1. An apparatus for preventing over-cooling of a plurality of fuel cells, comprising:
a cooling fluid manifold formed in the fuel cells of a stack of the fuel cells and through which cooling fluid flows therethrough;
end plates that are arranged on both ends of the stack of the fuel cells; and
at least one protrusion that is provided to be protruded outward by a preset length on one surface of each of the end plates and are disposed at the end of the cooling fluid manifold to reduce the flow amount of only the cooling fluid which flows in and out between separating plates adjacent to the end plates through the cooling fluid manifold.
2. The apparatus for preventing over-cooling of a fuel cell of claim 1, wherein the at least one protrusion is fitted to an inside of the cooling fluid manifold to block a portion of a flow channel of the cooling fluid that is formed between the separating plates.
3. The apparatus for preventing over-cooling of a fuel cell of claim 1, wherein the at least one protrusion is shaped to correspond to a section of the cooling fluid manifold.
4. The apparatus for preventing over-cooling of a fuel cell of claim 1, wherein the at least one protrusion is installed on at least one side of an inlet and an outlet of the cooling fluid manifold.
5. The apparatus for preventing over-cooling of a fuel cell of claim 1, wherein the at least one protrusion is formed integrally with the end plate.
6. The apparatus for preventing over-cooling of a fuel cell of claim 1, further comprising a dummy cell not participating in power generation, which is arranged at a portion facing the end plate.
7. The apparatus for preventing over-cooling of a fuel cell of claim 1, wherein the cooling fluid is water.
8. A fuel cell vehicle comprising:
a fuel cell stack having a plurality of fuel cells;
a cooling fluid manifold formed in the fuel cells of the fuel cell stack and through which cooling fluid flows therethrough;
end plates that are arranged on both ends of the stack of the fuel cell; and
at least one protrusion that is provided to be protruded outward by a preset length on one surface of each of the end plates and are disposed at the end of the cooling fluid manifold to reduce only the flow amount of the cooling fluid which flows in and out between separating plates adjacent to the end plates through the cooling fluid manifold.
9. The fuel cell vehicle of claim 8, wherein the at least one protrusion is fitted to an inside of the cooling fluid manifold to block a portion of a flow channel of the cooling fluid that is formed between the separating plates.
10. The fuel cell vehicle of claim 8, wherein the at least one protrusion is shaped to correspond to a section of the cooling fluid manifold.
11. The fuel cell vehicle of claim 8, wherein the at least one protrusion is installed on at least one side of an inlet and an outlet of the cooling fluid manifold.
12. The fuel cell vehicle of claim 8, wherein the at least one protrusion is formed integrally with the end plate.
13. The fuel cell vehicle of claim 8, further comprising a dummy cell not participating in power generation, which is arranged at a portion facing the end plate.
14. The fuel cell vehicle of claim 8, wherein the cooling fluid is water.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
1. A biphenyl derivative represented by formula 1:
wherein:
R1 and R2 are independently a hydrogen; a C1-20 linear or branched alkyl group; a C5-20 cycloalkyl group; a C6-20 aryl group; and a C6-20 aryl group having at least one substituent selected from the group consisting of a halogen atom, a C1-10 halogenated alkyl group, \u2014Si(R)(R\u2032)(R\u2033), a C1-10 alkyl group, a C1-10 alkoxy group, a C6-10 aryl group, a C4-10 heteroaryl group, and \u2014N(R)(R\u2032);
Ar1, Ar2, Ar3 and Ar4 are independently a hydrogen; a C1-20 linear or branched alkyl group; a C5-20 cycloalkyl group; a C6-20 aryl group; and a C6-20 aryl group having at least one substituent selected from the group consisting of a halogen atom, a C1-10 halogenated alkyl group, \u2014Si(R)(R\u2032)(R\u2033), a C1-10 alkyl group, a C-1-10 alkoxy group, a C6-10 aryl group, a C4-10 heteroaryl group and \u2014N(R)(R\u2032) or at least one selected from the group consisting of Ar1 and Ar2, and Ar3 and Ar4 are joined together to form a fused ring structure with the N to which they are attached; and
R, R\u2032 and R\u2033 are independently selected from the group consisting of a hydrogen atom, a C1-10 alkyl group, a C1-10 alkoxy group, a C6-10 aryl group and a C4-10 heteroaryl group.
2. The biphenyl derivative of claim 1, wherein in formula 1, \u2014N(Ar1)(Ar2) andor \u2014N(Ar3)(Ar4) are independently a group represented by formula 2:
wherein:
X is a single bond or \u2014(CH2)n\u2014, where n is an integer of 1\u02dc2, \u2014C(R3)(R4)\u2014, \u2014CH\u2550CH\u2014, \u2014S\u2014, \u2014O\u2014 or \u2014Si(R3)(R4)\u2014;
A1, A2, A3, A4, A5, A6, A7, A8, R3, and R4, are independently a hydrogen atom; a C1-20 linear or branched alkyl group; a C5-20 cycloalkyl group; a C5-20 aryl group; and a C5-20 aryl group having at least one substituent selected from the group consisting of a halogen atom, a C1-10 halogenated alkyl group, \u2014Si(R)(R\u2032)(R\u2033), a C1-10 alkyl group, a C1-10 alkoxy group, a C6-10 aryl group, a C4-10 heteroaryl group and \u2014N(R)(R\u2032), at least one selected from the group consisting of A1 and A2, A2 and A3, A3 and A4, A5 and A6, A6 and A7, and A7 and A8 being interconnected, respectively; and
R, R\u2032 and R\u2033 are independently selected from the group consisting of a hydrogen, a C1-10 alkyl group, a C1-10 alkoxy group, a C6-10 aryl group and a C4-10 heteroaryl group.
3. The biphenyl derivative of claim 2, wherein the group represented by formula (2) is one selected from the group consisting of groups (2a) through (2h):
wherein:
A1, A2, A3, A4, A5, A6, A7, A8, R3 and R4 are independently a hydrogen atom; a C1-20 linear or branched alkyl group; a C5-20 cycloalkyl group; a C5-20 aryl group; and a C5-20 aryl group having at least one substituent selected from the group consisting of a halogen atom, a C1-10 halogenated alkyl group, \u2014Si(R)(R\u2032)(R\u2033), a C1-10 alkyl group, a C1-10 alkoxy group, a C6-10 aryl group, a C4-10 heteroaryl group and \u2014N(R)(R\u2032), at least one selected from the group consisting of A1 and A2, A2 and A3, A3 and A4, A5 and A6, A6 and A7, and A7 and A8 being interconnected, respectively; and
R, R\u2032 and R\u2033 are independently selected from the group consisting of a hydrogen, a C1-10 alkyl group, a C1-10 alkoxy group, a C6-10 aryl group and a C4-10 heteroaryl group.
4. The biphenyl derivative of claim 1, wherein in formula 1, \u2014N(Ar1)(Ar2) andor \u2014N(Ar3)(Ar4) are independently a group represented by formula 3:
wherein R5 and R6 are independently a hydrogen; a C1-20 linear or branched alkyl group; a C5-20 cycloalkyl group; a C5-20 aryl group; and a C5-20 aryl group having at least one substituent selected from the group consisting of a halogen atom, a C1-10 halogenated alkyl group, \u2014Si(R)(R\u2032)(R\u2033), a C1-10 alkyl group, a C1-10 alkoxy group, a C6-10 aryl group, a C4-10 heteroaryl group and \u2014N(R)(R\u2032), R, R\u2032 and R\u2033 being independently selected from the group consisting of a hydrogen, a C1-10 alkyl group, a C1-10 alkoxy group, a C6-10 aryl group and a C4-10 heteroaryl group.
5. The biphenyl derivative of claim 4, wherein in formula 3, R5 and R6 are independently a group represented by formula 4:
wherein B1, B2, B3, B4 and B5 are independently a hydrogen; a C1-20 linear or branched alkyl group; a C5-20 cycloalkyl group; a C6-20 aryl group; and a C6-20 aryl group having at least one substituent selected from the group consisting of a halogen atom, a C1-10 halogenated alkyl group, \u2014Si(R)(R\u2032)(R\u2033), a C1-10 alkyl group, a C1-10 alkoxy group, a C6-10 aryl group, a C4-10 heteroaryl group and \u2014N(R)(R\u2032), R, R\u2032 and R\u2033 being independently selected from the group consisting of a hydrogen, a C1-10 alkyl group, a C1-10 alkoxy group, a C6-10 aryl group, and a C4-10 heteroaryl group.
6. The biphenyl derivative of claim 1, wherein the compound represented by formula 1 is at least one selected from the group consisting of compounds represented by formulas 1a through 1e;.
7. An organic EL device comprising an organic layer positioned between a pair of electrodes, the organic layer containing the biphenyl derivative of any one of claims 1 through 6.
8. The organic EL device of claim 7, wherein the organic layer is an emissive layer or a hole blocking layer.
9. The organic EL device of claim 7, wherein the organic layer is an emissive layer, the emissive layer comprising 70 to 99.9% by weight of the biphenyl derivative and 0.1 to 30% by weight of a dopant.