What is claimed is:
1. A method for forming on a substrate an electrode having a structure with at least two layers, the method comprising:
a first step of forming a first resist layer on the substrate, the first resist layer having a first opening therein;
a second step of forming a second resist layer on the first resist layer;
a third step of forming a second opening in the second resist layer, the second opening having a larger area than the first opening and being located in the vicinity of the first opening;
a fourth step of forming a first conductor layer on inner surfaces of the first and second openings and on surfaces of the first and second resist layers;
a fifth step of forming a second conductor layer on the first conductor layer in a region other than the inner peripheral surface of the second opening;
a sixth step of removing, by etching, the first conductor layer that lies at a portion that is not covered by the second conductor layer within the second opening;
a seventh step of removing, by a lift-off process, the second resist layer and the first and second conductor layers which are above the second resist layer; and
an eighth step of removing the first resist layer by ashing.
2. The method according to claim 1, wherein, in the first step, the first opening is formed in the first resist layer by photolithography.
3. The method according to claim 1 or 2, wherein, in the third step, the second opening is formed in the second resist layer by photolithography.
4. The method according to claim 1 or 2, wherein, in the third step, the second opening is formed to have an inverted-tapered cross-sectional shape.
5. The method according to claim 1 or 2, wherein, in the fourth step, the first conductor layer is formed by sputtering.
6. The method according to claim 1 or 2, wherein, in the fifth step, the second conductor layer is formed by deposition.
7. The method according to claim 1 or 2, wherein, in the sixth step, the first conductor layer is removed by plasma etching with a gas mixture of CF4 or CHF3 and oxygen.
8. The method according to claim 1 or 2, wherein the first conductor layer is formed by sputtering in the fourth step; the second conductor layer is formed by deposition in the fifth step; the first conductor layer is removed by dry etching in the sixth step; and the fourth and fifth steps are sequentially performed using a multi-chamber vacuum apparatus.
9. The method according to claim 8, wherein the sixth step is also performed with said multi-chamber vacuum apparatus.
10. The method according to claim 1 or 2, wherein the first resist layer is formed to have a thickness less than the second resist layer.
11. The method according to claim 1 or 2, further comprising a step of heat-treating the first resist layer between the first and second steps, such that the edge of the open end of the first opening is thermally deformed and chamfered.
12. The method according to claim 11, wherein said heat-treating step hardens the first resist layer.
13. The method according to claim 1 or 2, wherein the electrode is a gate electrode for a field effect transistor and the substrate is a semiconductor substrate.
14. The method according to claim 13, wherein the first conductor layer comprises a high-melting-point metal.
15. The method according to claim 13, wherein the second conductor layer has a multilayer structure, the layers each comprising metal and at least one of the layers comprising gold.
16. A field effect transistor comprising:
a gate electrode formed by the method according to claim 13;
a source electrode; and
a drain electrode,
said source and drain electrodes being disposed on said semiconductor substrate.
17. The method according to claim 1, further comprising an etching step which forms a recess in a portion of the substrate that is exposed to the first opening.
18. The method according to claim 17, wherein said fourth step further forms said first conductor layer in said recess.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
1. A high temperature oxidation resistant carbonaceous molding comprising:
a parent material made of carbon material and having an exterior surface;
a metallic carbide containing layer which is formed such that a metal is diffused to the exterior surface of the parent material and metal carbide is formed thereon and having cracks, wherein the metal is at least one of chromium, titanium, zirconium, hafnium, vanadium, niobium, tantalum, molybdenum, and tungsten;
a vitreous member composed of a vitreous material filled in the cracks; and
a vitreous material layer formed on a surface of the metallic carbide containing layer;
wherein the vitreous member and the vitreous material layer are integrated and cover the exterior surface of the parent material.
2. A high temperature oxidation resistant carbonaceous molding as set forth in claim 1, wherein the metallic carbide containing layer is more than 65 wt % carbide.
3. A high temperature oxidation resistant carbonaceous molding as set forth in claim 1, wherein the metallic carbide containing layer has thickness of from 10 to 50 \u03bcm.
4. A high temperature oxidation resistant carbonaceous molding as set forth in claim 1, wherein the cracks are like wedges from a surface of the metallic carbide containing layer toward the parent material.