1. An ink-jet recording apparatus, comprising:
a recording head which ejects ink to perform recording; and an ink-extracting member which has an ink-extract passage as an inner passage formed therein and which is to be removably connected to an ink cartridge that stores ink for extracting the ink from the ink cartridge to supply the ink to the recording head,
wherein the ink-extracting member is to be connected to the ink cartridge including: (a) an ink-outlet valve member which shuts off a flow of the ink from the ink cartridge and which establishes a state in which the ink can be extracted from the ink cartridge by the ink-extracting member when the ink-outlet valve member is pressed by the ink-extracting member which abuts on the ink-outlet valve member upon connection of the ink-extracting member to the ink cartridge; and (b) a seal which is disposed downstream of the ink-outlet valve member and into which the ink-extracting member is inserted so that the seal comes into close contact with an outer surface of the ink-extracting member,
wherein the ink-extracting member further includes, at an end portion thereof, an end face which abuts on the ink-outlet valve member, and at least one ink-extract communication opening which is formed at the end portion and which is formed in a peripheral wall of the ink-extracting member, so as to communicate with the ink-extract passage,
and wherein the at least one ink-extract communication opening is disposed, in a state in which the ink-extracting member is connected to the ink cartridge, at a position nearer to the ink-outlet valve member than a portion of the ink-extracting member with which the seal comes into close contact.
2. The ink-jet recording apparatus according to claim 1, wherein the end face of the ink-extracting member is generally flat.
3. The ink-jet recording apparatus according to claim 1, wherein the ink-extracting member has an end opening which is open in the end face thereof and to which the ink-extract passage is open, and each of the at least one ink-extract communication openings is a cutout which is formed at an end of the peripheral wall of the ink-extracting member and which is open in the end face.
4. The ink-jet recording apparatus according to claim 3, wherein the ink-extracting member is disposed such that the end opening is open upwards and the at least one ink-extract communication opening is formed so as to have a size determined such that an outer periphery of a surface of the ink in the ink-extracting member substantially reaches the end face of the ink-extracting member, the surface of the ink being concave owing to surface tension.
5. The ink-jet recording apparatus according to claim 1, wherein the at least one ink-extract communication opening consists of a plurality of ink-extract communication openings which are formed in the peripheral wall so as to be spaced apart from each other with a substantially constant spacing distance.
6. The ink-jet recording apparatus according to claim 1, wherein the ink-extracting member is formed of a resin material.
7. The ink-jet recording apparatus according to claim 1, wherein the ink-extracting member has at least one air-discharge passage for discharging air existing in a space located downstream of the ink-outlet valve member out into an exterior of the ink cartridge, upon insertion of the ink-extracting member into the seal.
8. The ink-jet recording apparatus according to claim 7, wherein the at least one air-discharge passage is formed so as to be held in communication with the exterior of the ink cartridge until the ink-extracting member substantially abuts on the ink-outlet valve member.
9. The ink-jet recording cartridge according to claim 7, wherein the at least one air-discharge passage is arranged such that communication between the space located downstream of the ink-outlet valve member and the exterior of the ink cartridge is shut off by the seal when the state in which the ink can be extracted from the ink cartridge by the ink-extracting member is established.
10. The ink-jet recording apparatus according to claim 7, wherein each of the at least one air-discharge passage is a groove formed in the outer surface of the ink-extracting member.
11. The ink-jet recording apparatus according to claim 1, comprising an air-introducing member which has an air-introduce passage as an inner passage formed therein and which is to be removably connected to the ink cartridge for introducing air into the ink cartridge,
wherein the air-introducing member is to be connected to the ink cartridge including an air-inlet valve member which shuts off a flow of the air into the ink cartridge and which establishes a state in which the air can be introduced into the ink cartridge by the air-introducing member when the air-inlet valve member is pressed by the air-introducing member which abuts on the air-inlet valve member upon connection of the air-introducing member to the ink cartridge,
and wherein the air-introducing member includes, at an end portion thereof, an end face which abuts on the air-inlet valve member, and at least one air-introduce communication opening which is formed at the end portion and which is formed in a peripheral wall of the air-introducing member, so as to communicate with the air-introduce passage.
12. The ink-jet recording apparatus according to claim 11, wherein the end face of the air-introducing member is generally flat.
13. The ink-jet recording apparatus according to claim 11, wherein the ink-extracting member and the air-introducing member are the same in shape.
14. An ink-jet recording apparatus, comprising:
a recording head which ejects ink to perform recording;
an ink cartridge which stores ink; and
an ink-extracting member which has an ink-extract passage as an inner passage formed therein and which is to be removably connected to the ink cartridge for extracting the ink from the ink cartridge to supply the ink to the recording head,
wherein the ink cartridge includes: (a) an ink-outlet valve member which shuts off a flow of the ink from the ink cartridge and which establishes a state in which the ink can be extracted from the ink cartridge by the ink-extracting member when the ink-outlet valve member is pressed by the ink-extracting member which abuts on the ink-outlet valve member upon connection of the ink-extracting member to the ink cartridge; and (b) a seal which is disposed downstream of the ink-outlet valve member and into which the ink-extracting member is inserted so that the seal comes into close contact with an outer surface of the ink-extracting member,
wherein the ink-extracting member further includes, at an end portion thereof, an end face which abuts on the ink-outlet valve member and at least one ink-extract communication opening which is formed at the end portion and which is formed in a peripheral wall of the ink-extracting member, so as to communicate with the ink-extract passage,
and wherein the at least one ink-extract communication opening is disposed, in a state in which the ink-extracting member is connected to the ink cartridge, at a position nearer to the ink-outlet valve member than a portion of the ink-extracting member with which the seal comes into close contact.
15. The ink-jet recording apparatus according to claim 14, wherein the end face of the ink-extracting member is generally flat.
16. An ink-jet recording apparatus, comprising:
a recording head which ejects ink to perform recording; and an ink-extracting member which has an ink-extract passage as an inner passage formed therein and which is to be removably connected to an ink cartridge that stores ink for extracting the ink from the ink cartridge to supply the ink to the recording head,
wherein the ink-extracting member is to be connected to the ink cartridge including: an ink-outlet valve member which shuts off a flow of the ink from the ink cartridge and which establishes a state in which the ink can be extracted from the ink cartridge by the ink-extracting member when the ink-outlet member is pressed by the ink-extracting member which abuts on the ink-outlet valve member upon connection of the ink-extracting member to the ink cartridge; and a seal which is disposed downstream of the ink-outlet valve member and into which the ink-extracting member is inserted so that the seal comes into close contact with an outer surface of the ink-extracting member,
and wherein the ink-extracting member further includes: at least one ink-extract communication opening which is disposed, in a state in which the ink-extracting member is connected to the ink cartridge, at a position nearer to the ink-outlet valve member than a portion of the ink-extracting member with which the seal comes into close contact; and at least one air-discharge passage for discharging air existing in a space located downstream of the ink-outlet valve member out into an exterior of the ink cartridge, upon insertion of the ink-extracting member into the seal.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
1. A procatalyst composition comprising:
a combination of a magnesium moiety, a titanium moiety and an internal electron donor comprising a substituted phenylene aromatic diester having the structure (I)
wherein R1-R14 are the same or different, each of R1-R14 is selected from the group consisting of hydrogen, a substituted hydrocarbyl group having 1 to 20 carbon atoms, an unsubstituted hydrocarbyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, a heteroatom, and combinations thereof; and
two consecutive R groups in R1-R4 are linked to form a cyclic structure.
2. The procatalyst composition of claim 1 wherein R1-R2 form a C6 membered ring and each of R3-R14 is selected from the group consisting of hydrogen, a substituted hydrocarbyl group having 1 to 20 carbon atoms, an unsubstituted hydrocarbyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, a heteroatom, and combinations thereof.
3. The procatalyst composition of claim 1 wherein each of R3-R14 is hydrogen.
4. The procatalyst composition of claim 1 wherein the substituted phenylene aromatic diester has the structure (IV)
and each of R3-R14 is hydrogen.
5. The procatalyst composition of claim 1 wherein R2-R3 form a C6 membered ring and each of R1, R4 and R5-R14 is selected from the group consisting of hydrogen, a substituted hydrocarbyl group having 1 to 20 carbon atoms, an unsubstituted hydrocarbyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, a heteroatom, and combinations thereof.
6. The procatalyst composition of claim 5 wherein each of R1, R4 and R5-R14 is hydrogen.
7. The procatalyst composition of claim 1 wherein the substituted phenylene aromatic diester has the structure (V)
and each of R1, R4 and R5-R14 is hydrogen.
8. A catalyst composition comprising the procatalyst of claim 1;
a cocatalyst; and
an activity limiting agent comprising an aliphatic mono-carboxylic acid ester.
9. The catalyst composition of claim 8 comprising an external electron donor comprising an alkoxysilane.
10. A procatalyst composition comprising:
a combination of a magnesium moiety, a titanium moiety and an internal electron donor comprising a substituted phenylene aromatic diester having the structure (I)
wherein R1-R14 are the same or different, each of R1-R14 is selected from the group consisting of hydrogen, a substituted hydrocarbyl group having 1 to 20 carbon atoms, an unsubstituted hydrocarbyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, a heteroatom, and combinations thereof;
two consecutive R groups in R5-R9 are linked to form a cyclic structure; and
two consecutive R groups in R10-R14 are linked to form a cyclic structure.
11. The procatalyst composition of claim 10 wherein the substituted phenylene aromatic diester has the structure (II)
and each of R2, R4, R5-R7 and R10-R12 is hydrogen.
12. The procatalyst composition of claim 10 wherein the substituted phenylene aromatic diester has the structure (III)
and each of R2, R4, R5, R6, R9, R10, R11, and R14 is hydrogen.
13. A catalyst composition comprising the procatalyst of claim 10;
a cocatalyst; and
an activity limiting agent comprising an aliphatic mono-carboxylic acid ester.
14. The catalyst composition of claim 13 comprising an external electron donor comprising an alkoxysilane.