1. A plastic resin composition comprising a titanium dioxide pigment comprising titanium dioxide particles and a dense hydrous silica coating formed on the surface of the titanium dioxide particles and an organic compound coating formed on the dense hydrous silica coating without any interlayers; and
a LDPE resin.
2. A plastic resin composition according to claim 1, wherein the organic compound is at least one selected from the group consisting of polyols, organosilicon compounds, alkanolamines and derivatives thereof, lauric acid and metal salts thereof, oleic acid and metal salts thereof, paraffin wax and derivatives thereof and polyethylene wax and derivatives thereof.
3. A plastic resin composition according to claim 1, wherein the organic compound is a polyol andor an organosilicon compound.
4. A plastic resin composition according to claim 1, wherein the organic compound is at least one selected from the group consisting of trimethylolpropane, trimethylolethane, alkylsilanes of 4-10 carbon atoms and hydrolyzates thereof and dimethylpolysiloxane.
5. A plastic resin composition according to claim 1, wherein the coating amount of the dense hydrous silica is in the range of 0.5-6% by weight in terms of SiO2 based on the titanium dioxide particles.
6. A plastic resin composition according to claim 1, wherein the coating amount of the organic compound is in the range of 0.5-5% by weight based on the titanium dioxide particles.
7. A process for producing a plastic resin composition comprising
forming a dense hydrous silica coating on titanium dioxide particles and thereafter forming an organic compound coating on the surface of the dense hydrous silica coating and obtaining a titanium dioxide pigment, and
blending the titanium dioxide pigment in a molten LDPE resin.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
1. A carrier for the production of an epoxidation catalyst, which carrier is obtained by preparing a carrier precursor containing (a) \u03b1-alumina, (b) silicon or a compound thereof, and (c) at least one element selected from the class consisting of germanium, tin, lead, phosphorus, antimony, and bismuth or a compound thereof and subsequently subjecting said precursor to a heat treatment in a non-oxidative gas.
2. A carrier according to claim 1, wherein said non-oxidative gas is at least one member selected from the group consisting of a reducing gas, an inert gas, and a gas having an oxygen concentration of not more than 10 vol. %.
3. A carrier according to claim 2, wherein said non-oxidative gas is at least one member selected from the group consisting of hydrogen gas, carbon monoxide gas, nitrogen oxide gas, dinitrogen oxide gas, ammonia, and a mixture of such gas with an inert gas.
4. A carrier according to claim 2, wherein said inert gas is at least one member selected from the group consisting of nitrogen gas, argon gas, rare gas, carbon dioxide gas, and alkane gas.
5. A carrier according to claim 3, wherein said non-oxidative gas is a mixture of hydrogen and an inert gas.
6. A carrier according to claim 5, wherein said non-oxidative gas is a mixture of hydrogen gas having a hydrogen concentration in the range of 0.1\u201350 vol. % and nitrogen gas.
7. A carrier according to claim 2, wherein said non-oxidative gas is a gas having an oxygen concentration of not more than 10 vol. %.
8. A carrier according to claim 5, wherein said non-oxidative gas is a mixture of hydrogen gas having a hydrogen concentration in the range of 0.1\u201315 vol. % and nitrogen gas.
9. A carrier according to claim 1, wherein the heat treatment in a non-oxidative gas is carried out at a temperature in the range of 400\u20131700\xb0 C.
10. A carrier according to claim 1, wherein said carrier precursor contains (a) \u03b1-alumina, (b) silicon or a compound thereof, and (c) at least one element selected from the class consisting of antimony, phosphorus, and bismuth or a compound thereof.
11. A carrier according to claim 1, wherein said carrier precursor contains (a) \u03b1-alumina, (b) silicon or a compound thereof, and (c) antimony or an antimony compound.
12. A carrier according to claim 1, wherein said carrier has a BET specific surface area in the range of 0.1\u201310 m2g, a water absorption ratio in the range of 10\u201350%, an average pore diameter in the range of 0.1\u20135 \u03bcm, and an apparent porosity in the range of 20\u201380%.
13. A catalyst, comprising silver and a carrier set forth in claim 1, wherein the silver is deposited on the carrier.
14. A catalyst according to claim 13, wherein the amount of the silver is in the range of 1\u201330 mass %.
15. A catalyst according to claim 14, further comprising a reaction promoter, wherein the reaction promoter is a metal element selected from the group consisting of alkali metals and thallium, and is also deposited on the carrier; and the amount of the reaction promoter is 0.0001\u20135 mass % (calculated as M2O, M being an alkali metal or thallium).
16. A method for the production of an epoxide by subjecting a corresponding unsaturated hydrocarbon having 2\u20134 carbon atoms to gas phase partial oxidation with a molecular oxygen-containing gas in the presence of a catalyst set forth in claim 13.
17. A carrier according to claim 2, wherein the heat treatment in a non-oxidative gas is carried out at a temperature in the range of 400\u20131700\xb0 C.
18. A carrier according to claim 3, wherein the heat treatment in a non-oxidative gas is carried out at a temperature in the range of 400\u20131700\xb0 C.
19. A carrier according to claim 4, wherein the heat treatment in a non-oxidative gas is carried out at a temperature in the range of 400\u20131700\xb0 C.
20. A carrier according to claim 5, wherein the heat treatment in a non-oxidative gas is carried out at a temperature in the range of 400\u20131700\xb0 C.
21. A carrier according to claim 6, wherein the heat treatment in a non-oxidative gas is carried out at a temperature in the range of 400\u20131700\xb0 C.
22. A carrier according to claim 7, wherein the heat treatment in a non-oxidative gas is carried out at a temperature in the range of 400\u20131700\xb0 C.
23. A carrier according to claim 8, wherein the heat treatment in a non-oxidative gas is carried out at a temperature in the range of 400\u20131700\xb0 C.