1. A silica powder surface-treated with an epoxy compound having a plurality of epoxy groups, wherein
at least one of the epoxy groups of the epoxy compound is ring-opened and bound to the surface of the silica powder, and
at least a portion of the remaining epoxy groups of the epoxy compound are reacted and bound to an amine compound.
2. The silica powder according to claim 1, wherein the remaining epoxy groups of the epoxy compound are reacted and bound to an amine compound.
3. The silica powder according to claim 1, wherein the epoxy compound has a molecular weight ranging from 200 to 1000.
4. The silica powder according to claim 1, wherein the epoxy compound contains no metal and has a molecular weight ranging from 200 to 1000.
5. The silica powder according to claim 1, wherein the silica powder has a primary mean particle size ranging from 5 to 50 nm.
6. The silica powder according to claim 1, wherein the amine compound is aliphatic and contains at least one nitrogen atom.
7. The silica powder according to claim 1, which has a specific surface area ranging from 50 to 380 m2g.
8. The silica powder according to claim 1, which has an amine group equivalent ranging from 6.0106 to 1.2102 molg.
9. The silica powder according to claim 1, wherein the epoxy compound is selected from the group consisting of glycerol triglycidyl ether, glycerol diglycidyl ether, diglycerol polyglycidyl ether, polypropylene glycol diglycidyl ether, ethylene glycol diglycidyl ether, trimethylolpropane polyglycidyl ether, neopentyl glycol diglycidyl ether, and polyethylene glycol diglycidyl ether.
10. The silica powder according to claim 1, wherein the amine compound is selcted from the group consisting of diethylamine, diethanolamine, N-methylethanolamine, ethylenediamine, diethylenetriamine, and tetraethylenepentamine.
11. A method for producing a silica powder, comprising surface-treating a silica powder with an epoxy compound having a plurality of epoxy groups and an amine compound.
12. The method for producing a silica powder according to claim 11, wherein said surface-treating comprises:
adding dropwise or spraying a liquid solution containing the epoxy compound to or onto the silica powder, wherein the silica powder is kept in a fluidized state;
heating the silica powder to a temperature from 90 to 200 C. to produce a primary product;
adding dropwise or spraying a liquid solution containing the amine compound to or onto the primary product, wherein the primary product is kept in a fluidized state; and
heating the primary product to a temperature from 90 to 200 C.
13. The method for producing a silica powder according to claim 12, wherein the liquid solution containing the epoxy compound is prepared by dissolving the epoxy compound in a first solvent and the liquid solution containing the amine compound is prepared by dissolving the amine compound in a second solvent.
14. The method for producing a silica powder according to claim 13, wherein the first solvent and the second solvent are independently selected from the group consisting of acetone, hexane, toluene, chloroform, diisopropyl ether, tetrahydrofuran, and mixtures thereof.
15. The method for producing a silica powder according to claim 11, wherein the method comprises:
adding dropwise or spraying both a liquid solution containing the epoxy compound having a plurality of epoxy groups and a liquid solution containing the amine compound to or onto a silica powder which is kept in a fluidized state simultaneously; and heating the silica powder, which has been added dropwise or sprayed with both the epoxy compound and the amine compound, in a fluidized state to a temperature from 90 to 200 C.
16. The method for producing a silica powder according to claim 15, wherein the liquid solution containing the epoxy compound is prepared by dissolving the epoxy compound in a first solvent and the liquid solution containing the amine compound is prepared by dissolving the amine compound in a second solvent.
17. The method for producing a silica powder according to claim 16, wherein the first solvent and the second solvent are independently selected from the group consisting of acetone, hexane, toluene, chloroform, diisopropyl ether, tetrahydrofuran, and mixtures thereof.
18. The method for producing a silica powder according to claim 11, wherein the surface treatment of the silica powder is performed with the epoxy compound in an amount of 0.1 to 60 parts by weight and the amine compound in an amount of 0.1 to 50 parts by weight, both based on 100 parts by weight of the silica powder.
19. The method for producing a silica powder according to claim 15, wherein the surface treatment of the silica powder is performed with the epoxy compound in an amount of 0.1 to 60 parts by weight and the amine compound in an amount of 0.1 to 50 parts by weight, both based on 100 parts by weight of the silica powder.
20. The method for producing a silica powder according to claim 11, wherein the epoxy compound (1) has at least two epoxy groups, (2) contains no metal, and (3) has a molecular weight ranging from 200 to 1000.
21. The method for producing a silica powder according to claim 15, wherein the epoxy compound (1) has at least two epoxy groups, (2) contains no metal, and (3) has a molecular weight ranging from 200 to 1000.
22. The method for producing a silica powder according to claim 11, wherein the surface treatment of the silica powder or the primary product is carried out in an inert gas atmosphere.
23. The method for producing a silica powder according to claim 15, wherein the surface treatment of the silica powder or the primary product is carried out in an inert gas atmosphere.
24. The method for producing a silica powder according to claim 11, wherein the surface treatment of the silica powder and the primary product is carried out in an inert gas atmosphere.
25. The method for producing a silica powder according to claim 15, wherein the surface treatment of the silica powder and the primary product is carried out in an inert gas atmosphere.
26. The method for producing a silica powder according to claim 11, wherein the epoxy compound is selected from the group consisting of glycerol triglycidyl ether, glycerol diglycidyl ether, diglycerol polyglycidyl ether, polypropylene glycol diglycidyl ether, ethylene glycol diglycidyl ether, trimethylolpropane polyglycidyl ether, neopentyl glycol diglycidyl ether, and polyethylene glycol diglycidyl ether.
27. The method for producing a silica powder according to claim 11, wherein
the amine compound is selected from the group consisting of diethylamine, diethanolamine, N-methylethanolamine, ethylenediamine, diethylenetriamine, and tetraethylenepentamine; and
the epoxy compound is selected from the group consisting of glycerol triglycidyl ether, glycerol diglycidyl ether, diglycerol polyglycidyl ether, polypropylene glycol diglycidyl ether, ethylene glycol diglycidyl ether, trimethylolpropane polyglycidyl ether, neopentyl glycol diglycidyl ether, and polyethylene glycol diglycidyl ether.
28. The method for producing a silica powder according to claim 15, wherein
the amine compound is selected from the group consisting of diethylamine, diethanolamine, N-methylethanolamine, ethylenediamine, diethylenetriamine, and tetraethylenepentamine; and
the epoxy compound is selected from the group consisting of glycerol triglycidyl ether, glycerol diglycidyl ether, diglycerol polyglycidyl ether, polypropylene glycol diglycidyl ether, ethylene glycol diglycidyl ether, trimethylolpropane polyglycidyl ether, neopentyl glycol diglycidyl ether, and polyethylene glycol diglycidyl ether.
29. A surface-modified silica powder produced by the method according to claim 11.
30. A surface-modified silica powder produced by the method according to claim 15.
31. A method of ink printing, comprising contacting an ink with a substrate comprising the surface-modified silica powder of claim 1.
32. A method of ink printing, comprising contacting an ink with a substrate comprising the surface-modified silica powder of claim 29.
33. A method of ink printing, comprising contacting an ink with a substrate comprising the surface-modified silica powder of claim 30.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
1. A gas turbine combustion system, comprising:
a combustor comprising a combustion chamber, the combustion chamber comprising one or more fluid channels to introduce air into at least one of a primary zone and an intermediate zone, the primary zone being enclosed by and defined by a domed portion of the combustor;
an a dual channel injector in fluid communication with the combustion chamber and configured to discharge fuel into the primary zone, the injector comprising an a first fuel channel, a second fuel channel, a plurality of air swirler ports, and an atomizer,
wherein the plurality of swilrer ports are configured to receive compressor airflow,
wherein the plurality of swirler ports are disposed circumferentially about the second fuel channel, and
wherein the swirler ports are configured to discharge to turbulent air flow in response to fuel being supplied through the first fuel channel and the second fuel channel to the atomizer; and
an igniter coupled to the combustion chamber, wherein the igniter is configured to ignite a fuel air mixture provided by the injector in the combustion chamber.
2. The gas turbine combustion system of claim 1, wherein the injector is configured to provide the fuel air mixture in the primary zone.
3. The gas turbine combustion system of claim 1, wherein the igniter is located adjacent to the primary zone.
4. The gas turbine combustion system of claim 1, wherein the injector comprises a first fuel channel and a second fuel channel.
5. The gas turbine combustion system of claim 1, wherein fuel is delivered to the combustion chamber through the first fuel channel in response to a starting operation.
6. The gas turbine combustion system of claim 1, wherein the atomizer is a diffuser.
7. The gas turbine combustion system of claim 6, wherein the diffuser is configured to discharge a mist of fuel.
8. The gas turbine combustion system of claim 7, wherein the air handler is an air swirler.
9. The gas turbine combustion system of claim 8, wherein the air swirler is configured to discharged a biased air flow that mixes with the mist of fuel.
10. A gas turbine combustor, comprising:
a combustion chamber including a primary zone and an intermediate zone, the primary zone being enclosed by and defined by a domed portion of the combustion chamber, the combustion chamber further comprising a first hole in fluid communication with the primary zone and a second hole in fluid communication with the intermediate zone;
an igniter coupled to the combustion chamber, the igniter configured to generate a spark in the primary zone; and
an injector coupled to the combustion chamber, and the injector configured to provide a fuel-air mist in the primary zone,
the injector comprising,
a first fuel channel, a second fuel channel, a plurality of air swirler ports, and an atomizer,
the air handler is in fluid communication with the swilrer ports,
the plurality of swirler ports are disposed circumferentially about the second fuel channel, and
the swirler ports are configured to discharge to turbulent air flow in response to fuel being supplied through the first fuel channel and the second fuel channel to the atomizer.
11. The gas turbine combustor of claim 10, further comprising an annulus defined between the gas turbine combustor housing and the combustion chamber.
12. The gas turbine combustor of claim 11, wherein the annulus is configured to receive a fluid flow from a compressor.
13. The gas turbine combustor of claim 11, wherein the first hole and the second hole are in are in fluid communication with the annulus.
14. The gas turbine combustor of claim 10, wherein the injector comprises an air handler.
15. The gas turbine combustor of claim 14, wherein the injector comprises a fuel atomizer.
16. The gas turbine combustor of claim 15, wherein the air handler is configured to create at least one of a turbulent air flow and a rotating airflow.
17. The gas turbine combustor of claim 15, wherein fuel is exhausted as a mist from the fuel atomizer and mixed with air exhausted from the air handler to create the fuel-air mist.
18. An APU, comprising:
a combustor comprising,
a housing,
a combustion chamber contained within the housing, combustion chamber having a domed portion defining a primary zone, the combustion chamber comprising an injector comprising;
an injector body,
a first fuel channel disposed within the injector body,
a second fuel channel disposed within the injector body and about the first fuel channel,
an atomizer in fluid communication with and configured to exhaust fuel from the first fuel channel and the second fuel channel, and
a plurality of air swirler ports disposed circumferentially about the second fuel channel, the plurality of the air swirler ports are configured to discharge to turbulent air flow in response to fuel,
the injector configured to provide a fuel air mist to the combustion chamber and an igniter configured to ignite the fuel air mist, the combustion chamber comprising a first plurality of holes in fluid communication with a primary zone and a second plurality of holes in fluid communication with an intermediate zone,
a channel defined between the combustion chamber and the housing;
a compressor in fluid communication with the channel, wherein fluid from the compressor is conducted through the channel and to the first plurality of holes and the second plurality of holes of the combustion chamber.
19. The APU of claim 18, wherein the injector comprises an air handler and a fuel atomizer.
20. The APU of claim 18, wherein the injector is configured to provide the fuel air mist in a volume adjacent to the igniter to achieve light off.