1. A composition comprising:
(1) a ligand characterized by the following general formula:
wherein R1 and R20 are each independently a ring having from 4-8 atoms in the ring, provided that R1 or R20 do not equal T-J, where T-J is as given by the general formula above and defined below;
T is a bridging group of the general formula \u2014(T\u2032R2R3)\u2014, where T\u2032 is selected from the group consisting of carbon and silicon, R2 and R3 are independently selected from the group consisting of hydrogen, halogen, and optionally substituted alkyl, heteroalkyl, aryl, heteroaryl, alkoxy, aryloxy, silyl, boryl, phosphino, amino, alkylthio, arylthio, and combinations thereof, provided that two or more R2 andor R3 groups may be joined together to form one or more optionally substituted ring systems having from 3-50 non-hydrogen atoms;
J is an optionally substituted five-membered heterocycle, containing at least one nitrogen atom as part of the ring;
(2) a metal precursor compound characterized by the general formula Cr(L)n where each L is independently selected from the group consisting of halide, alkyl, substituted alkyl, cycloalkyl, substituted cycloalkyl, heteroalkyl, substituted heteroalkyl heterocycloalkyl, substituted heterocycloalkyl, aryl, substituted aryl, heteroaryl, substituted heteroaryl, alkoxy, aryloxy, hydroxy, boryl, silyl, amino, amine, hydrido, allyl, diene, seleno, phosphino, phosphine, ether, thioether, carboxylates, thio, 1,3-dionates, oxalates, carbonates, nitrates, sulfates, ethers, thioethers and combinations thereof, wherein two or more L groups may be combined in a ring structure having from 3 to 50 non-hydrogen atoms; n is 1, 2, 3, 4, 5, or 6; and
(3) optionally, one or more activators.
2. The composition of claim 1, wherein the ligand is characterized by the following general formula:
wherein R1, R20, and T are described above; and X1 is nitrogen or \u2014C(R8)n\u2033\u2014, X2, X3, and X4 are selected from the group consisting of oxygen, sulfur, \u2014C(R8)n\u2032\u2014, \u2014N(R8)n\u2033\u2014, and provided that X1 is \u2014C(R8)n\u2033 or at least one of X2, X3, or X4 is \u2014C(R8)n\u2032
each n\u2032 is 1 or 2 and each n\u2033 is 0 or 1; and,
each R8 is independently selected from the group consisting of hydrogen, halogen, nitro, and optionally substituted alkyl, heteroalkyl, aryl, heteroaryl, alkoxy, aryloxy, silyl, boryl, phosphino, amino, alkylthio, arylthio, and combinations thereof, and optionally two or more R1, R20, R2, R3, and R8 groups may be joined to form one or more optionally substituted ring systems.
3. The composition of claim 2, wherein X4 is \u2014C(R8)n\u2033\u2014, wherein n\u2033=1, and R8 is optionally substituted phenyl.
4. The composition of claim 3, wherein R8 is phenyl.
5. The composition of claim 1, wherein R2 and R3 are joined together to form one or more optionally substituted ring systems having from 3-50 non-hydrogen atoms.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
1. A security element including:
a plurality of focusing elements,
a plurality of image regions where each image region is associated with a focusing element,
each image region is printed with at least two layers,
the first layer is offset by a first predetermined amount from a reference axis in the image region,
the second layer is offset by a second predetermined amount from a reference axis in the image region,
each layer being in different colours, and
each image region includes at least a first and second sub-region, wherein a first image is formed in a first range of viewing angles from the first sub-region and a second image is formed in a second range of viewing angles from the second sub-region.
2. A security element according to claim 1 wherein the second image is a complementary colour version of the first image.
3. A security element according to claim 1 including that the image region is printed with a third layer wherein the third layer is a different colour to either the first or second layer and that the third layer is offset by a third predetermined amount from the reference axis in the image region.
4. A security element according to claim 1 including that at least one of the layers of the image region are printed with a colour that corresponds to the RGB colour channel of a colour image with RGB channels or to the CMYK colour channel of a colour image with CMYK colour channels.
5. A security element according to claim 1 including that the at least two layers are contrasting colours.
6. A security element according to claim 1 including that at least one offset is a function of a gray-scale value of the colour channel of the colour of the corresponding layer.
7. A security element according to claim 1 including that the focusing elements are located on one side of a transparent or translucent substrate and that the image regions are located on the opposite side of the transparent or translucent substrate.
8. A security element according to claim 1 including that the focusing elements are located a distance from image regions which is substantially half the focal length of the focusing elements or the focusing elements are located a distance from image regions which is substantially the same or less than the focal length of the focusing elements.
9. A security element according to claim 1, wherein the focusing elements are selected from the group of refractive or diffractive part cylindrical lenses, prisms or zone plates; refractive or diffractive part spherical lenses or polygon based micro lenses; a sampling screen having printed parallel lines; and line elements, dot elements or elements of other shapes.
10. A security element according to claim 1 including that the image regions have a width substantially equal to or greater than half the width of the focusing elements.
11. A security element according to claim 1 including that the image regions have a width substantially equal to, or that differs from by a predetermined amount. the focal point width of the focusing elements at the image plane.
12. A security element according to claim 1 including that the image regions are applied using gravure printing, offset printing, flexographic printing, screen printing or embossing.
13. A security document including the security element of claim 1.
14. A method of forming a security element including the steps of:
providing a transparent or translucent substrate,
applying a plurality of focusing elements to a first surface of the transparent or translucent substrate,
applying a plurality of image regions to the opposite surface of the substrate with at least two layers,
wherein the first layer is offset by a first predetermined amount and the second layer is offset by a second predetermined amount from a reference axis in each image region,
each layer is printed in different colours and wherein
each image region includes at least a first and second sub-region, wherein a first image is formed in a first range of viewing angles from the first sub-region and a second image is formed in a second range of viewing angles from the second sub-region.
15. A method according to claim 14, wherein the second image is a complementary colour version of the first image.
16. A method according to claim 14. wherein each image region includes a third layer, different in colour to either the first or second layer, wherein the third layer is offset by a third predetermined amount from the reference axis in the image region.
17. A method according to claim 14. wherein each layer colour corresponds uniquely to a colour channel colour in the RGB or CMYK colour spacer.
18. A method according to claim 14, wherein at least one offset is a function of a gray-scale value of the colour channel of the colour of the corresponding layer.
19. A method according to claim 14, wherein the focusing elements are applied according to the steps of applying a radiation curable ink to the substrate; embossing the radiation curable ink to create focusing elements in the form of cylindrical lenses, spherical lenses, or diffractive structures: and curing the radiation curable ink.
20. A method according to claim 14, wherein the image regions have a width substantially equal to or greater than half the width of the focusing elements or substantially equal to the focal point width of the focusing elements in the image plane, or the image regions have a width that differs from the focal point width of the focusing elements at the image plane by a predetermined amount.
21. A method according to claim 14, wherein the image regions are applied by one or more of gravure printing, offset printing, flexographic printing, screen printing, and embossing.