1. A method for preparing an arylsulfur pentafluoride having a formula (I) as follows:
the process comprising:
reacting an arylsulfur halotetrafluoride having a formula (II):
with hydrogen fluoride in the presence of additives to form the arylsulfur pentafluoride, in which at least two additives are selected from a group consisting of fluoride salts of formula, M+\u2212F(HF)n, non-fluoride salts of formula, M+Y\u2212, and organic compounds that have one or more unsaturated bonds in a molecule;
in which: R1, R2, R3, R4, and R5 each is independently a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group having 1 to 18 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, a nitro group, a cyano group, a substituted or unsubstituted alkanesulfonyl group having 1 to 18 carbon atoms, a substituted or unsubstituted arenesulfonyl group having 6 to 30 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 18 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 30 carbon atoms, a substituted or unsubstituted acyloxy group having from 1 to 18 carbon atoms, a substituted or unsubstituted alkanesulfonyloxy group having from 1 to 18 carbon atoms, a substituted or unsubstituted arenesulfonyloxy group having from 6 to 30 carbon atoms, a substituted or unsubstituted alkoxycarbonyl group having 2 to 18 carbon atoms, a substituted or unsubstituted aryloxycarbonyl group having 7 to 30 carbon atoms, a substituted carbamoyl group having 2 to 18 carbon atoms, a substituted amino group having 1 to 18 carbon atoms, or a SF5 group;
X is a chlorine atom, bromine atom, or iodine atom;
M is a metal atom, an ammonium moiety, or a phosphonium moiety;
n is 0 or a mixed number greater than 0; and
Y is an anion moiety whose conjugated acid, HY, is less than HX in acidity, and Y is not F(HF)n.
2. The method of claim 1 wherein the mol ratio of the arylsulfur halotetrafluoride to the total amount of the additives is in a range of about 1:0.1 to about 1:5.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
1. A light emission device comprising:
a first substrate and a second substrate facing each other to form a vacuum chamber;
a first electrode arranged on the first substrate in a first direction;
a second electrode arranged above the first electrode in a second direction crossing the first direction;
an insulation layer interposed between the first electrode and the second electrode;
an electron emission region electrically connected to one of the first electrode or the second electrode;
a phosphor layer arranged on the second substrate;
an anode electrode arranged on the phosphor layer; and
a ground electrode in the vacuum chamber,
wherein at least one of the first electrode or the second electrode is divided into a plurality of sub-electrodes,
wherein a driving error sub-electrode of the plurality of sub-electrodes is electrically separated from normally driving sub-electrodes of the plurality of sub-electrodes, and wherein the driving error sub-electrode of the plurality of sub-electrodes is electrically connected to the ground electrode.
2. The light emission device of claim 1, wherein a crossed region of the first electrode and the second electrode defines a unit pixel.
3. The light emission device of claim 1, wherein the driving error sub-electrode is physically separated from the normally driving sub-electrodes.
4. The light emission device of claim 1, wherein each of the plurality of sub-electrodes has a width ranging from about 0.1 to about 5 mm.
5. The light emission device of claim 1, wherein the first electrodes are divided into a plurality of sub-electrodes and the second electrodes are divided into a plurality of sub-electrodes, and wherein the plurality of sub-electrodes of the first electrode are equal in number to that of the plurality of sub-electrodes of the second electrode.
6. The light emission device of claim 1, wherein the electron emission regions are formed of a carbon-based material, a nanometer-sized material, or combinations thereof.
7. The light emission device of claim 1, wherein the driving error sub-electrode is a short circuited or damaged sub-electrode.
8. A display device comprising:
a light emission device; and
a panel assembly configured with the light emission device to display an image by receiving light emitted from the light emission device,
wherein the light emission device comprises:
a first substrate and a second substrate facing each other to form a vacuum chamber;
a first electrode arranged on the first substrate in a first direction;
a second electrode arranged in a second direction crossing the first direction with an insulation layer interposed between the first electrode and the second electrode;
an electron emission region electrically connected to one of the first electrode or the second electrode;
a phosphor layer arranged on the second substrate;
an anode electrode arranged on the phosphor layer; and
a ground electrode in the vacuum chamber,
wherein at least one of the first electrode or the second electrode is divided into a plurality of sub-electrodes,
wherein a driving error sub-electrode of the plurality of sub-electrodes is electrically separated from normally driving sub-electrodes of the plurality of sub-electrodes, and wherein the driving error sub-electrode of the plurality of sub-electrodes is electrically connected to the ground electrode.
9. The display device of claim 8, wherein the panel assembly includes a plurality of first pixels, and
wherein the light emission device includes a plurality of second pixels,
wherein the second pixels are less in number than that of the first pixels, and
wherein the second pixels allow for emitting different intensities of light at the second pixels.
10. The display device of claim 9, wherein the number of first pixels arranged in each row of the panel assembly is more than 240 and the number of first pixels arranged in each column of the panel assembly is more than 240.
11. The display device of claim 10, wherein the number of second pixels arranged in each row of the light emission device is within a range from 2 to 99 and the number of second pixels arranged in each column of the light emission device is within a range from 2 to 99.
12. The display device of claim 8, wherein a crossed region of the first electrode and the second electrode defines a unit pixel.
13. The display device of claim 12, wherein the driving error sub-electrode is physically separated from the normally driving sub-electrodes.
14. The display device of claim 8, wherein each of the plurality of sub-electrodes has a width ranging from about 0.1 to about 5 mm.
15. The display device of claim 8, wherein the first electrodes are divided into a plurality of sub-electrodes and the second electrodes are divided into a plurality of sub-electrodes, and wherein the plurality of sub-electrodes of the first electrode are equal in number to that of the plurality of sub-electrodes of the second electrode.
16. The display device of claim 8, wherein the electron emission regions are formed of a carbon-based material, a nanometer-sized material, or combinations thereof.
17. The display device of claim 8, wherein the driving error sub-electrode is a short circuited or damaged sub-electrode.