1. A knee joint prosthesis comprising:
a femoral component having an anterior side, a posterior side, a pair of laterally spaced condylar portions, and an intercondylar portion joining the condylar portions and including a recess;
a cam surface located adjacent the intercondylar recess on the anterior side of the femoral component, the cam surface having a saddle shape and being defined by an at least substantially concave first radius of curvature and a convex third radius of curvature that is perpendicular to the concave first radius of curvature; and
a tibial component including a platform having an upper surface that includes first and second laterally spaced concavities, each adapted for receiving one condylar portion of the femoral component and a tibial post for reception in the intercondylar recess of the femoral component, the tibial post having a saddle shaped anterior cam surface that is complementary to the saddle shaped anterior cam surface of the femoral component and is defined by an at least substantially convex second radius of curvature and a concave fourth radius of curvature that is perpendicular to the convex second radius of curvature; wherein the convex second radius of curvature of the tibial component is less than the concave first radius of curvature of the femoral component;
wherein the saddle shaped anterior cam surface of the tibial post mates with the saddle shaped cam surface of the femoral component in an articulating manner in approximately 10 degrees of hyperextension of the knee.
2. The knee joint prosthesis of claim 1, wherein the convex second radius of curvature is 95% or less of the concave first radius of curvature.
3. The knee joint prosthesis of claim 1, wherein the convex second radius of curvature is 90% or less of the concave first radius of curvature.
4. The knee joint prosthesis of claim 1, wherein the convex third radius of curvature is between about 29% to about 42% of the concave fourth radius of curvature.
5. The knee joint prosthesis of claim 1, wherein the intercondylar portion includes an arcuate shaped roof and has a box angle of greater than 20\xb0 as measured from the roof to a plane parallel to a nominal base plane.
6. The knee joint prosthesis of claim 1, wherein the saddle shaped anterior cam surface of the tibial post is formed at an inferior part thereof.
7. The knee joint prosthesis of claim 1, wherein each of the spaced condylar portions has a surface that is convexly curved antero-posteriorly to match generally a lateral profile of an anatomical femoral condyle and convexly curved laterally throughout its antero-posterior extent.
8. The knee joint prosthesis of claim 1, wherein each of the at least substantially convex second radius of curvature of the anterior cam surface of the tibial post and the at least substantially concave first radius of curvature of the intercondylar portion of the femoral component includes a flat formed along the radius, each flat being positioned so that they contact one another when the two components mate with one another.
9. The knee joint prosthesis of claim 1, wherein
the intercondylar portion has an arcuate shaped roof and an angle of the intercondylar portion, as measured from the roof, to a horizontal plane, which is parallel to a base (ground) plane, is greater than 25\xb0 .
10. The knee joint prosthesis of claim 9, wherein the arcuate shaped roof is configured to be inserted into an arcuate shaped notch formed in the femur by removing bone.
11. The knee joint prosthesis of claim 9, wherein the angle of the intercondylar portion is between about 20\xb0 to about 35\xb0.
12. A knee joint prosthesis comprising:
a femoral component having an anterior side, a posterior side, a pair of laterally spaced condylar portions, and an intercondylar portion joining the condylar portions and including a recess;
a cam surface located adjacent the intercondylar recess on the anterior side of the femoral component, the cam surface being defined by an at least substantially concave first radius of curvature; and
a tibial component including a platform having an upper surface that includes first and second laterally spaced concavities, each adapted for receiving one condylar portion of the femoral component and a tibial post for reception in the intercondylar recess of the femoral component, the tibial post having an anterior cam surface defined by an at least substantially convex second radius of curvature;
wherein the first and second radiuses of curvature are different from one another to create a mismatch between the radii to encourage that the contact between the tibial and femoral component occurs at a center region of the tibial post instead of at lateral edges thereof;
wherein the intercondylar portion includes an arcuate shaped roof that extends between a pair of tangent side walls and has a box angle of greater than 20\xb0 as measured from the roof to a plane parallel to a nominal base plane, the intercondylar portion being configured so as to permit reception into and mating with a femur box notch formed in a femur bone, the femur box notch being defined by a rounded top surface and a pair of parallel side walls so as to permit the arcuate shaped roof to seat against the rounded top surface and the side walls of the intercondylar portion to seat against the side walls of the femur box notch.
13. A knee joint prosthesis comprising:
a femoral component having an anterior side, a posterior side, a pair of laterally spaced condylar portions, and an intercondylar portion joining the condylar portions and including a recess, the intercondylar portion having an arcuate shaped roof;
a cam surface located adjacent the intercondylar recess on the anterior side of the femoral component, the cam surface having a saddle shape and being defined by an at least substantially concave first radius of curvature and a convex third radius of curvature that is perpendicular to the concave first radius of curvature; and
a tibial component including a platform having an upper surface that includes first and second laterally spaced concavities, each adapted for receiving one condylar portion of the femoral component and a tibial post for reception in the intercondylar recess of the femoral component, the tibial post having a saddle shaped anterior cam surface that is complementary to the saddle shaped anterior cam surface of the femoral component and is defined by an at least substantially convex second radius of curvature and a concave fourth radius of curvature that is perpendicular to the convex second radius of curvature; wherein the convex second radius of curvature of the tibial component is less than the concave first radius of curvature of the femoral component;
wherein the saddle shaped anterior cam surface extends to an inferior part of the cam surface of the tibial post and is in articulating contact with the saddle shaped cam surface of the femoral component, the arcuate shaped roof of the intercondylar portion being configured to be inserted into an arcuate shaped notch formed in the femur by removing bone, with the intercondylar portion being received between and placed in contact with two parallel side walls that define the acuate shaped notch.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
1. A solution for use in reducing the volatility of urea fertilizers comprising N-(n-butyl)-thiophosphoric triamide (NBPT) dissolved in a buffered reaction mixture of an amino alcohol having the formula 1\u2014(H)x\u2014N\u2014((CH2)m\u2014OH)n where m is 1-3, x is 0 or 1, and n is 2 when x is 1 and 3 when x is 0 or the formula 2\u2014(H)y\u2014N\u2014((CH2)\u2014CHOH\u2014CH3)z such that the length of the carbon chain where the secondary hydroxyl group is located is 3, y is 0 or 1, and z is 2 when y is 1 and 3 when y is 0, and a carboxylic acid having 6 or fewer carbon atoms to form an NBPT solution, said buffered reaction mixture containing the ammonium ion of said amino alcohol, the carboxylate ion of said carboxylic acid, and said amino alcohol, and having a pH of 8 to 10.
2. The solution of claim 1, wherein said amino alcohol is selected from the group consisting of diethanolamine, dipropanolamine, triethanolamine, tripropanolamine, diisopropanolamine, triisopropanolamine, and mixtures thereof.
3. The solution of claim 1, wherein from about 15% to about 30% by weight NBPT is dissolved in said buffered reaction mixture.
4. The solution of claim 1, further including a co-solvent.
5. The solution of claim 4, wherein said co-solvent is ethylene glycol or propylene glycol.
6. The solution of claim 1, wherein said solution is diluted with water.
7. The solution of claim 1, wherein the pH of said buffered reaction mixture is from 9 to 10.
8. The solution of claim 1, wherein said carboxylic acid is selected from the group consisting of acetic acid, propionic acid, butyric acid, valeric acid, caproic acid, and mixtures thereof.
9. The solution of claim 1, wherein said amino alcohol has a pKa of between about 7.5 and 10 and said carboxylic acid has a pKa of 5 or less.
10. A solution for use in reducing the volatility of urea fertilizers comprising N-(n-butyl)-thiophosphoric triamide (NBPT) dissolved in a buffered reaction mixture of an amino alcohol selected from the group consisting of diethanolamine, dipropanolamine, triethanolamine, tripropanolamine, diisopropanolamine, triisopropanolamine, and mixtures thereof, and a carboxylic acid having 6 or fewer carbon atoms to form an NBPT solution, said buffered reaction mixture containing the ammonium ion of said amino alcohol, the carboxylate ion of said carboxylic acid, and said amino alcohol, and having a pH of 8 to 10.
11. The solution of claim 10, wherein the pH of said buffered reaction mixture is from 9 to 10.
12. The solution of claim 10, further including a co-solvent.
13. The solution of claim 10, wherein said carboxylic acid is selected from the group consisting of acetic acid, propionic acid, butyric acid, valeric acid, caproic acid, and mixtures thereof.
14. The solution of claim 10, wherein said amino alcohol has a pKa of between about 7.5 and 10 and said acid has a pKa of 5 or less.
15. A solution for use in reducing the volatility of urea fertilizers comprising N-(n-butyl)-thiophosphoric triamide (NBPT) dissolved in a buffered reaction mixture of an amino alcohol having the formula 1\u2014(H)x\u2014N\u2014((CH2)m\u2014OH)n where m is 1-3, x is 0 or 1, and n is 2 when x is 1 and 3 when x is 0 or the formula 2\u2014(H)y\u2014N\u2014((CH2)\u2014CHOH\u2014CH3)z such that the length of the carbon chain where the secondary hydroxyl group is located is 3, y is 0 or 1, and z is 2 when y is 1 and 3 when y is 0, and a carboxylic acid having 6 or fewer carbon atoms selected from the group consisting of acetic acid, propionic acid, butyric acid, valeric acid, caproic acid, and mixtures thereof, to form an NBPT solution, said buffered reaction mixture containing the ammonium ion of said amino alcohol, the carboxylate ion of said carboxylic acid, and said amino alcohol, and having a pH of 8 to 10.
16. The solution of claim 15, wherein the pH of said buffered reaction mixture is from 9 to 10.
17. The solution of claim 15, further including a co-solvent.
18. The solution of claim 15, wherein said amino alcohol has a pKa of between about 7.5 and 10 and said carboxylic acid has a pKa of 5 or less.