1. A process for treating a solid material or a shaped body comprising at least one zeolite, and being at least partly crystalline, wherein said solid material or the shaped body is brought in contact with a composition comprising waters after at least one of the following steps of an integrated process for producing a solid material or a shaped body: (i) after step (II) of separating the at least partly crystalline solid material from its mother liquors or (ii) after step (S) of shaping said solid material into a shaped body, or (iii) after a step (C) of calcining said solid material or said shaped body.
2. The process according to claim 1, wherein the solid material is brought in contact with a composition comprising water at elevated temperatures with respect to room temperature.
3. The process according to claim 1, wherein the composition comprising water is selected from: deionized water, water vapor, steam, steam at elevated pressures relative to ambient pressure, supercritical water, aqueous solutions, or ammonia water.
4. The process according to claim 1, wherein the at least one zeolite comprises Ti.
5. The process according to claim 4, wherein the at least one zeolite comprising Ti is selected from materials of the structure classes MFI, MEL, MWW, BEA or combinations thereof.
6. The process according to claim 1, wherein the step of bringing the solid material or the shaped body in contact with a composition comprising water, is performed in a reactor that is used for the synthesis or treatment of the solid material, or in a reactor in which the solid material, or one or more shaped bodies made form the solid material, are used as catalysts in a chemical reaction.
7. An integrated process for the production of a solid material, comprising at least one zeolite, said process comprising at least the following steps:
(I) crystallizing, at least partially, at least one solid material comprising at least one zeolite, out of a synthesis mixture, resulting in mixture (I) comprising at least said solid material and a mother liquor;
(II) separating andor concentrating the solid material in mixture (I);
(W) contacting the solid material from step (II) with a composition comprising water;
(III) agglomerating or granulating or agglomerating and granulating the solid material from step (W);
wherein step (III) is optional.
8. The integrated process according to claim 7, further comprising, after step (W), separating the solid material from at least a part of the composition comprising water.
9. The integrated process according to claim 7, wherein the method of separating andor concentrating in step (II), is selected from the group consisting of: ultrafiltration, spray-drying, spray granulating, contacting inert support bodies with the synthesis solution from (I).
10. The integrated process for the production of a shaped body comprising at least one zeolite, said process comprising at least the following steps:
(I) crystallizing at least partially, at least one solid material comprising at least one zeolite, out of a synthesis mixture, resulting in mixture (I) comprising at least said solid material and a mother liquor;
(II) separating andor concentrating the solid material in mixture (I);
(W) contacting the solid material from step (II) with a composition comprising water,
(III) agglomerating or granulating or agglomerating and granulating the solid material from step (W);
wherein step (III) is optional, and wherein, after step (W), or after step (III), at least one step (S) of shaping the solid material into a shaped body is performed.
11. The integrated process according to claim 10, wherein the at least one step of shaping the solid material is selected from: pelletizing, pressing, extruding, sintering, roasting, or briquetting.
12. The integrated process according to claim 10, wherein the step (W) is performed after the step (S) of shaping the solid material is performed, and wherein said step (W), either replaces the step (W) performed after step (II), or is performed in addition to the step (W) performed after step (II).
13. The integrated process according to claim 7, further comprising, after at least one of the steps (II), (W) or (III), a step (C) of calcining the solid material andor a shaped body comprising said solid material.
14. The integrated process according to claim 13, wherein said step of calcining is performed at temperatures higher than 400\xb0 C.
15. A solid material obtained by a process of treating a solid material comprising at least one zeolite, and being at least partly crystalline, wherein said solid material is brought in contact with a composition comprising water, after at least one of the following steps of an integrated process for producing said solid material: (i) after step (II) of separating the at least partly crystalline material from its mother liquor, or (ii) after a step (C) of calcining said solid material or a shaped body comprising said solid material.
16. The solid material according to claim 15, wherein the solid material comprises Ti.
17. The solid material according to claim 15, wherein the solid material displays an increased UVVIS absorption, over materials that have not been brought in contact with a composition comprising water, in the region from 250 to 350 nm.
18. The solid material according to claim 15, characterized in that it wherein the solid material is shaped into a shaped body in a step (S), and that in addition to the step of bringing the solid material in contact with a composition comprising water, or instead of said step, the shaped body is brought in contact with a composition comprising water, either directly after the step (S) of shaping the solid material into a shaped body, or after a subsequent step (C) of calcining said shaped body.
19. A method of catalyzing a reaction, comprising contacting the solid material according to claim 15, or a shaped body comprising said solid material, with a mixture comprising at least one compound with at least one C\u2014C-double bond and at least one hydroperoxide.
20. A method of catalyzing a reaction, comprising contacting the solid material according to claim 17, or a shaped body comprising said solid material, with a mixture comprising at least one compound with at least one C\u2014C-double bond and at least one hydroperoxide.
21. A catalyst or co-catalyst comprising the solid material according to claim 15, or a shaped body comprising said solid material, and one or more additives.
22. A catalyst or co-catalyst comprising the solid material body according to claim 16, or a shaped body comprising said solid material, and one or more additives.
23. A catalyst or co-catalyst comprising the solid material according to claim 17, or a shaped body comprising said solid material, and one or more additives.
24. A catalyst or co-catalyst comprising the solid material according to claim 18, or a shaped body comprising said solid material, and one or more additives.
25. The process according to claim 2, wherein the at least one zeolite comprises Ti.
26. The process according to claim 3, wherein the at least one zeolite contains comprises Ti.
27. The integrated process according to claim 8, further comprising, after at least one of the steps (II), (W) or (III), a step (C) of calcining the solid material andor a shaped body comprising said solid material.
28. The integrated process according to claim 9, further comprising, after at least one of the steps (II), (W) or (III), a step (C) of calcining the solid material andor a shaped body comprising said solid material.
29. The integrated process according to claim 10, further comprising, after at least one of the steps (II), (W) or (III), a step (C) of calcining the solid material andor the shaped body.
30. The integrated process according to claim 11, further comprising, after at least one of the steps (II), (W) or (III), a step (C) of calcining the solid material andor the shaped body.
31. The integrated process according to claim 12, further comprising, after at least one of the steps (II), (W) or (III), a step (C) of calcining the solid material andor the shaped body.
32. The solid material according to claim 16, wherein the solid material is shaped into a shaped body in a step (S), and that in addition to the step of bringing the solid material in contact with a composition comprising water, or instead of said step, the shaped body is brought in contact with a composition comprising water, either directly after the step (S) of shaping the solid material into a shaped body, or after a subsequent step (C) of calcining said shaped body.
33. The solid material according to claim 17, wherein the solid material is shaped into a shaped body in a step (S), and that in addition to the step of bringing the solid material in contact with a composition comprising water, or instead of said step, the shaped body is brought in contact with a composition comprising water, either directly after the step (S) of shaping the solid material into a shaped body, or after a subsequent step (C) of calcining said shaped body.
34. A shaped body comprising a solid material comprising at least one zeolite, and being at least partly crystalline, obtained by a process comprising the steps of:
(I) crystallizing, at least partially, the at least one solid material comprising at least one zeolite, out of a synthesis mixture, to form a mixture (I) comprising at least the solid material and a mother liquor;
(II) separating andor concentrating the solid material in mixture (I);
(S) shaping the solid material into a shaped body;
(C) calcining the shaped body at temperatures higher than 400\xb0 C., to form a calcined shape body;
(W) contacting the calcined shaped body with a composition comprising water; and
wherein the separation andor concentration in step (II) is carried out by a method selected from the group consisting of: filtration, ultrafiltration, diafiltration, centrifuge methods, spray drying and spray granulating; and
wherein the shaping of the solid material in step (S) is carried out by a method selected from the group consisting of: pelletizing, pressing, extruding, sintering, roasting and briquetting.
35. The shaped body according to claim 34, wherein the at least one zeolite comprises Ti.
36. The shaped body according to claim 35, wherein the at least one zeolite comprising Ti is selected from materials of the structure classes MFI, MEL, MWW, BEA or combinations thereof.
37. The shaped body according to claim 34, wherein the solid material displays an increased UVVIS absorption, over materials that have not been brought in contact with a composition comprising water, in the region from 250 to 350 nm.
38. The shaped body according to claim 34, wherein step (S) is carried out by extruding the solid material into an extrudate with a diameter ranging from about 1 mm to about 10 mm.
39. The solid material according to claim 16, wherein the solid material comprises at least one zeolite comprising Ti, selected from materials of the structure classes MFI, MEL, MWW, BEA or combinations thereof.
40. The solid material according to claim 39, wherein the at least one zeolite further comprises a member selected from vanadium, zirconium, niobium or combinations thereof.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
1. A GPS positioner having a rescue call function, comprising:
a global positioning receiving module for receiving navigation signals from satellites;
a Bluetooth communication interface electrically connected to the global positioning receiving module; and
an emergency button for sending a rescue request signal through the Bluetooth communication interface.
2. The GPS positioner having a rescue call function of claim 1, wherein the rescue request signal is sent to a device also with a Bluetooth communication interface, and then the device is driven to send a rescue request message or dial an emergency phone number.
3. The GPS positioner having a rescue call function of claim 1, further comprising a rescue request signal generator for transferring an output signal of the emergency button to the rescue request signal.
4. The GPS positioner having a rescue call function of claim 1, wherein the Bluetooth communication interface automatically searches a device also with a Bluetooth communication interface after the GPS positioner is powered on.
5. The GPS positioner having a rescue call function of claim 4, wherein the Bluetooth communication interface obtains match information from the device.
6. A GPS having a rescue call function, comprising:
a GPS positioner including:
a global positioning receiving module for receiving navigation signals from satellites;
a Bluetooth communication interface electrically connected to the global positioning receiving module; and
an emergency button for sending a rescue request signal through the Bluetooth communication interface; and
at least one device with a Bluetooth communication interface.
7. The GPS having a rescue call function of claim 6, wherein the rescue request signal of the GPS positioner drives the device with a Bluetooth communication interface to send a rescue request message or dial an emergency phone number.
8. The GPS having a rescue call function of claim 6, wherein the device with a Bluetooth communication interface is a personal digital assistant, a notebook computer or a smart phone.
9. The GPS having a rescue call function of claim 6, further comprising a positioning map read by the device with a Bluetooth communication interface.