1. An assembly comprising:
a first member including a first end portion comprising:
a main body including a first diameter;
a male gland including a first length and a second diameter, wherein the first diameter is greater than the second diameter; and
a groove positioned between the main body and the male gland;
a spring-energized polymeric seal seated within the groove and including a third diameter; and
a second member including a boss face defining a female bore configured to mate with the male gland, the female bore comprising an angled wall defining a lead-in angle having a second length and a lead-in width;
wherein the first length is greater than or equal to the second length, and wherein a difference between the second and third diameters is less than or equal to the lead-in width of the female bore.
2. The assembly of claim 1, wherein the first end portion of the first member is a tubing fitting attached to the first member.
3. The assembly of claim 1, and further comprising:
a flange extending from the first end portion of the first member, the flange including a first aperture configured to receive a fastening apparatus;
a second aperture adjacent to the female bore of the second member and configured to receive the fastening apparatus.
4. The assembly of claim 1, wherein the first and second members are suitable for containing a fluid and are in fluidic communication with each other.
5. The assembly of claim 4, wherein the fluid is selected from a group consisting of: air, water, fuel, and oil.
6. A tube-fitting configured to mate with a first tube comprising an opening defined by an angled wall having an angle length and a lead-in width, the tube-fitting comprising:
a first portion comprising a first diameter;
a second portion adjacent to the first portion and comprising a second diameter and a first length;
a groove positioned between the first and second portions and configured to receive a sealing member,
wherein a difference between the first and second diameters is less than or equal to the lead-in width of the opening of the first tube, and wherein the first length is greater than or equal to the angle length of the opening of the first tube.
7. The tube-fitting of claim 6, wherein the sealing member is a spring-energized polymeric seal.
8. The tube-fitting of claim 6, wherein the first portion of the tube-fitting is configured to attach to a second tube.
9. The tube-fitting of claim 6, and further comprising:
a flange extending from the first portion of the tube-fitting, the flange including an aperture configured to receive a fastening apparatus.
10. The tube-fitting of claim 6, wherein the tube-fitting is suitable for use with a fluid delivery tubing assembly.
11. The tube-fitting of claim 10, wherein the fluid delivery tubing assembly delivers a fluid selected from a group consisting of: air, water, fuel, and oil.
12. A plumbing connection comprising:
a first tubular member comprising:
a first portion comprising a first diameter D1;
a second portion adjacent to the first portion, extending from a first end to a second end, and comprising a second diameter D2, wherein D2<D1;
a sealing member disposed at the first end of the second portion and between the first and second portions, and comprising a third diameter D3, wherein D3>D2 and (D3\u2212D2)=A; and
a first length B measured from the sealing member to the second end of the second portion;
a second tubular member defining a female bore including a sidewall having a length C and oriented at an angle \u25a1 with respect to a longitudinal axis of the female bore, wherein the second portion of the first tubular member is disposed within the female bore, the sealing member contacts the sidewall of the female bore, B\u2267C, and A\u2266(C\xd7tan \u03b8).
13. The plumbing connection of claim 12, wherein the sealing member is a spring-energized polymeric seal.
14. The plumbing connection of claim 12, and further comprising:
a flange extending from the first tubular member and attached to a boss face of the second tubular member.
15. The plumbing connection of claim 14, wherein the flange is attached to the boss face with a bolt.
16. The plumbing connection of claim 12, wherein the first and second tubular members contain a fluid.
17. The plumbing connection of claim 13, wherein the fluid is selected from a group consisting of: air, water, fuel, and oil.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
1. A compound comprising a 1-Methyl-3-dihalogenomethyl-5-halogenopyrazole(thio)benzofuranyl carboxamide of formula (I)
in which
Hal1 represents chlorine or fluorine;
Y represents chlorine, bromine, fluorine or hydrogen;
T represents an oxygen or sulfur atom;
Q represents hydrogen, C1-C6-alkylsulfonyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-haloalkylsulfonyl, halo-C1-C4-alkoxy-C1-C4-alkyl;
X represents halogen, nitro, cyano, C1-C12-alkyl; C1-C6-haloalkyl having 1 to 9 identical or different halogen atoms; C1-C6-alkoxy; C1-C6-haloalkoxy having 1 to 9 identical or different halogen atoms; C1-C6-alkylsulfanyl; C1-C6-haloalkylsulfanyl having 1 to 9 identical or different halogen atoms; C1-C6-alkylsulfonyl; C1-C6-haloalkylsulfonyl having 1 to 9 identical or different halogen atoms; C2-C12-alkenyl; C2-C12-alkynyl; C3-C7-cycloalkyl; phenyl; tri(C1-C8)alkylsilyl; tri(C1-C8)alkylsilyl-C1-C8-alkyl;
m represents 0, 1, 2 or 3;
R1, R2, R3 and R4 independently of one another represent hydrogen, halogen; nitro; cyano; hydroxyl; amino; sulfanyl, C1-C16-alkyl; C3-C8-cycloalkyl; (C3-C8-cycloalkyl)-C1-C8-alkyl; (C3-C8-cycloalkyl)-C3-C8-cycloalkyl; C2-C8-alkenyl; C2-C8-alkynyl; C2-C8-alkenyl-C1-C16-alkyl; C2-C8-alkynyl-C1-C16-alkyl; C1-C16-alkoxy; C3-C8-cycloalkyloxy; (C3-C8-cycloalkyl)-C1-C8-alkyloxy; C1-C8-alkylsulfanyl; C3-C8-cycloalkylsulfanyl; (C3-C8-cycloalkyl)-C1-C8-alkylsulfanyl; C2-C8-alkenyloxy; C3-C8-alkynyloxy; aryl-C1-C8-alkyloxy which is optionally substituted by up to 6 identical or different groups Rb; aryl-C1-C8-alkylsulfanyl which is optionally substituted by up to 6 identical or different groups Rb; aryloxy which is optionally substituted by up to 6 identical or different groups Rb; arylsulfanyl which is optionally substituted by up to 6 identical or different groups Rb; (C3-C8-cycloalkyl)-C2-C8-alkenyl; (C3-C8-cycloalkyl)-C2-C8-alkynyl; tri(C1-C8)alkylsilyl; tri(C1-C8)alkylsilyl-C1-C8-alkyl; aryl-C1-C8-alkyl which is optionally substituted by up to 6 identical or different groups Rb; aryl-C2-C8-alkenyl which is optionally substituted by up to 6 identical or different groups Rb; aryl-C2-C8-alkynyl which is optionally substituted by up to 6 identical or different groups Rb; C1-C8-alkylamino; di-C1-C8-alkylamino; arylamino which is optionally substituted by up to 6 identical or different groups Rb; C1-C8-alkylcarbonyl; C1-C8-alkylcarbonyloxy; C1-C8-alkylcarbonylamino; C1-C8-alkoxycarbonyl; C1-C8-alkyloxycarbonyloxy; C1-C8-alkylcarbamoyl; di-C1-C8-alkylcarbamoyl; C1-C8-alkylaminocarbonyloxy; di-C1-C8-alkylaminocarbonyloxy; N\u2014(C1-C8-alkyl)hydroxycarbamoyl; C1-C8-alkoxycarbamoyl; N\u2014(C1-C8-alkyl)-C1-C8-alkoxycarbamoyl; aryl-C1-C8-alkylamino which is optionally substituted by up to 6 identical or different groups Rb; (C1-C8-alkoxyimino)-C1-C8-alkyl; (C2-C8-cycloalkoxyimino)-C1-C8-alkyl; C1-C8-alkyliminoxy; C1-C8-alkyliminoxy-C1-C8-alkyl; each of which is optionally substituted;
provided that R1, R3 and R4 do not represent methyl at the same time when R2 represents hydrogen, m represents 0 and Y represents chlorine or fluorine; R1 and R2 can form together with the carbon to which they are attached a C3-C8-cycloalkyl; C3-C8-cycloalkenyl, or a saturated 5, 6 or 7 membered heterocycle; each of which is optionally substituted;
R3 and R4 can form together with the carbon to which they are attached a C3-C8-cycloalkyl; C3-C8-cycloalkenyl, or a saturated 5, 6 or 7 membered heterocycle; each of which is optionally substituted;
Rb represents halogen; nitro, cyano, C1-C12-alkyl; C1-C6-haloalkyl having 1 to 9 identical or different halogen atoms; C1-C6-alkoxy; C1-C6-haloalkoxy having 1 to 9 identical or different halogen atoms; C1-C6-alkylsulfanyl; C1-C6-haloalkylsulfanyl having 1 to 9 identical or different halogen atoms; C1-C6-alkylsulfonyl; C1-C6-haloalkylsulfonyl having 1 to 9 identical or different halogen atoms; C2-C12-alkenyl; C2-C12-alkynyl; C3-C7-cycloalkyl; phenyl; tri(C1-C8)alkylsilyl; tri(C1-C8)alkylsilyl-C1-C8-alkyl.
2. 1-Methyl-3-dihalogenomethyl-5-halogenopyrazole(thio)benzofuranyl carboxamide of formula (I) according to claim 1, wherein
Hal1 represents chlorine or fluorine;
Y represents chlorine, fluorine or hydrogen;
T represents an oxygen or sulfur atom;
Q represents hydrogen, C1-C4-alkylsulfonyl, C1-C3-alkoxy-C1-C3-alkyl, C1-C4-haloalkylsulfonyl, halo-C1-C3-alkoxy-C1-C3-alkyl having in each case 1 to 9 fluorine, chlorine andor bromine atoms;
X represents fluorine, chlorine, methyl or trifluoromethyl;
m represents 0, 1 or 2;
R1, R2, R3 and R4 independently of one another represent hydrogen, halogen; cyano; C1-C16-alkyl; C3-C8-cycloalkyl; (C3-C8-cycloalkyl)-C1-C8-alkyl; (C3-C8-cycloalkyl)-C3-C8-cycloalkyl; C2-C8-alkenyl; C2-C8-alkynyl; C2-C8-alkenyl-C1-C16-alkyl; C2-C8-alkynyl-C1-C16-alkyl; C1-C16-alkoxy; C3-C8-cycloalkyloxy; (C3-C8-cycloalkyl)-C1-C8-alkyloxy; C1-C8-alkylsulfanyl; C3-C8-cycloalkylsulfanyl; (C3-C8-cycloalkyl)-C1-C8-alkylsulfanyl; C2-C8-alkenyloxy; C3-C8-alkynyloxy; aryl-C1-C8-alkyloxy which is optionally substituted by up to 6 identical or different groups Rb; \u2014C1-C8-alkylsulfanyl which is optionally substituted by up to 6 identical or different groups Rb; aryloxy which is optionally substituted by up to 6 identical or different groups Rb; arylsulfanyl which is optionally substituted by up to 6 identical or different groups Rb; (C3-C8-cycloalkyl)-C2-C8-alkenyl; (C3-C8-cycloalkyl)-C2-C8-alkynyl; tri(C1-C8)alkylsilyl; tri(C1-C8)alkylsilyl-C1-C8-alkyl; aryl-C1-C8-alkyl which is optionally substituted by up to 6 identical or different groups Rb; aryl-C2-C8-alkenyl which is optionally substituted by up to 6 identical or different groups Rb; aryl-C2-C8-alkynyl which is optionally substituted by up to 6 identical or different groups Rb; each of which is optionally substituted; provided that R1, R3 and R4 do not represent methyl at the same time when R2 represents hydrogen;
provided that R1, R3 and R4 do not represent methyl at the same time when R2 represents hydrogen, m represents 0 and Y represents chlorine or fluorine
R1 and R2 can form together with the carbon to which they are attached an optionally substituted C3-C8-cycloalkyl;
R3 and R4 can form together with the carbon to which they are attached an optionally substituted C3-C8-cycloalkyl;
Rb represents halogen; nitro, cyano, C1-C8-alkyl; C1-C4-haloalkyl having 1 to 9 identical or different halogen atoms; C1-C6-alkoxy; C1-C4-haloalkoxy having 1 to 9 identical or different halogen atoms; C1-C6-alkylsulfanyl; C1-C4-haloalkylsulfanyl having 1 to 9 identical or different halogen atoms; C1-C6-alkylsulfonyl; C1-C4-haloalkylsulfonyl having 1 to 9 identical or different halogen atoms; C2-C8-alkenyl; C2-C8-alkynyl; C3-C6-cycloalkyl; phenyl; tri(C1-C6)alkylsilyl; tri(C1-C6)alkylsilyl-C1-C6-alkyl.
3. 1-Methyl-3-dihalogenomethyl-5-halogenopyrazole(thio)benzofuranyl carboxamide of formula (I) according to claim 1, wherein
Hal1 represents fluorine;
Y represents chlorine, bromine, fluorine or hydrogen;
T represents an oxygen or sulfur atom;
Q represents hydrogen, methylsulfonyl, ethylsulfonyl, n- or isopropylsulfonyl, n-, iso-, sec- or tert-butylsulfonyl, methoxymethyl, methoxyethyl, ethoxymethyl, ethoxyethyl, trifluoromethylsulfonyl, trifluoromethoxymethyl;
X represents fluorine, chlorine, methyl or trifluoromethyl, where fluorine, chlorine, methyl or trifluoromethyl is located in the 4-, 5- or 6-position of the benzofuranyl radical;
m represents 0 or 1;
R1, R2, R3 and R4 independently of one another represent hydrogen, fluorine, chlorine, bromine, iodine; C1-C12-alkyl; C3-C6-cycloalkyl; (C3-C6-cycloalkyl)-C1-C6-alkyl; (C3-C6-cycloalkyl)-C3-C6-cycloalkyl; C1-C12-alkoxy; C3-C6-cycloalkyloxy; (C3-C6-cycloalkyl)-C1-C6-alkyloxy; each of which is optionally substituted by up to 6 identical or different groups Rb; provided that R1, R3 and R4 do not represent methyl at the same time when R2 represents hydrogen;
R1 and R2 can form together with the carbon to which they are attached an optionally substituted cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl;
R3 and R4 can form together with the carbon to which they are attached an optionally substituted cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl;
Rb represents fluorine, chlorine, bromine; C1-C6-alkyl; C1-C4-haloalkyl having 1 to 9 identical or different halogen atoms; C1-C4-alkoxy; C1-C4-haloalkoxy having 1 to 9 identical or different halogen atoms; C1-C4-alkylsulfanyl; C1-C4-haloalkylsulfanyl having 1 to 9 identical or different halogen atoms; C1-C4-alkylsulfonyl; C1-C4-haloalkylsulfonyl having 1 to 9 identical or different halogen atoms; C2-C6-alkenyl; C2-C6-alkynyl; C3-C6-cycloalkyl; phenyl; tri(C1-C4)alkylsilyl; tri(C1-C4)alkylsilyl-C1-C4-alkyl.
4. Process for preparing a compound of formula (I) according to claim 1, wherein in a Process (a) one or more carbonyl halides or acids of formula (II)
in which X3 represents halogen or hydroxyl,
are reacted with one or more amines of formula (III)
if appropriate in the presence of a coupling agent, if appropriate in the presence of an acid binder and if appropriate in the presence of a diluent to obtain a compound of formula (I-a),
which is optionally reacted with a thionating agent and if appropriate in the presence of a catalytic or stoichiometric or more quantity of a base to obtain a compound of formula (I-b)
5. Method for controlling phytopathogenic harmful fungi, comprising applying a compound of formula (I) according to claim 1 to the phytopathogenic harmful fungi andor a habitat thereof.
6. Composition for controlling phytopathogenic harmful fungi, comprising a content of at least one compound of formula (I) according to claim 1, in addition to one or more extenders andor surfactants.
7. Composition according to claim 6 comprising at least one further active ingredient selected from the group consisting of insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides, growth regulators, herbicides, fertilizers, safeners and semiochemicals.
8. A compound of formula (I) according to claim 1 capable of being used for control of phytopathogenic harmful fungi.
9. Process for producing compositions for controlling phytopathogenic harmful fungi, comprising mixing a compound of the formula (I) according to claim 1 with one or more extenders andor surfactants.
10. A compound of formula (I) according to claim 1 capable of being used for treatment of one or more transgenic plants.
11. A compound of the formula (I) according to claim 1 capable of being used for treatment of seed and of seed of one or more transgenic plants.