1. A lead pin, comprising: a shaft portion; and
a connection head portion provided to a top end side of the shaft portion, and having a diameter which is larger than a diameter of the shaft portion; wherein the connection head portion includes a bonding surface on an opposite side to the shaft portion side, and the bonding surface includes a flat surface provided in a center part, and extends to a convex surface which is provided in substantially a first ring shape at an outer periphery of the flat surface such that the flat surface is continuous with and smoothly joins the convex surface, wherein a peripheral edge of the flat surface and an inside edge of the convex surface meet at an identical height position and the flat surface does not protrude from the convex surface, the convex surface having a rounded portion with a radius R in substantially a convex shape, the convex surface extending from the peripheral edge of the flat surface to an inclining surface which is provided in substantially a second ring shape at an outside of the convex surface and a height of the inclining surface is lowered toward an outside gradually, the inclining surface widening toward the outside gradually, and wherein a diameter of the flat surface is larger than a diameter of a shaft portion.
2. The lead pin according to claim 1, wherein the inclining surface is a concave surface having a rounded portion with a radius R2 in substantially a concave shape.
3. The lead pin according to claim 1, wherein the inclining surface is straight along a radial cross section.
4. The lead pin according to claim 1, wherein the radius R is set in a range of 0.5 H to H, when H is a thickness of the connection head portion.
5. A wiring substrate with lead pin, comprising:
the lead pin set forth in claim 1; and
a wiring substrate including a pin connection portion; wherein the connection head portion of the lead pin is connected to the pin connection portion of the wiring substrate via a solder layer.
6. The wiring substrate with lead pin, according to claim 5, wherein the wiring substrate includes a chip connection portion on an opposite surface to a surface on which the pin connection portion is provided, and a semiconductor chip is connected to the chip connection portion of the wiring substrate by a reflow soldering.
7. The wiring substrate with lead pin, according to claim 5, wherein the solder layer exists only on a bonding surface side of the connection head portion of the lead pin.
8. A method of manufacturing a wiring substrate with lead pin, comprising:
preparing the lead pin set forth in claim 1, and
a wiring substrate including a pin connection portion on one surface and a chip connection portion on the other surface;
connecting the connection head portion of the lead pin to the pin connection portion via a solder layer in a state such that the pin connection portion of the wiring substrate is directed upward; and
connecting a semiconductor chip to the chip connection portion by a reflow soldering in a state that the chip connection portion of the wiring substrate is directed upward, and simultaneously making the solder layer connecting the lead pin reflow in a state that the lead pin hangs in midair under the wiring substrate.
9. The method of manufacturing a wiring substrate with lead pin, according to claim 8, wherein, in the step of making the solder layer connecting the lead pin reflow, an inclination of the lead pin which is fitted with an inclined state from a perpendicular direction is corrected toward the perpendicular direction side based on a reflow of the solder layer and gravitation.
10. The lead pin according to claim 1, wherein the inclining surface is a concave surface or straight along a radial cross section.
11. The lead pin according to claim 1, wherein the height is a height along an axial direction of the shaft portion.
12. The lead pin according to claim 1, wherein the radius R is a radius of substantially a cross section of a toroidal shape.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
1-22. (canceled)
23. The process of claim 40, wherein said liquid plasticizer is selected from the group consisting of water; glycerol; propylene glycol; aqueous solutions of glycerol, propylene glycol, monosaccharides, and disaccharides; and invert and high fructose corn syrups.
24. The process of claim 40, wherein said liquid plasticizer is water.
25. The process of claim 40, further comprising cooling said extruded mixture.
26. The process of claim 40, wherein said encapsulate is selected from the group consisting of medications, pesticides, vitamins, preservatives, and flavoring agents.
27. The process of claim 40, wherein said encapsulate is a flavoring agent.
28. The process of claim 27, wherein said flavoring agent is selected from the group consisting of natural extracts, oleoresins, essential oils, protein hydrolysates, aqueous reaction flavors, compounded natural flavors, and artificial flavors.
29. The process of claim 27, wherein said flavoring agent comprises a plasticizer or an emulsifier.
30. The process of claim 40, wherein said extruder is a twin screw extruder.
31-39. (canceled)
40. A process for preparing an encapsulation composition, comprising:
(A) an encapsulate, encapsulated in:
(B) a glassy matrix, said matrix comprising:
60 to 99% by weight, based on the total weight of said matrix (B), of larch gum; and
1 to 40% by weight, based on the total weight of said matrix (B), of a low molecular weight carbohydrate or polyol, wherein said low molecular weight carbohydrate or polyol is selected from the group consisting of glucose, sucrose, maltose, lactose, 42 D.E. corn syrup solid, 36 D.E. corn syrup solid, erythritol, lactitol, mannitol, sorbitol, maltitol, isomalt, xylitol, hydrogenated corn syrup, hydrogenated glucose syrup, hydrogenated maltose syrup, hydrogenated lactose syrup, and a mixture thereof,
and wherein said glassy matrix has a glass transition temperature of from room temperature to 55.7\xb0 C.;
said process comprising:
(i) mixing matrix (B) with a liquid plasticizer and encapsulate (A) in an extruder, to obtain a melted mixture which comprises encapsulate (A) and matrix (B); and
(ii) extruding said melted mixture, to obtain an extruded mixture.
41. The process of claim 40, wherein said matrix (B) comprises:
60 to 80% by weight, based on the total weight of said matrix (B), of larch gum; and
20 to 40% by weight, based on the total weight of said matrix (B), of said low molecular weight carbohydrate or polyol.
42. The process of claim 40, wherein said glassy matrix has a glass transition temperature of from 30\xb0 C. to 55.7\xb0 C.
43. The process of claim 40, wherein said glassy matrix has a glass transition temperature of from 30\xb0 C. to 40\xb0 C.