1. A manufacturing method for an article of photo-curing compose resin, comprising:
providing a plastic article with an upper surface and a bottom surface, a photo-curing compose resin, an ink layer, and a plastic material;
coating the photo-curing compose resin on the upper surface of the plastic article;
pressing and curing the photo-curing compose resin to form a plurality of patterns;
shaping the plastic article with the patterns;
coating the ink layer on the bottom surface of the plastic article; and
injecting the plastic material to attach the plastic material with the ink layer.
2. The manufacturing method according to claim 1, wherein the plastic article is made of Polyethylene Terephthalate (PET), Polycarbonate (PC), Tri-acetyl Cellulose (TAC), Polymethylmethacrylate (PMMA), Methylmethacrylate (styrene), or Cyclic Olefin Copolymer (COC), and the thickness of the plastic article is from 10 \u03bcm to 1000 \u03bcm.
3. The manufacturing method according to claim 1, wherein the photo-curing compose resin has one of or more than one of full acrylate resin, polyester acrylate, epoxy acrylate and polyurethane acrylate from 5% to 95% of the photo-curing compose resin.
4. The manufacturing method according to claim 1, further comprising a dilution, the dilution has one monomer, the monomer includes one or more than one of monofunctional monomer, difunctional monomer, trifunctional monomer, and multifunctional monomer in 5% to 95% weight ratio of the photo-curing compose resin.
5. The manufacturing method according to claim 1, wherein the photo-curing compose resin further comprises one of or more than one of photo initiator, leveling agent, antifoam agent, and lubricant in 0.1% to 20% weight ratio of the photo-curing compose resin.
6. The manufacturing method according to claim 1, wherein the photo-curing compose resin further comprises one of or more than one of organic composite and inorganic composite in 0.1% to 50% weight ratio of the photo-curing compose resin.
7. The manufacturing method according to claim 1, wherein the photo-curing compose resin further comprises organic or inorganic micro particulates with diameter of 1 nm-100 \u03bcm, the organic or inorganic micro particulates are one kind of or more than one kinds of PMMA, Silica dioxide, Cerium dioxide, Aluminum trioxide, Zinc oxide, and Sodium oxide in 0.1% to 60% weight ratio of the photo-curing compose resin, and the particulates are distributed in the photo-curing compose resin.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
What is claimed is:
1. A recording material comprising a support having a recording layer thereon capable of forming a color with the application of heat andor pressure,
the material further comprising at least one layer containing acetoacetyl-modified polyvinyl alcohol and a hardening agent between the support and the recording layer; and wherein
the hardening agent is a compound having, in one molecule thereof, two or more vinyl groups adjacent to a substituent having a positive Hammett’s substituent constant p.
2. The recording material of claim 1, wherein the hardening agent is 2-ethylenesulfonyl-N-2-(2-ethylenesulfonyl-acetylamino)ethylacetamide.
3. The recording material of claim 1, wherein the acetoacetyl-modified polyvinyl alcohol has a polymerization degree of 1,000 or more.
4. The recording material of claim 2, wherein the acetoacetyl-modified polyvinyl alcohol has a polymerization degree of 1,000 or more.
5. The recording material of claim 1, wherein the layer containing the acetoacetyl-modified polyvinyl alcohol and the hardening agent further contains a lamellar inorganic compound.
6. The recording material of claim 2, wherein the layer containing the acetoacetyl-modified polyvinyl alcohol and the hardening agent further contains a lamellar inorganic compound.
7. The recording material of claim 3, wherein the layer containing the acetoacetyl-modified polyvinyl alcohol and the hardening agent further contains a lamellar inorganic compound.
8. The recording material of claim 5, wherein the lamellar inorganic compound is water swelling synthetic mica, and amass ratio (xy) of amass (x) of the acetoacetyl-modified polyvinyl alcohol and amass (y) of the water swelling synthetic mica is in a range of from 2 to 30.
9. The recording material of claim 6, wherein the lamellar inorganic compound is water swelling synthetic mica, and amass ratio (xy) of amass (x) of the acetoacetyl-modified polyvinyl alcohol and a mass (y) of the water swelling synthetic mica is in a range of from 2 to 30.
10. The recording material of claim 7, wherein the lamellar inorganic compound is water swelling synthetic mica, and amass ratio (xy) of a mass (x) of the acetoacetyl-modified polyvinyl alcohol and amass (y) of the water swelling synthetic mica is in a range of from 2 to 30.
11. The recording material of claim 1, wherein the support is a laminated support comprising a paper substrate having a polyolefin laminated on both surfaces thereof, and the layer containing the acetoacetyl-modified polyvinyl alcohol and the hardening agent is adjacent to the support.
12. The recording material of claim 2, wherein the support is a laminated support comprising a paper substrate having a polyolefin laminated on both surfaces thereof, and the layer containing the acetoacetyl-modified polyvinyl alcohol and the hardening agent is adjacent to the support.
13. The recording material of claim 3, wherein the support is a laminated support comprising a paper substrate having a polyolefin laminated on both surfaces thereof, and the layer containing the acetoacetyl-modified polyvinyl alcohol and the hardening agent is adjacent to the support.
14. The recording material of claim 5, wherein the support is a laminated support comprising a paper substrate having a polyolefin laminated on both surfaces thereof, and the layer containing the acetoacetyl-modified polyvinyl alcohol and the hardening agent is adjacent to the support.
15. The recording material of claim 8, wherein the support is a laminated support comprising a paper support having a polyolefin laminated on both surfaces thereof, and the layer containing the acetoacetyl-modified polyvinyl alcohol and the hardening agent is adjacent to the support.
16. The recording material of claim 1, wherein the recording layer comprises a plurality of layers forming yellow, magenta and cyan colors, respectively.
17. The recording material of claim 2, wherein the recording layer comprises a plurality of layers forming yellow, magenta and cyan colors, respectively.
18. The recording material of claim 3, wherein the recording layer comprises a plurality of layers forming yellow, magenta and cyan colors, respectively.
19. The recording material of claim 5, wherein the recording layer comprises a plurality of layers forming yellow, magenta and cyan colors, respectively.
20. The recording material of claim 8, wherein the recording layer comprises a plurality of layers forming yellow, magenta and cyan colors, respectively.