1. A hydrocarbon cracking catalyst in which a metal or a metal oxide selected from the group consisting of a rare earth metal, an oxide thereof, an alkaline earth metal and an oxide thereof is deposited only on the surface of zeolite, not present in the pores of the zeolite.
2. The hydrocarbon cracking catalyst of claim 1 in which the metal or metal oxide is deposited in the range of 0.1-20 wt % based on the weight of the carrier.
3. The hydrocarbon cracking catalyst of claim 1 in which the zeolite has a crystal structure of MFI, MEL, TPN, MTT or FER.
4. The hydrocarbon cracking catalyst of claim 1 in which the zeolite is HZSM-5 having an SiO2Al2O3 ratio of 15-200.
5. The hydrocarbon cracking catalyst of claim 1 in which the rare earth metal is selected from the group consisting of La, Ce and Pr and the alkaline earth metal is selected from the group consisting of Mg, Ca, Sr and Ba.
6. A method for preparing a hydrocarbon cracking catalyst comprising the steps of:
a) dissolving a metal-hydrocarbon complex or an organometal larger than the pore size of a zeolite carrier in an organic solvent;
b) depositing the resultant solution on the surface of zeolite; and
c) drying and calcining the resultant zeolite catalyst.
7. The method of claim 6 in which the hydrocarbon is selected from the group consisting of C4-C10 paraffinic, olefinic and aromatic hydrocarbons.
8. The method of claim 6 in which the metal-hydrocarbon complex or organometal is a complex of a rare earth metal or an alkaline earth metal and a hydrocarbon selected from the group consisting of lanthanum (III) 2-ethylhexanoate, calcium 2-ethylhexanoate, barium 2-ethylhexanoate, cerium 2-ethylhexanoate, yttrium 2-ethylhexanoate, strontium cyclohexane butylate and magnesium myristate.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
1. A method comprising:
forming a gate structure on a surface of a semiconductor substrate;
forming a sidewall spacer on the gate structure;
forming a recess within the semiconductor substrate adjacent the sidewall spacer;
modifying the recess within the semiconductor substrate such that the modified recess has a first portion that extends from the surface of the semiconductor substrate and a second portion that extends from the first portion at a first angle ranging from about 50\xb0 to about 70\xb0 and a third portion that extends from the surface of the semiconductor substrate and a fourth portion that extends from the third portion at a second angle ranging from about 50\xb0 to about 70\xb0, the second portion directly opposing the fourth portion, wherein the first and second angles are measured with respect to an axis that is parallel to the surface of the substrate, wherein the first portion is aligned with an outer edge of the sidewall spacer, wherein the outer edge of the sidewall spacer is further away from the gate structure than an inner edge of the sidewall spacer; and
depositing a semiconductor material into the modified recess, wherein the semiconductor material is different from the semiconductor substrate.
2. The method of claim 1, wherein a sidewall of the recess is aligned with the outer edge of the sidewall spacer.
3. The method of claim 1, wherein forming the recess within the semiconductor substrate adjacent the sidewall spacer includes performing a first dry etching process, and
wherein modifying the recess within the semiconductor substrate includes performing a second dry etching process that is different from the first dry etching process.
4. The method of claim 1, wherein forming the recess within the semiconductor substrate adjacent the sidewall spacer includes performing a dry etching process, and
wherein modifying the recess within the semiconductor substrate includes performing a wet etching process.
5. The method of claim 1, further comprising implanting an ion into the semiconductor substrate adjacent the sidewall spacer prior to forming the recess within the semiconductor substrate adjacent the sidewall spacer, and
wherein forming the recess within the semiconductor substrate adjacent the sidewall spacer includes removing a portion of the semiconductor substrate implanted with the ion.
6. The method of claim 1, wherein depositing the semiconductor material into the modified recess includes depositing the semiconductor material via an epitaxy process to form a raised sourcedrain region.
7. The method of claim 1, wherein forming the sidewall spacer on the gate structure includes:
depositing a first material layer over the semiconductor substrate and the gate structure,
depositing a second material layer over the first material layer, and
removing at least a portion of the first and second material layers to form the sidewall spacer.
8. A method comprising:
forming a gate structure on a surface of a semiconductor substrate;
forming a spacer on the gate structure;
forming a recess within the semiconductor substrate adjacent the spacer, the recess having an edge aligned with an outer edge of the spacer, the outer edge of the spacer being further away from the gate structure than an inner edge of the spacer;
modifying the recess within the semiconductor substrate such that the modified recess has a first vertical section that extends from the surface of the semiconductor substrate and a first tapered section that tapers from the first vertical section in a direction away from the surface of the semiconductor substrate and a second vertical section that extends from the surface of the semiconductor substrate and a second tapered section that tapers from the second vertical section in a direction away from the surface of the semiconductor substrate and towards the first tapered section, the second vertical section directly opposing the first vertical section, wherein the first vertical section extends along a first plane and the sidewall of the gate structure extends along a second plane that is parallel to the first plane, the first and second planes being spaced apart from each other; and
depositing a semiconductor material into the modified recess, wherein the semiconductor material is different from the semiconductor substrate.
9. The method of claim 8, forming the spacer on the gate structure includes:
depositing a first material layer over the semiconductor substrate and the gate structure,
depositing a second material layer over the first material layer, and
removing at least a portion of the first and second material layers to form the spacer.
10. The method of claim 9, wherein removing at least the portion of the first and second material layers to form the spacer includes completely removing the second material layer.
11. The method of claim 9, wherein after removing at least the portion of the first and second material layers, the sidewall spacer includes a remaining portion of the first and second material layers.
12. The method of claim 11, further comprising completely removing the remaining portion of the second material layer after depositing the semiconductor material into the modified recess.
13. The method of claim 9, wherein the first material layer is a pad oxide layer and the second material layer is a capping layer.
14. The method of claim 9, wherein the first vertical section directly underlies the spacer.
15. A method comprising:
forming a first transistor of a first type and a second transistor of a second type on a surface of a semiconductor substrate, wherein the first type is different than the second type, wherein the first transistor includes a first gate structure and the second transistor includes a second gate structure;
forming a protective layer over the first transistor;
forming a spacer on the second gate structure of the second transistor;
forming a recess within the semiconductor substrate adjacent the spacer on the second gate structure;
modifying the recess within the semiconductor substrate such that the modified recess has a first portion that extends from the surface of the semiconductor substrate and a second portion that extends from the first portion at a first angle ranging from about 50\xb0 to about 70\xb0 and a third portion that extends from the surface of the semiconductor substrate and a fourth portion that extends from the third portion at a second angle ranging from about 50\xb0 to about 70\xb0, the second portion directly opposing the fourth portion, wherein the first and second angles are measured with respect to an axis that is parallel to the surface of the substrate; and
depositing a semiconductor material into the modified recess, wherein the semiconductor material is different from the semiconductor substrate.
16. The method of claim 15, removing the protective layer over the first transistor prior to depositing the semiconductor material into the modified recess.
17. The method of claim 15, wherein the first transistor is an NMOS transistor and the second transistor is a PMOS transistor.
18. The method of claim 15, further comprising implanting an ion into the semiconductor substrate adjacent the spacer prior to forming the recess within the semiconductor substrate adjacent the spacer, and
wherein forming the recess within the semiconductor substrate adjacent the spacer includes removing a portion of the semiconductor substrate implanted with the ion.
19. The method of claim 15, wherein forming the recess within the semiconductor substrate adjacent the spacer includes performing a dry etching process, and
wherein modifying the recess within the semiconductor substrate includes performing a wet etching process.
20. The method of claim 15, wherein the semiconductor material includes silicon germanium (SiGe).