1. A phosphinine compound of formula I
where
n=0 or 1,
Y=O, NH, NR1,
R1=H, an aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms,
R2, R3, R4, R5, R6, R7, R8, R9=H, an aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic, or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, where R2 to R9 are identical or different and may be covalently linked to one another, F, Cl, Br, I, \u2014CF3, \u2014OR10, \u2014COR10, \u2014CO2R10, \u2014CO2M, \u2014SR10, \u2014SO2R10, \u2014SOR10, \u2014SO3R10, \u2014SO3M, \u2014SO2NR10R11, \u2014NR10R11, N\u2550CR10R11 or NH2, wherein at least one of R2 to R9 is heterocyclic or aliphatic heterocyclic,
R10, R11=H, a substituted or unsubstituted aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms, identical or different,
M=an alkali metal, an alkaline earth metal, ammonium or phosphonium ion,
Q=a divalent aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, and
W and X are each an aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, which may be identical or different or covalently linked to one another.
2. A phosphinine compound of formula I
where
n=0 or 1,
Y=O, NH, NR1,
R1=H, an aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms,
R2, R3, R4, R5, R6, R7, R8, R9 =H, an aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic, or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, where R2 to R9 are identical or different and may be covalently linked to one another, F, Cl, Br, I, \u2014CF3, \u2014OR10, \u2014COR10, \u2014CO2R10, \u2014CO2M, \u2014SR10, \u2014SO2R10, \u2014SOR10, \u2014SO3R10, \u2014SO3M, \u2014SO2NR10R11, \u2014NR10R11, N\u2550CR10R11 or NH2,
R10, R11=H, a substituted or unsubstituted aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms, identical or different,
M=an alkali metal, an alkaline earth metal, ammonium or phosphonium ion,
Q=a heterocyclic or aliphatic-heterocyclic radical having from 1 to 50 carbon atoms, and
W and X are each an aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, which may be identical or different or covalently linked to one another.
3. A phosphinine compound of formula I
where
n=0 or 1,
Y=O, NH, NR1,
R1=H, an aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms,
R2, R3, R4, R5, R6, R7, R8, R9=H, an aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic, or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, where R2 to R9 are identical or different and may be covalently linked to one another, F, Cl, Br, I, \u2014CF3, \u2014OR10, \u2014COR10, \u2014CO2R10, \u2014CO2M, \u2014SR10, \u2014SO2R10, \u2014SOR10, \u2014SO3R10, \u2014SO3M, \u2014SO2NR10R11, \u2014NR10R11, N\u2550CR10R11 or NH2,
R10, R11=H, a substituted or unsubstituted aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms, identical or different,
M=an alkali metal, an alkaline earth metal, ammonium or phosphonium ion,
Q=a divalent aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, and
W and X are each a heterocyclic or aliphatic-heterocyclic radical having from 1 to 50 carbon atoms, which may be identical or different or covalently linked to one another.
4. The phosphinine compound as claimed in claim 1, wherein Q is a hydrocarbon radical of formula VI
where
R31, R32, R33, R34, R35, R36, R37, R38=H, an aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, F, Cl, Br, I, \u2014CF3, \u2014OR39, \u2014COR39, \u2014CO2R39, \u2014CO2M, \u2014SR39, \u2014SO2R39, \u2014SOR39, \u2014SO3R39, \u2014SO3M, \u2014SO2NR39R40, \u2014NR39R40, N\u2550CR39R40 or NH2,
R39, R40=H, a substituted or unsubstituted, aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms, identical or different,
M=an alkali metal, an alkaline earth metal, ammonium or phosphonium ion, and positions a and b serve as linkage points.
5. The phosphinine compound as claimed in claim 3, wherein Q is a hydrocarbon radical of formula VI
where
R31, R32, R33, R34, R35, R36, R37, R38=H, an aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, F, Cl, Br, I, \u2014CF3, \u2014OR39, \u2014COR39, \u2014CO2R39, \u2014CO2M, \u2014SR39, \u2014SO2R39, \u2014SOR39, \u2014SO3R39, \u2014SO3M, \u2014SO2NR39R40, \u2014NR39R40, N\u2550CR39R40 or NH2,
R39, R40=H, a substituted or unsubstituted, aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms, identical or different,
M=an alkali metal, an alkaline earth metal, ammonium or phosphonium ion, and positions a and b serve as linkage points.
6. A phosphinine-metal complex comprising a metal of transition metal elements of Groups 4, 5, 6, 7 and 8 of the Periodic Table of the Elements and at least one phosphinine of formula I
where
n=0 or 1,
Y=O, NH, NR1,
R1=H, an aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms,
R2, R3, R4, R5, R6, R7, R8, R9=H, an aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic, or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, where R2 to R9 are identical or different and may be covalently linked to one another, F, Cl, Br, I, \u2014CF3, \u2014OR10, \u2014COR10, \u2014CO2R10, \u2014CO2M, \u2014SR10, \u2014SO2R10, \u2014SOR10, \u2014SO3R10, \u2014SO3M, \u2014SO2NR10R11, \u2014NR10R11, N\u2550CR10R11 or NH2, wherein at least one of R2 to R9 is heterocyclic or aliphatic heterocyclic,
R10, R11=H, a substituted or unsubstituted aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms, identical or different,
M=an alkali metal, an alkaline earth metal, ammonium or phosphonium ion,
Q=a divalent aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, and
W and X are each an aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, which may be identical or different or covalently linked to one another.
7. A phosphinine-metal complex comprising a metal of transition metal elements of Groups 4, 5, 6, 7 and 8 of the Periodic Table of the Elements and at least one phosphinine of formula I
where
n=0 or 1,
Y=O, NH, NR1,
R1=H, an aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms,
R2, R3, R4, R5, R6, R7, R8, R9=H, an aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic, or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, where R2 to R9 are identical or different and may be covalently linked to one another, F, Cl, Br, I, \u2014CF3, \u2014OR10, \u2014COR10, \u2014CO2R10, \u2014CO2M, \u2014SR10, \u2014SO2R10, \u2014SOR10, \u2014SO3R10, \u2014SO3M, \u2014SO2NR10R11, \u2014NR10R11, N\u2550CR10R11 or NH2,
R10, R11=H, a substituted or unsubstituted aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms, identical or different,
M=an alkali metal, an alkaline earth metal, ammonium or phosphonium ion,
Q=a heterocyclic or aliphatatic heterocyclic radical having from 1 to 50 carbon atoms, and
W and X are each an aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, which may be identical or different or covalently linked to one another.
8. A phosphinine-metal complex comprising a metal of transition metal elements of Groups 4, 5, 6, 7 and 8 of the Periodic Table of the Elements and at least one phosphinine of formula I
where
n=0 or 1,
Y=O, NH, NR1,
R1=H, an aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms,
R2, R3, R4, R5, R6, R7, R8, R9=H, an aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic, or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, where R2 to R9 are identical or different and may be covalently linked to one another, F, Cl, Br, I, \u2014CF3, \u2014OR10, \u2014COR10, \u2014CO2R10, \u2014CO2M, \u2014SR10, \u2014SO2R10, \u2014SOR10, \u2014SO3R10, \u2014SO3M, \u2014SO2NR10R11, \u2014NR10R11, N\u2550CR10R11 or NH2,
R10, R11=H, a substituted or unsubstituted aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms, identical or different,
M=an alkali metal, an alkaline earth metal, ammonium or phosphonium ion,
Q=a divalent aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, and
W and X are each a heterocyclic or aliphatic-heterocyclic radical having from 1 to 50 carbon atoms, which may be identical or different or covalently linked to one another.
9. The phosphinine-metal complex as claimed in claim 6, wherein W and X are each an aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms and are covalently linked as in formula II
10. The phosphinine-metal complex as claimed in claim 7, wherein W and X are each an aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms and are covalently linked as in formula II
11. The phosphinine-metal complex as claimed in claim 6, wherein W and X are each an aromatic hydrocarbon radical having from 1 to 50 carbon atoms and are covalently linked as in formula III
where
R12, R13, R14, R15, R16, R17=H, an aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic, or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, where R12 to R17 are identical or different and may be covalently linked to one another, F, Cl, Br, I, \u2014CF3, \u2014OR18, \u2014COR18, \u2014CO2R18, \u2014CO2M, \u2014SR18, \u2014SO2R18, \u2014SOR18, \u2014SO3R18, \u2014SO3M, \u2014SO2NR18R19, \u2014NR 18R19, N\u2550CR18R19 or NH2, wherein at least one of R2 to R9 is heterocyclic or aliphatic heterocyclic,
R18, R19=H, a substituted or unsubstituted, aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms, identical or different, and
M=an alkali metal, an alkaline earth metal, ammonium or phosphonium ion.
12. The phosphinine-metal complex as claimed in claim 7, wherein W and X are each an aromatic hydrocarbon radical having from 1 to 50 carbon atoms and are covalently linked as in formula III
where
R12, R13, R14, R15, R16, R17=H, an aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic, or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, where R12 to R17 are identical or different and may be covalently linked to one another, F, Cl, Br, I, \u2014CF3, \u2014OR18, \u2014COR18, \u2014CO2R18, \u2014CO2M, \u2014SR18, \u2014SO2R18, \u2014SOR18, \u2014SO3R18, \u2014SO3M, \u2014SO2NR18R19, \u2014NR18R19, N\u2550CR18R19 or NH2, wherein at least one of R2 to R9 is heterocyclic or aliphatic heterocyclic,
R18, R19=H, a substituted or unsubstituted, aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms, identical or different, and
M=an alkali metal, an alkaline earth metal, ammonium or phosphonium ion.
13. The phosphinine-metal complex as claimed in claim 6, wherein W and X are each an aromatic hydrocarbon radical having from 1 to 50 carbon atoms and are covalently linked as in formula IV
where
R21, R22, R23, R24, R25, R26, R27 , R28=H, an aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, where R21 to R28 are identical or different and may be covalently linked to one another, F, Cl, Br, I, \u2014CF3, \u2014OR29, \u2014COR29, \u2014CO2R29, \u2014CO2M, \u2014SR29, \u2014SO2R29, \u2014SOR29, \u2014SO3R29, \u2014SO3M, \u2014SO2NR29R30, \u2014NR29R30, N\u2550CR29R30 or NH2,
R29, R30=H, a substituted or unsubstituted, aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms, and
M=an alkali metal, an alkaline earth metal, ammonium or phosphonium ion.
14. The phosphinine-metal complex as claimed in claim 7, wherein W and X are each an aromatic hydrocarbon radical having from 1 to 50 carbon atoms and are covalently linked as in formula IV
where
R21, R22, R23, R24, R25, R26, R27, R28=H, an aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, where R21 to R28 are identical or different and may be covalently linked to one another, F, Cl, Br, I, \u2014CF3, \u2014OR29, \u2014COR29, \u2014CO2R29, \u2014CO2M, \u2014SR29, \u2014SO2R29, \u2014SOR29, \u2014SO3R29, \u2014SO3M, \u2014SO2NR29R30, \u2014NR29R30, N\u2550CR29R30 or NH2,
R29, R30=H, a substituted or unsubstituted, aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms, and
M=an alkali metal, an alkaline earth metal, ammonium or phosphonium ion.
15. The phosphinine-metal complex as claimed in claim 6, wherein W and X are each an aromatic hydrocarbon radical having from 1 to 50 carbon atoms and are covalently linked as in formula V
where
R20=H, an aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms,
R21, R22, R23, R24, R25, R26, R27, R28=H, an aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, where R21 to R28 are identical or different and may be covalently linked to one another, F, Cl, Br, I, \u2014CF3, \u2014OR29, \u2014COR29, \u2014CO2R29, \u2014CO2M, \u2014SR29, \u2014SO2R29, \u2014SOR29, \u2014SO3R29, \u2014SO3M, \u2014SO2NR29R30, \u2014NR29R30, \u2014N\u2550CR29R30 or NH2,
R29, R30=H, a substituted or unsubstituted, aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms,
M=an alkali metal, an alkaline earth metal, ammonium or phosphonium ion.
R2 to R9 are indentical or different and may be covalenty linked to one another.
16. The phosphinine-metal complex as claimed in claim 7, wherein W and X are each an aromatic hydrocarbon radical having from 1 to 50 carbon atoms and are covalently linked as in formula V
where
R20=H, an aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms,
R21, R22, R23, R24, R25, R26, R27, R28=H, an aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, where R21 to R28 are identical or different and may be covalently linked to one another, F, Cl, Br, I, \u2014CF3, \u2014OR29, \u2014COR29, \u2014CO2R29, \u2014CO2M, \u2014SR29, \u2014SO2R29, \u2014SOR29, \u2014SO3R29, \u2014SO3M, \u2014SO2NR29R30, \u2014NR29R30, \u2014N\u2550CR29R30or NH2,
R29, R30=H, a substituted or unsubstituted, aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms,
M=an alkali metal, an alkaline earth metal, ammonium or phosphonium ion.
R2 to R9 are identical or different and may be covalently linked to one another.
17. The phosphinine-metal complex as claimed in claim 6, wherein Q is a hydrocarbon radical of the formula VI
where
R31, R32, R33, R34, R35, R36, R37, R38=H, an aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, F, Cl, Br, I, \u2014CF3, \u2014OR39, \u2014COR39, \u2014CO2R29, \u2014CO2M, \u2014SR39, \u2014SO2R39, \u2014SOR39, \u2014SO3R39, \u2014SO3M, \u2014SO2NR39R40, \u2014NR39R40, N\u2550CR39R40 or NH2,
R39, R40=H, a substituted or unsubstituted, aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms, and
M=an alkali metal, an alkaline earth metal, ammonium or phosphonium ion, and where positions a and b serve as linkage points.
18. The phosphinine-metal complex as claimed in claim 8, wherein Q is a hydrocarbon radical of the formula VI
where
R31, R32, R33, R34, R35, R36, R37, R38=H, an aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, F, Cl, Br, I, \u2014CF3, \u2014OR39, \u2014COR39, \u2014CO2R29, \u2014CO2M, \u2014SR39, \u2014SO2R39, \u2014SOR39, \u2014SO3R39, \u2014SO3M, \u2014SO2NR39R40, \u2014NR39R40, N\u2550CR39R40 or NH2,
R39, R40=H, a substituted or unsubstituted, aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms, and
M=an alkali metal, an alkaline earth metal, ammonium or phosphonium ion, and where positions a and b serve as linkage points.
19. The phosphinine-metal complex as claimed in claim 6, wherein the metal is rhodium, platinum, cobalt or ruthenium.
20. The phosphinine-metal complex as claimed in claim 7, wherein the metal is rhodium, platinum, cobalt or ruthenium.
21. The phosphinine-metal complex as claimed in claim 8, wherein the metal is rhodium, platinum, cobalt or ruthenium.
22. A process, comprising:
hydroformylating an olefin in a reaction medium containing a phosphinine having formula I
where
n=0 or 1,
Y=O, NH, NR1,
R1=H, an aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms,
R2, R3, R4, R5, R6, R7, R8, R9=H, an aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic, or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, where R2 to R9 are identical or different and may be covalently linked to one another, F, Cl, Br, I, \u2014CF3, \u2014OR10, \u2014COR10, \u2014CO2R10, \u2014CO2M, \u2014SR10, \u2014SO2R10, \u2014SOR10, \u2014SO3R10, \u2014SO3M, \u2014SO2NR10R11, \u2014NR10R11, N\u2550CR10R11 or NH2,
R10, R11=H, a substituted or unsubstituted aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms, identical or different,
M=an alkali metal, an alkaline earth metal, ammonium or phosphonium ion,
Q=a divalent aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, and
W and X are each an aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, which may be identical or different or covalently linked to one another.
23. A process, comprising:
hydroformylating an olefin in a reaction medium containing a phosphinine-metal complex as a catalyst, said phosphinine having formula I
where
n=0 or 1,
Y=O, NH, NR1,
R1=H, an aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms,
R2, R3, R4, R5, R6, R7, R8, R9=H, an aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic, or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, where R2 to R9 are identical or different and may be covalently linked to one another, F, Cl, Br, I, \u2014CF3, \u2014OR10, \u2014COR10, \u2014CO2R10, \u2014CO2M, \u2014SR10, \u2014SO2R10, \u2014SOR10, \u2014SO3R10, \u2014SO3M, \u2014SO2NR10R11, \u2014NR10R11, N\u2550CR10R11 or NH2,
R10, R11=H, a substituted or unsubstituted aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms, identical or different,
M=an alkali metal, an alkaline earth metal, ammonium or phosphonium ion,
Q=a divalent aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, and
W and X are each an aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, which may be identical or different or covalently linked to one another.
24. A process, comprising:
hydroformylating an olefin in a reaction medium, wherein said phosphinine having the following formula I and at least one other phosphorus containing ligand are present in the olefin
where
n=0 or 1,
Y=O, NH, NR1,
R1=H, an aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms,
R2, R3, R4, R5, R6, R7, R8, R9=H, an aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic, or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, where R2 to R9 are identical or different and may be covalently linked to one another, F, Cl, Br, I, \u2014CF3, \u2014OR10, \u2014COR10, \u2014CO2R10, \u2014CO2M, \u2014SR10, \u2014SO2R10, \u2014SOR10, \u2014SO3R10, \u2014SO3M, \u2014SO2NR10R11, \u2014NR10R11, N\u2550CR10R11 or NH2,
R10, R11=H, a substituted or unsubstituted aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms, identical or different,
M=an alkali metal, an alkaline earth metal, ammonium or phosphonium ion,
Q=a divalent aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, and
W and X are each an aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, which may be identical or different or covalently linked to one another.
25. A process, comprising:
hydroformylating an olefin in a reaction medium containing a phosphinine-metal complex as a catalyst, said phosphinine having formula I
where
n=0 or 1,
Y=O, NH, NR1,
R1=H, an aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms,
R2, R3, R4, R5, R6, R7, R8, R9,=H, an aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic, or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, where R2 to R9 are identical or different and may be covalently linked to one another, F, Cl, Br, I, \u2014CF3, \u2014OR10, \u2014COR10, \u2014CO2R10, \u2014CO2M, \u2014SR10, \u2014SO2R10, \u2014SOR10, \u2014SO3R10, \u2014SO3M, \u2014SO2NR10R11, \u2014NR10R11, N\u2550CR10R11 or NH2,
R10, R11=H, a substituted or unsubstituted aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms, identical or different,
M=an alkali metal, an alkaline earth metal, ammonium or phosphonium ion,
Q=a divalent aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, and
W and X are each an aliphatic, alicyclic, aliphatic-alicylic, heterocyclic, aliphatic-heterocyclic, aromatic, aromatic-aromatic or aliphatic-aromatic hydrocarbon radical having from 1 to 50 carbon atoms, which may be identical or different or covalently linked to one another.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
1. A system for automatically loading software components, the system being installed in a BIOS of a computer, the system comprising:
an identifying and judging module configured for identifying whether there is an identifier recorded in a desktop management interface (DMI) in the BIOS, and detecting that the computer is not installed with a specified operating system if the DMI includes an identifier, and that the computer is installed with the specified operating system if there is no identifier recorded in the DMI; and
a loading module configured for loading specified application software to the computer if the computer is installed with the specified operating system, wherein the application software is a System Locked Preinstallation (SLP) 2.0.
2. A computer-based method for automatically loading software components, the method comprising:
powering on a computer, identifying whether there is an identifier recorded in a desktop management interface (DMI) in a BIOS of the computer, and detecting that the computer is not installed with a specified operating system if the DMI includes an identifier, and that the computer is installed with the specified operating system if there is no identifier recorded in the DMI; and
loading specified application software to the computer if the computer is installed with the specified operating system, wherein the application software is a System Locked Preinstallation (SLP) 2.0.