanent magnet;
when the electric current in the single direction is applied to the electromagnet, the electromagnet has a repulsive force in relation to the first permanent magnet;
the stopping member rotates in a direction of releasing the locking of the engaging portion to the engagement portion, by the repulsive force of the first permanent magnet in relation to the electromagnet; and
when the electric current to the electromagnet is removed, the stopping member rotates, by an attractive force of the first permanent magnet to the electromagnet, in a direction in which the engaging portion locks to the engagement portion.
3. The focal plane shutter for a camera as set forth in claim 2, wherein:
the electromagnet includes a second permanent magnet having a repulsive force in relation to the first permanent magnet;
when the electric current is applied in the single direction to the electromagnet, the electromagnet produces a magnetic force for canceling the repulsive force of the second permanent magnet in relation to the first permanent magnet, so that the stopping member is rotated, by the attractive force of the first permanent magnet in relation to the electromagnet, in the direction in which the engaging portion releases the locking of the engagement portion; and
when the electric current is removed from the electromagnet, the stopping member is rotated, by the repulsive force of the second permanent magnet in relation to the first permanent magnet, in the direction in which the engaging portion locks the engagement portion.
4. The focal plane shutter for a camera as set forth in claim 1, wherein:
the stopping member rotates around a shaft, and has
the engaging portion on one end thereof,
a ferromagnetic portion on another end, and
a spring that biases the another end in a direction away from the electromagnet;
the operating portion is structured with the ferromagnetic portion and the spring that biases the another end in the direction away from the electromagnet;
when an electric current is applied in the single direction to the electromagnet, the electromagnet has an attractive force in relation to the ferromagnetic portion;
the stopping member is rotated by the attractive force of the ferromagnetic portion in relation to the electromagnet, against a biasing force of the spring that biases in the direction away from the electromagnet, in a direction for releasing the locking of the engaging portion to the engagement portion; and
when the electric current is removed from the electromagnet, the stopping member is rotated, by the force of the spring that biases in the direction away from the electromagnet, in a direction wherein the engaging portion locks the engagement portion.
5. The focal plane shutter for a camera as set forth in claim 1, wherein:
the first driving member for the leading blade has a pushing portion on an outside of the engagement portion;
the stopping member has a pushed portion to the outside of the engaging portion; and,
in a state in which the stopping member is at the position where the engaging portion can lock the engagement portion of the first driving member, and when the first driving member is rotated so that the leading blade group is driven in the direction of opening the exposure opening, the pushing portion of the first driving member pushes back the pushed portion of the stopping member, and the engagement portion of the first driving member is locked by the engaging portion.
6. A digital camera comprising:
a focal plane shutter comprising:
a driving mechanism for a leading blade, having
a first driving member for the leading blade, which drives a leading blade group in a direction of closing an exposure opening, through rotation by a biasing force of a set spring, and
a second driving member for the leading blade, which drives the leading blade group in a direction of opening the exposure opening, through pushing the first driving member against the biasing force of the set spring through rotation through a biasing force of a driving spring for the leading blade; and
a switching mechanism that switches between imaging in a normally open system, in which an image frame is opened during standby after an exposing operation, and imaging in a normally closed system, in which the image frame is closed during standby after the exposing operation, through switching between stopping and releasing of the stopping, by the first driving member, of rotation in the direction of closing the exposure opening by the leading blade, wherein:
the switching mechanism has
an electromagnet to which an electric current is applied in only a single direction, and
a stopping member having
an engaging portion able to lock an engagement portion that is provided in the first driving member for the leading edge, and
an operating portion wherein a direction of a force, in relation to the electromagnet, switches, in accordance with switching between an application and removal of an electric current in the single direction to the electromagnet, so as to move the engaging portion to a position wherein it is able to release locking of the engagement portion when the electric current is applied and to move the engaging portion to a position wherein it is able to lock the engagement portion when the electric current is removed; and
the rotation of the first driving member for the leading blade in the direction, in which the leading blade closes the exposure opening, is switched between being stopped, and released from the stop, depending on the locking, or the release of the locking, of the engagement portion by the engaging portion after the exposing operation and prior to the standby.