1. A method of forming a vertical capacitor, comprising:
forming an input electrode and an output electrode spaced apart from each other on a top surface of a substrate;
etching a bottom surface of the substrate to form first via holes, the first via holes being spaced apart from each other to expose the input and output electrodes;
forming a conductive material in the first via holes to form via electrodes connected to the input and output electrodes; and
forming a dielectric layer in the substrate to be interposed between the via electrodes.
2. The method of claim 1, wherein the input and output electrodes are formed by depositing one of Ti, Ta, W, TiN, WN, TaSiN, WSiN, or Au using a sputtering process.
3. The method of claim 1, wherein the via electrodes are formed by depositing one of Ti, Ta, W, Ru, TiN, WN, TaSiN, or WSiN using a sputtering process.
4. The method of claim 1, wherein the forming of the dielectric layer comprises:
etching the substrate to form a second via hole between the via electrodes; and
filling the second via hole with a dielectric material.
5. The method of claim 4, wherein the dielectric layer is formed by one of physical vapor deposition (PVD), chemical vapor deposition (CVD), and atomic layer deposition (ALD) processes.
6. The method of claim 5, wherein the dielectric layer comprises at least one of silicon oxide, aluminum oxide, tantalum oxide, silicon oxynitride, or silicon nitride.
7. A vertical capacitor, comprising:
a substrate;
input and output electrodes provided spaced apart from each other, on a top surface of the substrate;
via electrodes extending from a bottom surface of the substrate to the top surface of the substrate to be electrically connected to the input and output electrodes; and
a dielectric layer provided through the substrate between the via electrodes,
wherein the via electrodes are spaced apart from each other to define a gap, and the via electrodes are not electrically connected with any material disposed within the gap,
wherein each of the via electrodes has a shape of column extending in a vertical direction from the bottom surface to the top surface of the substrate, and each of the column-shaped via electrode is not electrically connected to any inner electrode disposed inside of the substrate between the top and bottom surfaces, and the dielectric layer is not formed as a plurality of laminated layers.
8. The vertical capacitor of claim 7, wherein the via electrodes comprise one of Ti, Ta, W, TiN, WN, TaSiN, WSiN, or Au.
9. The vertical capacitor of claim 7, wherein the dielectric layer is formed of a dielectric material having a dielectric constant greater than that of the substrate.
10. The vertical capacitor of claim 9, wherein the dielectric layer comprises at least one of silicon oxide, aluminum oxide, tantalum oxide, silicon oxynitride, or silicon nitride.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
1. A method of releasing stored hydrogen comprising the steps of:
providing a material comprising hydrogen fixed fullerenes; and
irradiating said material in a substantially oxygen free environment with electromagnetic radiation of a sufficient intensity to dehydrogenate said material.
2. The method of claim 1, wherein said electromagnetic radiation ranges from 10\u221212 m to 1012 m in wavelength and comprises gamma rays, x-rays, extreme ultraviolet, ultraviolet, visible, infrared, microwave, radio wave or any combination thereof.
3. The method of claim 2, wherein said electromagnetic radiation is coherent or incoherent.
4. The method of claim 1, wherein said oxygen free environment comprises a vacuum or a non-oxidizing gas atmosphere.
5. The method of claim 1, wherein said hydrogen fixed fullerenes comprises hydrogen fixed to fullerenes, endohedral fullerenes, substituted fullerenes, functionalized fullerenes, or any mixture thereof.
6. The method of claim 1, wherein said material comprises CxHy, wherein x is 28 to 1500, and, y is 2 to x.
7. The method of claim 1, wherein said material comprises CxMyHz, where M is a metal, x is 28 to 1500, y is 1 to x, and z is 2 to x.
8. The method of claim 1, wherein said material comprises a plurality of hydrogen fixed fullerenes secured by a carrier or matrix.
9. The material of claim 8, wherein said carrier or matrix comprises an organic gas, liquid or solid; an inorganic gas, liquid, or solid; a polymer or polymer composite; water, an aqueous solution or aqueous suspension; a metal or metal alloy, a glass or ceramic; a biological or biologically derived material; or any mixture thereof.
10. The method of claim 8, wherein said material comprises a hydrogen fixed fullerene coated polymeric tape.