1. A method to characterize subterranean formations, comprising:
a) extracting drill cuttings from a used drilling fluid at the Earth’s surface, wherein the drilling fluid transports the drill cuttings to the Earth’s surface after use of the drilling fluid in a drilling of a wellbore in a subterranean reservoir;
b) grouping the drill cuttings into a group of cuttings based on a time of arrival of the drill cuttings at the Earth’s surface;
c) repeating steps a) and b) at least once to provide a plurality of groups of drill cuttings that arrive sequentially at different recorded times at the Earth’s surface;
d) measuring bulk density of at least one of the plurality of groups of drill cuttings of c);
e) performing a multi-energy X-ray CT scan of the at least one group of drill cuttings of d) to generate digital images of the drill cuttings of the group of drill cuttings;
f) estimating the bulk density and effective atomic number as data pairs for each of the cuttings of the at least one group of cuttings scanned in e);
g) assembling a reconstituted core using at least of a portion of the at least one group of drill cuttings; and
h) determining at least one rock or formation parameter associated with a subterranean location in the subterranean reservoir using the reconstituted core.
2. The method of claim 1, further comprising performing steps d), e), f) and g) for at least two of the plurality of groups of drill cuttings of c).
3. The method of claim 1, wherein b) comprises estimating downhole coordinates from which the group of cuttings were produced to within about plus or minus 10 feet of actual downhole location.
4. The method of claim 1, wherein said extracting of said drill cuttings from said drilling fluid in a) comprises separating the cuttings from the drilling fluid with a shale shaker.
5. The method of claim 1, wherein the group of drill cuttings of b) are stored in a bag or canister.
6. The method of claim 1, further comprising classifying the group of drill cuttings by size after b) and before d).
7. The method of claim 6, wherein the classifying by size comprises separating and recovering a fraction of the group of drill cuttings having a size above about 60 mesh to about 40 mesh, or a fraction lower than about 40 mesh to about 60 mesh, for further use in d).
8. The method of claim 1, wherein the group of drill cuttings of b) are cleaned before d).
9. The method of claim 1, wherein two or more groups of drill cuttings are analyzed in d), e), f) and g), and results thereof are arranged in sequential order.
10. The method of claim 9, further wherein corresponding downhole coordinates of estimated locations of each of two or more groups of drill cuttings is recorded along with the physical location of the groups of drill cuttings.
11. The method of claim 1, wherein a sequential arrangement of a plurality of the groups of drill cuttings are placed in separate respective containers.
12. The method of claim 11, wherein the container is a tube with a circular or rectangular cross section.
13. The method of claim 11, wherein the container is an open tray having a width selected wherein the container and the contained drill cuttings pass through a sample opening on an X-ray CT scanner in e).
14. The method of claim 11, where the group of drill cuttings is secured in position in the container by embedding the drill cuttings in a resin material that holds the drill cuttings securely in place.
15. The method of claim 1, wherein b) comprises physically measuring the bulk density of at least one of the plurality of groups of drill cuttings.
16. The method of claim 15, wherein the physically measuring comprises weighing a group of drill cuttings (M1) and placing the drill cuttings in a container of known volume (V1), then filling the container with a liquid, and recording volume of liquid (V2) required to fill the container, and calculating bulk density (\u03c1) with the formula:
\u03c1
=
M
1
V
1
–
V
2
.
17. The method of claim 1, wherein assembling of the reconstituted core in g) comprises physically assembling the drill cuttings of the group to provide the reconstituted core.
18. The method of claim 1, wherein assembling of the reconstituted core in g) comprises logically assembling the drill cuttings of the group to provide the reconstituted core.
19. The method of claim 1, wherein the reconstituted core of g) cross-references a location on the reconstituted core and a subterranean location from which the drill cuttings were produced.
20. The method of claim 1, wherein the drill cuttings included in the reconstituted core in g) comprise all drill cuttings collected in a particular time period and from a particular subterranean location.
21. The method of claim 20, wherein the drill cuttings included in the reconstituted core in g) comprise drill cuttings further classified according to size, shape, or both.
22. The method of claim 1, further comprising i) displaying at least one of the X-ray CT scans and estimates of bulk density and effective atomic number produced from the reconstituted cores.
23. The method of claim 22, wherein said displaying comprises at least one of graphically displaying on paper and electronically displaying on a computer display.
24. The method of claim 22, wherein the reconstituted cores are displayed as a log of a representation of a horizontal well core.
25. The method of claim 1, wherein the at least one rock or formation parameter associated with a subterranean location in the subterranean reservoir of h) is at least one rock property selected from porosity, mineralogy, grain size, grain size variation, pyrite variation, cutting size, cutting size distribution, geomechanics, or any combinations thereof.
26. The method of claim 1, wherein the at least one rock or formation parameter associated with a subterranean location in the subterranean reservoir of h) is at least one of a facies location in the formation and a formation property.
27. A method to characterize subterranean formations, comprising:
a) extracting drill cuttings from a used drilling fluid at the Earth’s surface, wherein the drilling fluid transports the drill cuttings to the Earth’s surface after use of the drilling fluid in a drilling of a wellbore in a subterranean reservoir;
b) grouping the drill cuttings into a group of cuttings based on a time of arrival of the drill cuttings at the Earth’s surface;
c) repeating steps a) and b) at least once to provide a plurality of groups of drill cuttings that arrive sequentially at different recorded times at the Earth’s surface;
d) measuring bulk density of a plurality of groups of drill cuttings of c);
e) performing a multi-energy X-ray CT scan of the plurality of drill cuttings of d) to generate digital images of the drill cuttings of the groups of drill cuttings;
f) estimating the bulk density and effective atomic number as data pairs for each of the cuttings of the at least one group of cuttings scanned in e);
g) determining if a change in trend occurs for a group of drill cutting in f):
h) assembling a reconstituted core using a group of drill cuttings for which a change in trend was determined to occur in g); and
i) determining at least one rock or formation parameter associated with a subterranean location in the subterranean reservoir using the reconstituted core of h).
28. A system to characterize subterranean formations, comprising:
(a) a drill cutting collection unit for extracting drill cuttings from a drilling fluid in groups of drill cuttings based on a time of arrival of the drill cuttings at the Earth’s surface and placing the groups of drill cuttings in respective containers;
(b) a device for measuring bulk density of at least one of the plurality of groups of drill cuttings;
(c) a multi-energy X-ray CT scanner having a stage capable of holding at least one of the groups of drill cuttings, and optionally including the container that holds the group of drill cuttings, and
(d) one or more computer systems operable to i) obtain 3-D digital images of the groups of drill cuttings, ii) estimating the bulk density and effective atomic number as data pairs for each of the cuttings of the at least one group of cuttings scanned in the multi-energy X-ray CT scanner e), iii) assembling a reconstituted core using at least of a portion of the at least one group of drill cuttings, iv) using the reconstituted core to determine at least one rock or formation parameter associated with a subterranean location in the subterranean reservoir, and v) output the results to at least one device to display, print, or store results of the computations; and
(e) at least one device to display, print, or store results of the computations.
29. A computer program product on a non-transitory computer readable medium that, when performed on a processor in a computerized device provides a method for performing computations of one or more or all of the indicated steps of the method of claim 1.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
1. A P2O5\u2014BaO\u2014ZnO\u2014Nb2O5 type optical glass, containing 25-50 wt. % P2O5, 16-35 wt. % BaO, 1-25 wt. % ZnO, 3-10wt. % Nb2O5, 0.1-8 wt. % B2O3 and 0.1-10 wt. % F.
2. The optical glass according to claim 1, further containing at least one of: 0-8 wt. % GeO2, 0-1 wt. % Al2O3 (excluding 1 wt. %), 0-8 wt. % Li2O, 0-10 wt. % Na2O, 0-8 wt. % K2O, 0-10 wt. % CaO, 0-15 wt. % SrO, 0-5 wt. % MgO, 0-10 wt. % W03, 0-8 wt. % Gd2O3, 0-8 wt. % Ta2O5, 0-5 wt. % Y2O3, 0-3 wt. % ZrO2, 0-10 wt. % LiF, 0-10 wt. % NaF, 0-15 wt. % ZnF2, and 0-15 wt. % BaF2.
3. The optical glass according to claim 1, having a refractive index (nd) of 1.58 to 1.70, an Abbe number (nd) of 42 to 58, a glass transition point (Tg) of 470\xb0 C. or lower, and a glass deformation point (At) of 500\xb0 C. or lower.
4. The optical glass according to claim 1, used for transfer of a fine structure.