1. A multilayer ceramic capacitor comprising:
an element main body in which a dielectric layer and an inner electrode layer are alternately laminated,
the inner electrode layer comprising: a composite structure having an inner electrode main layer of a base metal; and particles consisting of ceramic particles buried in the inner electrode main layer,
wherein an average particle diameter of the buried ceramic particles is \u2154 or less, not including zero, of a thickness of the inner electrode layer.
2. The multilayer ceramic capacitor according to claim 1, wherein a content of ceramic particles buried in the inner electrode main layer is in a range of 1.0 to 20% in terms of a sectional area.
3. A method of manufacturing the multilayer ceramic capacitor of claim 1, the method comprising:
a step of preparing a dielectric layer forming paste for forming the dielectric layer;
a step of preparing an inner electrode forming paste for forming an inner electrode;
a step of forming a chip laminate which is a work in process of the element main body using the dielectric layer forming paste and the inner electrode forming paste; and
a filing step of firing the chip laminate, the inner electrode forming paste containing base metal particles for forming an inner electrode main layer which functions as an electrode, and ceramic particles,
the step of firing the chip laminate comprising: a first firing step performed at a firing temperature of 200 to 1000\xb0 C.; and a second firing step performed at a firing temperature higher than that of the first firing temperature after the first firing step.
4. The method of manufacturing the multilayer ceramic capacitor according to claim 3, wherein the content of the ceramic particles in the inner electrode forming paste is in a range of 0.1 to 40 wt % in conversion into a solid content with respect to that of a base metal.
5. The method of manufacturing the multilayer ceramic capacitor according to claim 3, wherein an average particle diameter of the base metal particles contained in the inner electrode forming paste is 0.4 \u03bcm or less (which does not include zero), and an average particle diameter of the ceramic particles is 0.1 \u03bcm or less (which does not include zero).
6. The method of manufacturing the multilayer ceramic capacitor according to claim 3, wherein the first forming step is performed in order to fire and to form the inner electrode layer while confining the ceramic particles added mainly to the inner electrode forming paste inside the inner electrode layer, and the second firing step is performed in order to fire and to form the dielectric layer while confining mainly the ceramic particles inside the inner electrode layer.
7. The method of manufacturing the multilayer ceramic capacitor according to claim 3, wherein the first firing step is performed in a reduction atmosphere.
8. The multilayer ceramic capacitor according to claim 1, wherein the thickness of the inner electrode main layer ranges from 0.5 to 5 \u03bcm.
9. The multilayer ceramic capacitor according to claim 1, wherein the thickness of the inner electrode main layer ranges from 0.5 to 2.5 \u03bcm.
10. The multilayer ceramic capacitor according to claim 1, wherein the ceramic particles comprise a titanium oxide material, a titanate complex oxide, or a mixture thereof.
11. The multilayer ceramic capacitor according to claim 10, wherein the titanium oxide material comprises NiO, CuO, Mn3O4, Al2O3, MgO, or SiO2 in a range of 0.001 to 30% by weight.
12. The multilayer ceramic capacitor according to claim 10, wherein the titanate complex oxide is barium titanate.
13. The multilayer ceramic capacitor according to claim 12, wherein an atom ratio of BaTi is in a range of 0.95 to 1.20.
14. The multilayer ceramic capacitor according to claim 13, wherein the barium titanate comprises MgO, CaO, Mn3O4, Y2O3, V2O5, ZnO, ZrO2, Nb2O5, Cr2O3, Fe2O3, P2O5, SrO, Na2O, K2O, Li2O, SiO2, WO3, or combinations thereof in a range of about 0.001 to 30% by weight.
15. The multilayer ceramic capacitor according to claim 1, wherein the ceramic particles comprise an oxide compound of a combination of one or two or more of Ba, Ca, Sr, Ti, Zr, Mg, Mn, V, Y, Cr, Nb, Si, K, Na, Li, B, Sc, Hf, Al, W, and a lanthanoid material.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
1. A polyolefin composition comprising
(A) a first propylene-ethylene random copolymer having an ethylene content CMA of 1.0-6 wt % and an MFR(A) measured according to ISO 1133 of 5-40 g10 min and
(B) a second propylene-ethylene random copolymer, wherein the polyolefin composition has an ethylene content CMAB of 2.5-6 wt % and an MFR(AB) measured according to ISO 1132 of 3-20 g10 min with the proviso that CMAB>CMA and MFR(A)MFR(AB)>1.45 and where the polyolefin composition further has a randomness R of the ethylene distribution in the polymer chain of \u22670.945.
2. A polyolefin composition comprising
(A) a first propylene-ethylene random copolymer having an ethylene content CMA 1.0-6 wt % and an MFR(A) measured according to ISO 1133 of 5-40 g10 min and
(B) a second propylene-ethylene random copolymer, wherein
the polyolefin composition has an ethylene content CMAB of 2.5-6 wt % and an MFR(AB) measured according to ISO 1132 of 3-20 g10 min with the proviso that CMAB>CMA and where the polyolefin composition shows a broadness B of 0.67 or more and where the polyolefin composition further has a randomness R of the ethylene distribution in the polymer chain of \u22670.945.
3. A polyolefin composition according to claim 1, having a polydispersity (MwMn) of not less than 4.
4. A polyolefin composition according to claim 1, wherein the polyolefin composition comprises 20-80 wt % propylene-ethylene random copolymer (A) and 80-20 wt % propylene-ethylene random copolymer (B).
5. A polyolefin composition according to claim 1, wherein the melting temperature Tm in \xb0 C., determined by differential scanning calorimetry (DSC), satisfies the relationship Tm\u2266162.5\u22125.4*CMAB, wherein CMAB denotes the ethylene content in wt % of the polyolefin composition.
6. A polyolefin composition according to claim 1, wherein the polyolefin composition has a melting temperature Tm in \xb0 C., determined by differential scanning calorimetry (DSC), of not less than 125\xb0 C. and below 160\xb0 C.
7. A polyolefin composition according to claim 1, wherein, when manufactured into a cast film having a thickness of 80 \u03bcm, the polyolefin composition shows a transparency expressed as \u0394 haze measured as the difference between the haze value, measured according to ASTM D 1003, after sterilisation at 121\xb0 C. for 30 min and the haze value before sterilisation of not more than 10.0%.
8. A process for producing a polyolefin composition comprising,
A) preparing an olefin polymerisation catalyst by
a) preparing a solution of a complex of a Group 2 metal and an electron donor by reacting a compound of said metal with said electron donor or a precursor thereof in an organic liquid reaction medium;
b) adding said solution of said complex to at least one compound of a transition metal of any of groups 4-6 to produce an emulsion the dispersed phase of which contains more than 50 mol % of the Group 2 metal in said complex;
c) agitating the emulsion, optionally in the presence of an emulsion stabilizer, in order to maintain the droplets of said dispersed phase within an average particle size range of suitably 5 to 200 \u03bcm, preferably 10 to 100 \u03bcm, even more preferably 20 to 50 \u03bcm;
d) solidifying said droplets of the dispersed phase; and
e) recovering the obtained solidified particles of the olefin polymerisation catalyst,
B) producing a first propylene-ethylene random copolymer (A) having an ethylene content CMA of 0.5-8 wt % and an MFR(A) of 5-40 g10 min by polymerising propylene and ethylene in the presence of an olefin polymerisation catalyst system comprising the
(B1) olefin polymerisation catalyst
(B2) a cocatalyst including an aluminium alkyl compound, and
(B3) an external donor including a silane compound, and
C) producing a second propylene-ethylene random copolymer (B) by polymerising propylene and ethylene in the presence of the olefin polymerisation catalyst system, such that
the polyolefin composition has an ethylene content CMAB of 1-10 wt % and an MFR(AB) of 3-20 g10 min with the proviso that CMAB>CMA and MFR(A)MFR(AB)>1.45 and a randomness R of the ethylene distribution in the polymer chain of \u22670.945.
9. A process for producing a polyolefin composition comprising,
A) preparing an olefin polymerisation catalyst by
a) preparing a solution of a complex of a Group 2 metal and an electron donor by reacting a compound of said metal with said electron donor or a precursor thereof in an organic liquid reaction medium;
b) adding said solution of said complex to at least one compound of a transition metal of any of groups 4-6 to produce an emulsion the dispersed phase of which contains more than 50 mol % of the Group 2 metal in said complex;
c) agitating the emulsion, optionally in the presence of an emulsion stabilizer, in order to maintain the droplets of said dispersed phase within an average particle size range of suitably 5 to 200 \u03bcm, preferably 10 to 100 \u03bcm, even more preferably 20 to 50 \u03bcm;
d) solidifying said droplets of the dispersed phase; and
e) recovering the obtained solidified particles of the olefin polymerisation catalyst,
B) producing a first propylene-ethylene random copolymer (A) having an ethylene content CMA of 0.5-8 wt % and an MFR(A) of 5-40 g10 min by polymerising propylene and ethylene in the presence of an olefin polymerisation catalyst system comprising the
(B1) olefin polymerisation catalyst
(B2) a cocatalyst including an aluminium alkyl compound, and
(B3) an external donor including a silane compound, and
C) producing a second propylene-ethylene random copolymer (B) by polymerising propylene and ethylene in the presence of the olefin polymerisation catalyst system, such that
the polyolefin composition has an ethylene content CMAB of 1-10 wt % and an MFR(AB) of 3-20 g10 min with the proviso that CMAB>CMA and the polyolefin composition has a broadness B of 0.67 or more and a randomness R of the ethylene distribution in the polymer chain of \u22670.945.
10. An article comprising, a polyolefin composition having
(A) a first propylene-ethylene random copolymer having an ethylene content CMA of 1.0-6 wt % and an MFR(A) measured according to ISO 1133 of 5-40 g10 min and
(B) a second propylene-ethylene random copolymer, wherein
the polyolefin composition has an ethylene content CMAB of 2.5-6 wt % and an MFR(AB) measured according to ISO 1132 of 3-20 q10 min with the proviso that CMAB>CMA and MFR(A)MFR(AB)>1.45 and where the polyolefin composition further has a randomness R of the ethylene distribution in the polymer chain of >0.945.
11. Article according to claim 10, which is a blown film or cast film.
12. Article according to claim 10, wherein the article is for food packaging or a medical article.
13. Article according to claim 10, wherein the article is selected from the group consisting of a food wrapping film and a container, e.g. a conduit or a tube, for holding andor storing andor guiding a therapeutic fluid, and an article for holding andor storing andor guiding blood and a constituent thereof.
14. A polyolefin composition according to claim 2, having a polydispersity (MwMn) of not less than 4.
15. A polyolefin composition according to claim 2, wherein the polyolefin composition comprises 20-80 wt % propylene-ethylene random copolymer (A) and 80-20 wt % propylene-ethylene random copolymer (B).
16. A polyolefin composition according to claim 2, wherein the melting temperature Tm in \xb0 C., determined by differential scanning calorimetry (DSC), satisfies the relationship Tm<162.5\u22125.4*CMAB, wherein CMAB denotes the ethylene content in wt % of the polyolefin composition.
17. A polyolefin composition according to claim 2, wherein the polyolefin composition has a melting temperature Tm in \xb0 C., determined by differential scanning calorimetry (DSC), of not less than 125\xb0 C. and below 160\xb0 C.
18. A polyolefin composition according to claim 2, wherein, when manufactured into a cast film having a thickness of 80 \u03bcm, the polyolefin composition shows a transparency expressed as \u0394 haze measured as the difference between the haze value, measured according to ASTM D 1003, after sterilisation at 121\xb0 C. for 30 min and the haze value before sterilisation of not more than 10.0%.