1461135105-a1ab86b9-2460-4c17-96f9-eaea8af83341

1. A remote control apparatus, comprising:
a user input unit comprising a plurality of buttons and a sensor configured to sense a movement of the remote control apparatus;
a communication unit configured to communicate with an external apparatus; and
a controller configured to transmit a signal via the communication unit in response to sensing the movement of the remote control apparatus through the sensor and to control an operation state of the sensor based on information received from the external apparatus via the communication unit in response to transmitting the signal to the external apparatus,
wherein the received information is a response signal related to the signal transmitted to the external apparatus.
2. The remote control apparatus of claim 1, wherein the information received from the external apparatus indicates that the external apparatus is connected to another external apparatus.
3. The remote control apparatus of claim 2, further comprising a display, wherein a predetermined mode is a power saving mode to inactivate the display.
4. The remote control apparatus of claim 1, wherein the controller is further configured to determine whether the external apparatus is connected to another external apparatus based on the information received from the external apparatus, and change the operation state of the sensor to a predetermined state if it is determined that the external apparatus is connected to another external apparatus.
5. The remote control apparatus of claim 4, wherein the predetermined state is a power saving state.
6. The remote control apparatus of claim 5,
wherein if video information is received from the external apparatus through the communication unit when the sensor is in the power saving state, the controller is configured to set the sensor to an active state.
7. The remote control apparatus of claim 1, further comprising:
a display;
wherein the controller, when video information is received from the external apparatus through the communication unit, displays the received video information on the display.
8. The remote control apparatus of claim 1, wherein a predetermined state is one of a plurality of operation states setting power consumption of the remote control apparatus,
wherein the controller is further configured to set the operation state to a first state when the external apparatus is turned on, set the operation state to a second state when a user command is not input for a predetermined time while the external apparatus is connected to another external apparatus or the external apparatus is turned on, and set the operation state to a third state when the external apparatus is turned off, and
wherein the second state consumes less power than the first state, and consumes more power than the third state.
9. The remote control apparatus of claim 8, wherein the first state is an active operation state where the remote control apparatus is activated as a whole, the third state is a sleep state where only a power button of the remote control apparatus is activated, and the second state is an idle state where the power button and a button related to communication and the sensor are activated.
10. The remote control apparatus of claim 1, wherein the controller controls the sensor to operate in either an active state or power saving state according to the information received from the external apparatus.
11. The remote control apparatus of claim 10, wherein the signal is transmitted in response to an information through the user input unit, and the controller controls the communication unit to change from a power saving state to an active state, for transmitting the signal to the external apparatus.
12. The remote control apparatus of claim 10, wherein when a user command in not input from the user input unit for a predetermined time while the sensor operates in an active mode, the controller controls the sensor to operate in a power saving mode.
13. The remote control apparatus of claim 1, wherein the controller controls the communication unit to transmit a user command input through the user input unit to the external apparatus, and to set an operation mode of the remote control apparatus to a predetermined mode according to the information received from the external apparatus, the information being related to a state of the external apparatus.
14. A method for setting a mode of a remote control apparatus communicably linked to an external apparatus, the method comprising:
transmitting a signal to the external apparatus in response to a sensor of the remote control apparatus sensing a movement of the remote control apparatus;
receiving information from the external apparatus in response to the transmitting the signal to the external apparatus; and
setting an operation state of the sensor of the remote control apparatus based on the information, in which the sensor is to sense the movement of the remote control apparatus,
wherein the information is a response signal related to the signal transmitted to the external apparatus.
15. The method of claim 14, wherein the setting comprises:
determining whether the external apparatus is connected to another external apparatus based on the received information; and
setting the operation state of the sensor to a predetermined state if it is determined that the external apparatus is connected to another external apparatus.
16. The method of claim 15, wherein the predetermined state is a power saving state.
17. The method of claim 14, further comprising if the remote control apparatus receives video information from the external apparatus when the remote control apparatus is in a power saving state, setting the sensor to an active state.
18. The method of claim 14, further comprising if video information is received from the external apparatus, displaying the received video information on a display of the remote control apparatus.
19. The method of claim 14, wherein the predetermined state is one of a plurality of operation states setting power consumption of the remote control apparatus,
wherein the setting the operation state comprises setting the operation state to a first state when the external apparatus is turned on, setting the operation state to a second state when a user command is not input for a predetermined time while the external apparatus is connected to
another external apparatus or the external apparatus is turned on, and setting the operation state to a third state when the external apparatus is turned off, and
wherein the second state consumes less power than the first state, and consumes more power than the third state.
20. The method of claim 19, wherein the first state is an active operation state where the remote control apparatus is activated as a whole, the third state is a sleep state where only a power button of the remote control apparatus is activated, and the second state is an idle state where the power button and a button related to communication and the sensor are activated.
21. A broadcast receiving apparatus, comprising:
a communication unit comprising a wireless communication unit configured to communicate with a remote control apparatus; and
a controller configured to control the wireless communication unit to transmit, to the remote control apparatus, information in response to receiving a signal via the communication unit, to set an operation state of the remote control apparatus to a predetermined state according to the information,
wherein the communication unit receives the signal which is transmitted in response to a sensor of the remote control apparatus sensing movement of the remote control apparatus, and
wherein the information is a response signal related to the signal received from the remote control apparatus.
22. The broadcast receiving apparatus of claim 21, wherein in response to the broadcast receiving apparatus being connected to an external apparatus, the
controller is configured to transmit the information regarding the state of the broadcast receiving apparatus to set the operation state of the remote control apparatus to the predetermined state.
23. The broadcast receiving apparatus of claim 22, wherein the predetermined state is a power saving state.
24. The broadcast receiving apparatus of claim 23, wherein the controller is configured to transmit video information to set the remote control apparatus to an active state when the remote control apparatus is in the power saving state.
25. The broadcast receiving apparatus of claim 21, wherein the controller is configured to transmit video information to display on a display of the remote control apparatus.
26. A non-transitory computer readable recording medium having recorded thereon a program that causes a remote control apparatus to execute a method for setting a state of the remote control apparatus communicably linked to an external apparatus, the method comprising:
transmitting a signal to the external apparatus in response to a sensor of the remote control apparatus sensing a movement of the remote control apparatus;
receiving by the remote control apparatus information from the external apparatus; and
setting an operation state of the sensor of the remote control apparatus based on the information received from the external apparatus in response to the transmitting the signal to the external apparatus, in which the sensor is to sense a movement of the remote control apparatus,
wherein the information is a response signal related to the signal transmitted to the external apparatus.
27. The non-transitory computer readable recording medium of claim 26, wherein the setting comprises:
determining whether the external apparatus is connected to another external apparatus based on the received information; and
setting an operation state of the remote control apparatus to a predetermined state if it is determined that the state apparatus is connected to another external apparatus.
28. The non-transitory computer readable recording medium of claim 27, wherein the predetermined state is a power saving state.
29. The non-transitory computer readable recording medium of claim 27, further comprising if the remote control apparatus receives video information from the external apparatus when the remote control apparatus is in the power saving state, setting the sensor of the remote control apparatus to an active state.
30. The non-transitory computer readable recording medium of claim 26, further comprising if video information is received from the external apparatus, displaying the received video information on a display of the remote control apparatus.

The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.

1. N-Aryl-4,5-diaminopyrazole of formula (I) or a physiologically compatible salt thereof of an organic or inorganic acid
wherein
R1 and R2 independently of each other denote a hydrogen atom, a straight-chain or branched C1-C6-alkyl group, a hydroxyl group, a straight-chain or branched C1-C6-monohydroxyalkyl group, a straight-chain or branched C3-C6-dihydroxyalkyl group, a straight-chain or branched C1-C6-alkoxy group, a strait-chain or branched C1-C6-hydroxyalkoxy group, a straight-chain or branched C3-C6-dihydroxyalkoxy group, an amino group, a C1-C4-monoalkylamino group, a di(C1-C4)-alkylamino group, a C1-C4-aminoalkyl group, a halogen atom, a difluoromethyl group or a trifluoromethyl group;
Y stands for a nitrogen atom, or a C\u2014R3 group, wherein C is a carbon atom of the aromatic ring and R3 is a hydrogen atom, a halogen atom, a straight-chain or branched C1-C6-alkyl group, a straight-chain or branched C1-C6-hydroxyalkyl group, a straight-chain or branched C2-C6-alkoxy group, a straight-chain or branched C2-C6-hydroxyalkoxy group or a straight-chain or branched C2-C6-alkoxyalkoxy group;
X denotes an acid radical and n has a value from 0 to 3;
provided that when Y stands for a C\u2014R3 group, at least one of the R1, R2 and R3 groups is different from hydrogen.
2. N-Aryl-4,5-diaminopyrazole according to claim 1, characterized in that in formula (I) R1 and R2 independently of each other denote hydrogen, a methyl group, an ethyl group, an isopropyl group, an amino group or a methoxy group; and Y stands for a C\u2014H group, a C\u2014Cl group, a C-methyl group or a C-ethyl group and, in particular, a nitrogen atom, and when Y stands for a C\u2014H group at least one of the R1 and R2 groups does not denote hydrogen.
3. N-Aryl-4,5-diaminopyrazole according to claim 1, characterized in that it is a salt of sulfuric acid, hydrochloric acid, citric acid or tartaric acid.
4. N-Aryl-4,5-diaminopyrazole according to characterized in that it is selected from among 1-(2-methylphenyl)-4,5-diamino-1H-pyrazole dihydrochloride, 1-(3-methylphenyl)-4,5-diamino-1H-pyrazole dihydrochloride, 1-(4-methylphenyl)-4,5-diamino-1H-pyrazole dihydrochloride, 1-(2,4-dimethylphenyl)-4,5-diamino-1H-pyrazole dihydrochloride, 1-(2,5-dimethylphenyl)-4,5-diamino-1H-pyrazole dihydrochloride, 1-(2-ethylphenyl)-4,5-diamino-1H-pyrazole dihydrochloride, 1-(4-isopropylphenyl)-4,5-diamino-1H-pyrazole dihydrochloride, 1-(4-methoxylphenyl)-4,5-diamino-1H-pyrazole dihydrochloride, 1-(4-aminophenyl)-4,5-diamino-1H-pyrazole sulfate (1:1), 1-(4-chlorophenyl)-4,5-diamino-1H-pyrazole sulfate (2:1) and 1-(2-pyridinyl)-4,5-diamino-1H-pyrazole dihydrochloride.
5. Colorant for oxidative dyeing of keratin fibers, characterized in that it contains at least one N-aryl-4,5-diaminopyrazole according to.
6. Colorant according to claim 5, characterized in that it contains the N-aryl-4,5-diaminopyrazole in an amount from 0.005 to 20 weight percent.
7. Colorant according to claim 5, characterized in that additionally it contains other dye components from the group consisting of developers, couplers, 4-(2,5-diaminobenzylamino)aniline, 3-(2,5-diaminobenzylamino)aniline, natural dyes, dyes identical to natural ones and synthetic direct dyes.
8. Ready-for-use colorant for oxidative dyeing of keratin fibers, characterized in that it is obtained by mixing a colorant according to with an oxidant in a weight ratio from 5:1 to 1:3.
9. Colorant according to claim 8, characterized in that the ready-for-use oxidative colorant has a pH from 3 to 11.
10. Colorant according to, characterized in that it is a hair colorant.

1461135082-a83d4d82-44a4-4b37-85db-5eaef067cb93

1. A packaged, presulfided catalyst useful to hydrogenate hydrocarbon resin without an in situ sulfiding step, comprising:
porous catalyst particles comprising a supported metal catalyst structure comprising an internal pore volume with presulfided interstitial surfaces;
about 20 wt. % of a low molecular weight hydrocarbon resin, based on the weight of the supported metal catalyst structure, filling from 90 to 95 percent of the pore volume to improve a crush strength of the catalyst particles; and
an air-tight, transportable container housing the discrete catalyst particles in an inert atmosphere.
2. A method to hydrogenate hydrocarbon resin, comprising:
preparing catalyst particles comprising a supported metal catalyst structure comprising an internal pore volume with oxidized interstitial surfaces;
sulfiding the supported metal catalyst structure to form presulfided interstitial surfaces;
in an inert atmosphere, contacting the presulfided catalyst particles with about 20 wt. % percent of a low molecular weight hydrocarbon resin, based on the weight of the presulfided catalyst particles, to fill from 90 to 95 percent of the pore volume and improve a crush strength of the catalyst particles;
optionally screening the resin-filled catalyst particles to remove fines;
sealing the resin-filled catalyst particles in an air-tight, transportable container housing the discrete catalyst particles in an inert atmosphere;
loading the resin-filled catalyst particles from the container into a catalyst bed in a hydrogenation reactor; and
immediately (without a separate in situ sulfiding step) contacting the catalyst bed with an unsaturated hydrocarbon resin under hydrogenation conditions to hydrogenate the unsaturated hydrocarbon resin.

The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.

1. An aromatic amine derivative represented by the following general formula (1):
wherein A1 to A4 each independently represents a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted aryl group having 5 to 50 ring carbon atoms, a substituted or unsubstituted aralkyl group having 6 to 50 ring carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, a substituted or unsubstituted alkoxyl group having 1 to 50 ring carbon atoms, a substituted or unsubstituted aryloxy group having 5 to 50 ring carbon atoms, a substituted or unsubstituted arylamino group having 5 to 50 ring carbon atoms, a substituted or unsubstituted alkylamino group having 1 to 20 carbon atoms, a substituted or unsubstituted heterocyclic group having 3 to 50 ring carbon atoms, a substituted or unsubstituted silyl group having 3 to 50 carbon atoms or a halogen atom;
a, b, c and d each independently represents an integer of 0 to 5, when a, b, c or d each is 2 or greater, A1 to A4 may be the same with or different from each other, and may bond each other to form a saturated or unsaturated ring; and further, a couple of A1 and A2, and a couple of A3 and A4 may bond each other to form a saturated or unsaturated ring;
R1 to R4 each independently represents a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted aryl group having 5 to 50 ring carbon atoms, a substituted or unsubstituted aralkyl group having 6 to 50 ring carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms, a substituted or unsubstituted arylamino group having 5 to 20 ring carbon atoms, a substituted or unsubstituted alkylamino group having 1 to 20 carbon atoms, a substituted or unsubstituted heterocyclic group having 3 to 50 ring carbon atoms or a substituted or unsubstituted silyl group having 3 to 50 carbon atoms; a couple of R1 and R2, and a couple of R3 and R4 may bond each other to form a saturated or unsaturated ring;
however, a case where all of R1 to R4 in the general formula (1) are hydrogen atoms is excluded.
2. The aromatic amine derivative according to claim 1, wherein at least one of R1 or R3 in the general formula (1) independently represents a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted aryl group having 5 to 50 ring carbon atoms, a substituted or unsubstituted aralkyl group having 6 to 50 ring carbon atoms or a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms.
3. The aromatic amine derivative according to claim 1, wherein R1 and R3 in the general formula (1) each independently represents a substituted or unsubstituted alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted aryl group having 5 to 50 ring carbon atoms, a substituted or unsubstituted aralkyl group having 6 to 50 ring carbon atoms or a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms.
4. The aromatic amine derivative according to claim 1, wherein at least one of R2 or R4 in the general formula (1) independently represents a substituted or unsubstituted primary alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted secondary alkyl group having 1 to 50 carbon atoms, a substituted or unsubstituted aryl group having 5 to 50 ring carbon atoms, a substituted or unsubstituted aralkyl group having 1 to 50 ring carbon atoms or a substituted or unsubstituted cycloalkyl group having 3 to 50 ring carbon atoms.
5. The aromatic amine derivative according to claim 1, wherein R1 to R4 in the general formula (1) each independently represents a hydrogen atom, a substituted or unsubstituted arylamino group having 5 to 20 ring carbon atoms, a substituted or unsubstituted alkylamino group having 1 to 20 carbon atoms, a substituted or unsubstituted heterocyclic group having 3 to 50 ring carbon atoms or a substituted or unsubstituted silyl group having 3 to 50 carbon atoms.
6. The aromatic amine derivative according to claim 1, wherein A1 to A4 each independently represents a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 5 to 20 ring carbon atoms, a substituted or unsubstituted aralkyl group having 6 to 20 ring carbon atoms, a substituted or unsubstituted cycloalkyl group having 5 to 12 ring carbon atoms, a substituted or unsubstituted alkoxyl group having 1 to 6 ring carbon atoms, a substituted or unsubstituted aryloxy group having 5 to 18 ring carbon atoms, a substituted or unsubstituted arylamino group having 5 to 18 ring carbon atoms, a substituted or unsubstituted alkylamino group having 1 to 6 carbon atoms, a substituted or unsubstituted heterocyclic group having 3 to 20 ring carbon atoms, a substituted or unsubstituted silyl group having 3 to 20 carbon atoms or a halogen atom;
a, b, c and d each independently represents an integer of 0 to 2, when a, b, c or d each is 2 or greater, A1 to A4 may be the same with or different from each other, and may bond each other to form a saturated or unsaturated ring; and further, a couple of A1 and A2, and a couple of A3 and A4 may bond each other to form a saturated or unsaturated ring;
R1 to R4 each independently represents a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 5 to 20 ring carbon atoms, a substituted or unsubstituted aralkyl group having 6 to 20 ring carbon atoms, a substituted or unsubstituted cycloalkyl group having 5 to 12 ring carbon atoms, a substituted or unsubstituted arylamino group having 5 to 18 ring carbon atoms, a substituted or unsubstituted alkylamino group having 1 to 10 carbon atoms, a substituted or unsubstituted heterocyclic group having 3 to 20 ring carbon atoms or a substituted or unsubstituted silyl group having 3 to 20 carbon atoms; a couple of R1 and R2, and a couple of R3 and R4 may bond each other to form a saturated or unsaturated ring;
however, a case where all of R1 to R4 in the general formula (1) are hydrogen atoms is excluded.
7. The aromatic amine derivative according to claim 1, wherein the alkyl group represented by R2 and R4 in the general formula (1) are primary or secondary.
8. The aromatic amine derivative according to claim 1, wherein at least one of R1 or R3 in the general formula (1) represents a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, a s-butyl group, a t-butyl group or a cyclohexyl group.
9. The aromatic amine derivative according to claim 1, wherein at least one of R2 or R4 in the general formula (1) represents a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, a s-butyl group, a t-butyl group or a cyclohexyl group.
10. The aromatic amine derivative according to claim 1, which is represented by the following formula:
11. The aromatic amine derivative according to claim 1, which is represented by the following formula:
12. The aromatic amine derivative according to claim 1, which is represented by the following formula:
13. The aromatic amine derivative according to claim 1, which is represented by the following formula:
14. The aromatic amine derivative according to claim 1, which is represented by the following formula:
15. The aromatic amine derivative according to claim 1, which is represented by the following formula:
16. The aromatic amine derivative according to claim 1, which is represented by the following formula:
17. The aromatic amine derivative according to claim 1, which is represented by the following formula: