1. A pneumatic tire for a construction vehicle having a tread divided into a central area and two side areas located at both sides of the central area in a tire width direction, and a plurality of lug grooves arranged in each of the side areas, wherein
the central area is provided with a central narrow groove continuously extending along the tire circumferential direction in a zigzag form and formed by alternately connecting a first inclined groove portion extending at a predetermined angle with respect to a tire circumferential direction and a second inclined groove portion extending at an opposite angle to the first inclined groove portion with respect to the tire circumferential direction;
each of the side areas is provided with a side narrow groove passing through a tire width direction inner side portion of each of the lug grooves and extending in the tire circumferential direction;
the tire width direction inner side portion of each of the lug grooves is arranged to face a proximate joint portion of joint portions of the first inclined groove portion and the second inclined groove portion in the tire width direction;
a width direction narrow groove is provided between the tire width direction inner side portion of each of the lug grooves and the proximate join portion; and,
the central narrow groove, the side narrow grooves and the width direction narrow groove define a plurality of polygonal block land portions having five or more sides in the tread portion, the block land portions being lined in the tire circumferential direction to form two block arrays arranged next to each other.
2. The pneumatic tire for a construction vehicle according to claim 1, wherein
a groove depth of the central narrow groove is 60% or more of a groove depth of each of the lug grooves.
3. The pneumatic tire for a construction vehicle according to claim 1, wherein
an amplitude of an extending shape of the central narrow groove is in the range of 5% to 30% of the tread width.
4. The pneumatic tire for a construction vehicle according to claim 1, wherein
the first inclined groove portion extends at an angle in the range of 20\xb0 to 50\xb0 with respect to the tire circumferential direction.
5. The pneumatic tire for a construction vehicle according to claim 1, wherein
the second inclined groove portion extends at an angle in the range of \u221220\xb0 to \u221250\xb0 with respect to the tire circumferential direction.
6. The pneumatic tire for a construction vehicle according to claim 1, wherein
a groove width of the central narrow groove is in the range of 3% to 8% of an arrangement pitch of the block land portions.
7. The pneumatic tire for a construction vehicle according to claim 1, wherein,
under the condition of the tire being contact with the road surface, opposed groove walls of the first inclined groove portion and the second inclined groove portion of the central narrow groove and the width direction narrow groove are brought into contact with each other, and opposed groove walls of the side narrow grooves are not brought into contact with each other.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
1. A fire retardant polymer composition comprising:
a polymer material;
a plurality of monomers of a polycondensed partially hydrolyzed chelated metal oxide precursor; and
at least one flame retardant constituent.
2. The fire retardant polymer composition of claim 1, wherein said polymer material comprises at least one of an acrylic, an unsaturated polyester, a saturated polyester, an alkyd, a vinyl ester, a polyurethane, an epoxy, a phenol, an urea-aldehyde, a polyvinyl aromatic, a maleimide, a polyvinyl halide, a polyolefin, a polyorganosiloxane, an amino resin, a polyamide, a polyimide, a polyetherimide, a polyphenylene sulfide, an aromatic polysulfone, a polyamideimide, a polyesterimide, a polyesteramideimide, a polyvinyl acetal, a fluorinated polymer, and a polycarbonate.
3. The fire retardant polymer composition of claim 1, wherein said polycondensed partially hydrolyzed chelated metal oxide precursor comprises at least one of a transition metal, an alkaline earth metal and a metallic element from Groups 3A, 4A and 5A of the periodic table of elements.
4. The fire retardant polymer composition of claim 1, wherein said polycondensed partially hydrolyzed chelated metal oxide precursor comprises at least one of aluminum, antimony, bismuth, calcium, chromium, magnesium, tin, titanium, zinc, and zirconium.
5. The fire retardant polymer composition of claim 1, wherein the polycondensed partially hydrolyzed chelated metal oxide precursor comprises a multifunctional compound containing at least one chelating group coordinated to at least one of an alkaline earth metal, a transition metal, a Group 3A metal, a Group 4A metal and a Group 5A metal.
6. The fire retardant polymer composition of claim 1, wherein the polycondensed partially hydrolyzed chelated metal oxide precursor comprises a multifunctional compound selected from the group comprising alkoxylated diamines, aminoalkylphosphonic acid, amino tris(methylene phosphonic acid), citric acid, diethylenetriamine pentaacetic acid, ethylenediaminetetraacetic acid, gluconic acid, glucoheptonoic acid, hexamethylenediamine tetra(methylene phosphonic acid), 2-(methacryloyloxy)ethyl acetoacetate, 5-(methacryloyloxy)methyl salicylic acid, 4-methacryloylamino salicylic acid, hydroxyethyl salicylate, hydroxyethyl salicylamide, 2-(2-hydroxy ethoxy) phenol, o-hydroxybenzoylacetone, 5-hydroxy-2-(hydroxymethyl)-4H-pyran-4-one, N-hydroxyethylenediaminetriacetic acid, hydroxyethylidene diphosphonic acid, hydroxyethane diphosphonic acid, nitrilotriacetic acid, sorbitol, tolyltrizole, o-hydroxybenzoylacetone, 2-hydroxydibensoylmethane, N-(acetoacetyl)glycine, acetylacetone, poly(ethylene glycol) methacrylate, and poly(propylene glycol) methacrylate.
7. The fire retardant polymer composition of claim 1, wherein the polycondensed partially hydrolyzed chelated metal oxide precursor comprises a supplemental multifunctional compound selected from the group comprising acetylacetone, poly(ethylene glycol) methacrylate, poly(propylene glycol) methacrylate, salicylic acid, 3-hydroxy-2-methyl-4-pyrone, and 8-hydroxyquinolone.
8. The fire retardant polymer composition of claim 1, wherein said at least one flame retardant constituent comprises at least one of a halogen-based, a phosphorous-based, a nitrogen-based and a sulfur-based flame retardant constituent.
9. The fire retardant polymer composition of claim 1, further comprising at least one of a blowing agent, a fibrous reinforcing material, a pigment, a mold release agent, a thermoplastic polymeric material, an elastomeric polymeric material, a shrink control agent, a wetting agent, an antifoam agent, a surface treatment agent, a surface treatment agent, and a thickener.
10. The fire retardant polymer composition of claim 1, wherein said fire retardant polymer composition is transparent.
11. A process for making a flame retardant polymer composition comprising the steps of:
contacting a polymer material with a metal oxide sol comprising a liquid and a condensation product of a partially hydrolyzed chelated metal oxide precursor to form a mixture;
contacting said polymer material with at least one flame retardant constituent; and
at least one of polymerizing and solidifying said polymer material.
12. The process of claim 11, the process further comprising the step of selecting said polymer material from the group comprising an acrylic, an unsaturated polyester, a saturated polyester, an alkyd, a vinyl ester, a polyurethane, an epoxy, a phenol, an urea-aldehyde, a polyvinyl aromatic, a maleimide, a polyvinyl halide, a polyolefin, a polyorganosiloxane, an amino resin, a polyamide, a polyimide, a polyetherimide, a polyphenylene sulfide, an aromatic polysulfone, a polyamideimide, a polyesterimide, a polyesteramideimide, a polyvinyl acetal, a fluorinated polymer, and a polycarbonate.
13. The process of claim 11, the process further comprising the step of formulating said metal oxide sol by contacting a metal oxide precursor with a multifunctional compound.
14. The process of claim 13, the process further comprising the step of selecting said metal oxide precursor from the group comprising at least one of a transition metal, an alkaline earth metal and a metallic element from Groups 3A, 4A and 5A of the periodic table of elements.
15. The process of claim 13, the process further comprising the step of selecting said multifunctional compound from the group comprising alkoxylated diamines, aminoalkylphosphonic acid, amino tris(methylene phosphonic acid), citric acid, diethylenetriamine pentaacetic acid, ethylenediaminetetraacetic acid, gluconic acid, glucoheptonoic acid, hexamethylenediamine tetra(methylene phosphonic acid), 2-(methacryloyloxy)ethyl acetoacetate, 5-(methacryloyloxy)methyl salicylic acid, 4-methacryloylamino salicylic acid, hydroxyethyl salicylate, hydroxyethyl salicylamide, 2-(2-hydroxy ethoxy) phenol, o-hydroxybenzoylacetone, 5-hydroxy-2-(hydroxymethyl)-4H-pyran-4-one, N-hydroxyethylenediaminetriacetic acid, hydroxyethylidene diphosphonic acid, hydroxyethane diphosphonic acid, nitrilotriacetic acid, sorbitol, tolyltrizole, o-hydroxybenzoylacetone, 2-hydroxydibensoylmethane, N-(acetoacetyl)glycine, acetylacetone, poly(ethylene glycol) methacrylate, and poly(propylene glycol) methacrylate.
16. The process of claim 13, the process further comprising the step of formulating said metal oxide sol by contacting said metal oxide precursor with a supplemental multifunctional compound, said supplemental multifunctional compound selected from the group comprising acetylacetone, poly(ethylene glycol) methacrylate, poly(propylene glycol) methacrylate, salicylic acid, 3-hydroxy-2-methyl-4-pyrone, and 8-hydroxyquinolone.
17. The process of claim 11, the process further comprising the step of removing said liquid from said mixture prior to the step of at least one of polymerizing and solidifying said polymer material.
18. The process of claim 11, the process further comprising the step of removing said liquid from said mixture after the step of at least one of polymerizing and solidifying said polymer material.
19. The process of claim 11, wherein said step of combining said mixture with at least one flame retardant constituent comprises selecting said at least one flame retardant constituent from the group comprising a halogen-based, a phosphorous-based, a nitrogen-based and a sulfur-based flame retardant constituent.
20. The process of claim 11, the process further comprising the step of contacting said mixture with at least one ingredient selected from the group comprising a blowing agent, a fibrous reinforcing material, a pigment, a mold release agent, a thermoplastic polymeric material, an elastomeric polymeric material, a shrink control agent, a wetting agent, an antifoam agent, a surface treatment agent, and a thickener.
21. The process of claim 11, wherein said step of contacting said polymer material with at least one flame retardant constituent is performed after said step of contacting said polymer material with a metal oxide sol.
22. A fire retardant polymer foam composition comprising:
a polymer material;
a plurality of monomers of a polycondensed partially hydrolyzed chelated metal oxide precursor;
a flame retardant constituent; and
a blowing agent.
23. The fire retardant polymer foam composition of claim 22, wherein said polymer material comprises polyurethane.
24. The fire retardant polymer foam composition of claim 22, wherein said partially hydrolyzed chelated metal oxide precursor comprises at least one of a transition metal, an alkaline earth metal and a metallic element from Groups 3A, 4A and 5A of the periodic table of elements.
25. The fire retardant polymer foam composition of claim 24, wherein said partially hydrolyzed chelated metal oxide precursor comprises at least one of aluminum, antimony, bismuth, calcium, chromium, magnesium, tin, titanium, zinc and zirconium.
26. The fire retardant polymer foam composition of claim 22, wherein the partially hydrolyzed chelated metal oxide precursor comprises a multifunctional compound containing at least one chelating group coordinated to at least one of an alkaline earth metal, a transition metal, a Group 3A metal, a Group 4A metal and a Group 5A metal.
27. The fire retardant polymer foam composition of claim 22, wherein the partially hydrolyzed chelated metal oxide precursor comprises a multifunctional compound selected from the group comprising alkoxylated diamines, aminoalkylphosphonic acid, amino tris(methylene phosphonic acid), citric acid, diethylenetriamine pentaacetic acid, ethylenediaminetetraacetic acid, gluconic acid, glucoheptonoic acid, hexamethylenediamine tetra(methylene phosphonic acid), 2-(methacryloyloxy)ethyl acetoacetate, 5-(methacryloyloxy)methyl salicylic acid, 4-methacryloylamino salicylic acid, hydroxyethyl salicylate, hydroxyethyl salicylamide, 2-(2-hydroxy ethoxy) phenol, o-hydroxybenzoylacetone, 5-hydroxy-2-(hydroxymethyl)-4H-pyran-4-one, N-hydroxyethylenediaminetriacetic acid, hydroxyethylidene diphosphonic acid, hydroxyethane diphosphonic acid, nitrilotriacetic acid, sorbitol, tolyltrizole, o-hydroxybenzoylacetone, 2-hydroxydibensoylmethane, N-(acetoacetyl)glycine, acetylacetone, poly(ethylene glycol) methacrylate, and poly(propylene glycol) methacrylate.
28. The fire retardant polymer foam composition of claim 22, wherein said at least one flame retardant constituent comprises at least one of a halogen-based, a phosphorous-based, a nitrogen-based and a sulfur-based flame retardant constituent.