1. A composition comprising:
(A) a compound having at least one aliphatic unsaturation;
(B) a cyclic organohydrogensilicon crosslinking compound containing at least one silicon-bonded hydrogen atom (SiH) per molecule, prepared by a platinum catalyzed coupling reaction of a methylhydrogen cyclosiloxane, with a reactant containing aliphatic unsaturation, hydroxy functionalities, or a mixture of both,
wherein 5-70 percent of the SiH bonds in the cyclic organohydrogensilicon crosslinking compound are replaced or converted to functional groups by adding to the coupling reaction at least one functional compound selected from the group consisting of allylglycidyl ether, vinylcyclohexylepoxide, and compounds containing propargyloxy and hexynyloxy groups; and
(B1) a linear organohydrogensilicon crosslinking compound containing at least one silicon-bonded hydrogen atom per molecule.
2. A composition according to claim 1 wherein the functional compound is allylglycidyl ether, or vinylcyclohexylepoxide.
3. A composition according to claim 2 wherein the cyclic organohydrogensilicon crosslinking compound has the structure:
and where 10-25 percent of the SiH groups has been replaced with propylglycidylether groups, x is 1-5, d is about 8, and Me is methyl.
4. A release coating composition comprising:
(A) a compound having at least one aliphatic unsaturation;
(B) a cyclic organohydrogensilicon crosslinking compound containing at least one silicon-bonded hydrogen atom (SiH) per molecule, prepared by a platinum catalyzed coupling reaction of a methylhydrogen cyclosiloxane, with a reactant containing aliphatic unsaturation, hydroxy functionalities, or a mixture of both;
wherein 5-70 percent of the SiH bonds in the cyclic organohydrogensilicon crosslinking compound are replaced or converted to functional groups by adding to the coupling reaction at least one functional compound selected from the group consisting of allylglycidyl ether, vinylcyclohexylepoxide, and compounds containing propargyloxy and hexynyloxy groups;
(B1) a linear organohydrogensilicon crosslinking compound containing at least one silicon-bonded hydrogen atom per molecule; and
(C) a platinum group metal-containing catalyst.
5. A release coating composition according to claim 4 wherein the functional compound is allylglycidyl ether or vinylcyclohexylepoxide.
6. A release coating composition according to claim 5 wherein the cyclic organohydrogensilicon crosslinking compound has the structure:
and where 10-25 percent of the SiH groups has been replaced with propylglycidylether groups, x is 1-5, d is about 8, and Me is methyl.
7. A release coating composition according to claim 4 wherein the composition further comprises one or more components selected from the group consisting of an inhibitor, a bath life extender, a release modifier, and a solvent.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
1. An optical assembly comprising:
a receiver die having a central area;
a lens assembly optically coupled with the receiver die and encapsulating at least a portion of the receiver die,
wherein the lens assembly comprises a focal lens surface having an optical axis portion extending from the focal lens surface to the receiver die, and
wherein the lens assembly further comprises a base portion interposed in a base portion arrangement between the focal lens surface and the receiver die configured to substantially limit off axis rays at the central area of the receiver die collected via the focal lens surface.
2. An optical assembly as recited in claim 1 wherein the base portion of the lens assembly comprises an optical barrier perimeter.
3. An optical assembly as recited in claim 2 wherein the optical barrier perimeter comprises an optical barrier surface that is substantially at least one of graduated or tapered or conical and extending from a receiver die area proximate to the receiver die to a lens area proximate to the focal lens surface.
4. An optical assembly as recited in claim 2 wherein the optical barrier perimeter has a longitudinal dimension extending substantially along at least a majority of the optical axis portion of the focal lens surface, from proximate the focal lens surface to proximate the receiver die.
5. An optical assembly as recited in claim 1 wherein the base portion of the lens assembly comprises a solid optical member extending substantially along at least a majority of the optical axis portion of the focal lens surface, from proximate the focal lens surface to proximate the receiver die.
6. An optical assembly as recited in claim 5 wherein the solid optical member encapsulates at least the portion of the receiver die.
7. An optical assembly as recited in claim 5 wherein the solid optical member comprises a member surface that is substantially at least one of graduated or tapered or conical and extending from a receiver die area proximate to the receiver die to a lens area proximate to the focal lens surface.
8. An optical assembly as recited in claim 5 wherein:
the focal lens surface has a lens aperture; and
the solid optical member has an optical member entry aperture arranged proximate to the lens aperture of the focal lens surface and configured to limit off axis rays at the central area of the receiver die collected via the focal lens surface.
9. An optical assembly as recited in claim 8 wherein the optical member entry aperture of the solid optical member is substantially larger than the lens aperture of the focal lens surface.
10. An optical assembly as recited in claim 5 wherein, the solid optical member has an optical member exit aperture arranged proximate to the receiver die and configured to substantially limit off axis rays at the central area of the receiver die collected via the focal lens surface.
11. An optical assembly as recited in claim 5 wherein the solid optical member has an optical member entry aperture and an optical member exit aperture interposed between the focal lens surface and the receiver die and configured to substantially limit off axis rays at the central area of the receiver die collected via the focal lens surface.
12. An optical assembly as recited in claim 5 wherein the focal lens surface has a lens aperture, and the solid optical member has an optical member exit aperture, and wherein the optical member exit aperture of the solid optical member is substantially larger than the lens aperture of the focal lens surface.
13. An optical assembly as recited in claim 5 wherein the solid optical member has an optical member entry aperture and an optical member exit aperture, and wherein the solid optical member extends from the optical member entry aperture to the optical member exit aperture along a majority of optical axis portion of the focal lens surface, from proximate the focal lens surface to proximate the receiver die.
14. An optical assembly as recited in claim 5 wherein the solid optical member comprises a wavelength selective member that is substantially transparent to a first wavelength of light and substantially blocks a second wavelength of light, wherein the first and second wavelengths are substantially different from one another.
15. An optical assembly as recited in claim 1 further comprising a bubble limiting apparatus configured to substantially limit presence of bubbles between the focal lens surface and the receiver die.
16. An optical assembly as recited in claim 15 wherein the bubble limiting apparatus comprises a solid optical member having a member surface portion that is substantially at least one of graduated or tapered or conical and extending from an optical exit aperture of the solid optical member to an optical entry aperture of the solid optical member that is smaller than the optical exit aperture of the solid optical member and configured to substantially limit presence of bubbles between the focal lens surface and the receiver die, when the solid optical member is initially molded in liquid form.
17. An apparatus comprising:
a receiver die; and
a high aspect ratio lens assembly optically coupled with the receiver die,
wherein the high aspect ratio lens assembly comprises a lens surface and an elongated optical member having a narrow extremity arranged proximate to the lens surface and a broad extremity arranged proximate to the receiver die,
wherein the elongated optical member has an elongated dimension that is substantially greater than a width dimension of the narrow extremity, and
wherein the elongated optical member is interposed along the elongated dimension between the lens surface and the receiver die so as to provide the high aspect ratio of the high aspect ratio lens assembly.
18. An apparatus as recited in claim 17 wherein ratio of the elongated dimension to the narrow dimension is substantially greater than approximately 1:1.
19. A method of manufacturing a device comprising:
die-attaching a receiver chip to a first portion of a substrate;
electrically connecting a first terminal of the receiver chip to a first lead of the device, wherein the first lead extends from the first portion of the substrate;
forming uncured elastomeric encapsulant into a focal lens surface and a bubble limiting apparatus configured to substantially limit presence of bubbles between the focal lens surface and the receiver die; and
curing the elastomeric encapsulant.
20. A method as recited in claim 19 wherein the bubble limiting apparatus comprises a solid optical member having a surface that is substantially at least one of graduated or tapered or conical and extending from an optical exit aperture of the solid optical member to an optical entry aperture of the solid optical member that is smaller than the optical exit of the solid optical member and configured to substantially limit presence of bubbles between the focal lens surface and the receiver die, when forming the solid optical member from the uncured elastomeric encapsulant.