1. An adhesive article comprising:
a fluorothermoplastic film having a interior portion and a major surface; and
a pressure sensitive adhesive layer adhered to at least a portion of the major surface, wherein the pressure sensitive adhesive comprises a silicone polyurea block copolymer and an MQ tackifying resin, and wherein the silicone polyurea block copolymer comprises n blocks represented by the formula
and m blocks represented by the formula
wherein
each R is methyl;
each Z is \u2014CH2C6H4C(CH3)2C6H4CH2\u2014;
each Y is \u2014CH2CH2CH2\u2014;
each D is H:
each B is \u2014CH2CH2CH2CH(CH3)\u2014;
p is an integer number that is at least 10;
n is an integer that is at least 1; and
m is an integer in a range of from at least 1 up to and including 1,000, and wherein the ratio of n to m is in a range of from about 1:10 to about 10:1.
2. A method of making an adhesive article, the method comprising adhering a pressure sensitive adhesive layer to at least a portion of a major surface of a fluorothermoplastic film, wherein the pressure sensitive adhesive comprises a silicone polyurea block copolymer and an MQ tackifying resin, wherein the pressure sensitive adhesive comprises a silicone polyurea block copolymer and an MQ tackifying resin, and wherein the silicone polyurea block copolymer comprises n blocks represented by the formula
and m blocks represented by the formula
wherein
each R is methyl;
each Z is \u2014CH2C6H4C(CH3)2C6H4CH2\u2014;
each Y is \u2014CH2CH2CH2\u2014;
each D is H:
each B is \u2014CH2CH2CH2CH(CH3)\u2014;
p is an integer number that is at least 10;
n is an integer that is at least 1; and
m is an integer in a range of from at least 1 up to and including 1,000, and wherein the ratio of n to m is in a range of from about 1:10 to about 10:1.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
1. A complex of the formula:
wherein:
M is platinum or palladium,
Ar1 is a substituted or unsubstituted pyridinyl, isoquinolinyl, quinazolinyl, or imidazolyl ring when M is palladium, and Ar1 is a substituted or unsubstituted pyridinyl, isoquinolinyl, quinazolinyl, imidazolyl pyrazolyl, quinolinyl, triazolyl, benzimidazolyl, benzoxazolyl, or benzothiazolyl ring when M is platinum,
each of Ar2, Ar3, and Ar4 is independently a substituted or unsubstituted phenyl or pyridyl ring;
Ar5 is a substituted or unsubstituted phenyl ring,
Ar6 is a substituted or unsubstituted phenyl ring, or is absent,
each of X1, X2, X3, and X4 is independently a carbon or nitrogen atom,
each of A1 and A2 is independently a nitrogen, carbon, boron, phosphorus, or silicon atom, and each of A1 and A2 is independently optionally substituted, and
each of b1 and b2 is independently present or absent, and if present is an oxygen, sulfur, nitrogen, carbon, boron, phosphorus, or silicon atom.
2. The complex of claim 1, wherein:
Ar1 is a substituted or unsubstituted pyridinyl, isoquinolinyl, quinazolinyl, or imidazolyl ring,
Ar2 is a substituted or unsubstituted phenyl ring, and
Ar6 is absent.
3. The complex of claim 1, wherein:
Ar1 is a substituted or unsubstituted pyridinyl, isoquinolinyl, quinazolinyl, or imidazolyl ring,
Ar2 is a substituted or unsubstituted phenyl ring, and
Ar6 is a substituted or unsubstituted phenyl ring.
4. The complex of claim 1, wherein the complex is selected from the group consisting of:
5. The complex of claim 1, wherein the complex is selected from the group consisting of:
6. The complex of claim 1, wherein the complex is selected from the group consisting of:
7. The complex of claim 1, wherein the complex is selected from the group consisting of:
8. The complex of claim 1, wherein the complex is selected from the group consisting of: