1. A rigid flame retardant polyurethane foam which satisfies the requirements of ASTM E-84 for a Class I foam comprising the reaction product of:
at least one polyisocyanate; with
a polyol component comprising,
from about 2 wt. % to about 35 wt. %, based on the weight of the polyol component, of at least one sucrose-based polyol,
from about 2 wt. % to about 35 wt. %, based on the weight of the polyol component, of at least one non sucrose-based isocyanate-reactive compound, and
from about 1 wt. % to about 13 wt. %, based on the weight of the foam, of at least one aromatic polyester polyol,
in the presence of water, and optionally, at least one of carbon dioxide, surfactants, flame retardants, pigments, catalysts and fillers,
with the proviso that the rigid polyurethane foam contains no trimethylolpropane-based polyols.
2. The rigid polyurethane foam according to claim 1, wherein the at least one polyisocyanate is chosen from ethylene diisocyanate, 1,4-tetramethylene diisocyanate, 1,6-hexamethylene diisocyanate, 1,12-dodecane diisocyanate, cyclobutane-1,3-diisocyanate, cyclohexane-1,3-and-1,4-diisocyanate, 1-isocyanato-3,3,5-trimethyl-5-isocyanatomethyl-cyclohexane (isophorone diisocyanate), 2,4- and 2,6-hexahydrotoluene diisocyanate, dicyclohexylmethane-4,4\u2032-diisocyanate (hydrogenated MDI, or HMDI), 1,3- and 1,4-phenylene diisocyanate, 2,4- and 2,6-toluene diisocyanate (TDI), diphenylmethane-2,4\u2032- andor -4,4\u2032-diisocyanate (MDI), naphthylene-1,5-diisocyanate, triphenyl-methane-4,4\u2032,4\u2033-diisocyanate, polyphenyl-polymethylene-polyisocyanates (crude MDI), norbornane diisocyanates, m- and p-isocyanatophenyl sulfonylisocyanates, perchlorinated aryl polyisocyanates, carbodiimide-modified polyisocyanates, urethane-modified polyisocyanates, allophanate-modified polyisocyanates, isocyanurate-modified polyisocyanates, urea-modified polyisocyanates, biuret containing polyisocyanates and isocyanate-terminated prepolymers.
3. The rigid polyurethane foam according to claim 1, wherein the at least one polyisocyanate is an isocyanate-terminated prepolymer.
4. The rigid polyurethane foam according to claim 1, wherein the isocyanate index is from about 100 to about 400.
5. The rigid polyurethane foam according to claim 1, wherein the isocyanate index is from about 105 to about 200.
6. The rigid polyurethane foam according to claim 1, wherein the at least one sucrose-based polyol comprises from about 4 wt. % to about 20 wt. %, based on the weight of the polyol component.
7. The rigid polyurethane foam according to claim 1, wherein the at least one non sucrose-based isocyanate-reactive compound is chosen from polyethers, polyesters, polyacetals, polycarbonates, polyesterethers, polyester carbonates, polythioethers, polyamides, polyesteramides, polysiloxanes, polybutadienes and polyacetones.
8. The rigid polyurethane foam according to claim 1, wherein the at least one non sucrose-based isocyanate-reactive compound is a polyether polyol.
9. The rigid polyurethane foam according to claim 1, wherein the at least one non sucrose-based isocyanate-reactive compound comprises from about 4 wt. % to about 20 wt. %, based on the weight of the polyol component.
10. The rigid polyurethane foam according to claim 1, wherein the at least one aromatic polyester polyol comprises from about 5 wt. % to about 13 wt. %, based on the weight of the foam.
11. The rigid polyurethane foam according to claim 1, wherein the catalyst comprises one or more chosen from triethylamine, tributylamine, triethylene diamine, N-methylmorpholine, N-ethylmorpholine, N,N,N\u2032,N\u2032-tetramethylethylene diamine, pentamethyldiethylene triamine, 1,4-diazabicyclo2.2.2octane, N-methyl-N\u2032-(dimethylaminoethyl)piperazine, bis(dimethylaminoalkyl)piperazines, N,N-dimethylbenzylamine, N,N-dimethylcyclohexylamine, N,N-diethylbenzylamine, bis(N,N-diethylaminoethyl)adipate, N,N,N\u2032,N\u2032-tetramethyl-1,3-butanediamine, N,N-dimethyl-\u03b2-phenylethylamine, amine salt of diazabicycloundecene and formic acid, 1,2-dimethylimidazole, 2-methylimidazole, monocyclic and bicyclic amidines, bis(dialkylamino)alkyl ethers, triethanolamine, triisopropanolamine, N-methyldiethanolamine, N-ethyldiethanolamine, N,N-dimethylethanolamine, dioctyl tin mercaptide, tin(II) acetate, tin(II) octoate, tin(II) ethylhexoate, tin(II) laurate, dibutyltin dilaurate, dibutyltin dichloride, dibutyltin diacetate, dibutyltin maleate, and dioctyltin diacetate, bismuth neodecanoate, bismuth versalate, bismuth carboxylates, zinc neodecanoate, zinc versalate and carboxylic acid salts containing zinc and bismuth.
12. The rigid polyurethane foam according to claim 1, wherein the flame retardant is chosen from phosphonates, phosphites, phosphates, halogen-containing compounds, melamine, antimony oxides, zinc compounds, aluminum compounds, magnesium compounds and mixtures thereof.
13. The rigid polyurethane foam according to claim 1, wherein the flame retardant is chosen from dimethyl methylphosphonate, diethyl ethyl phosphonate, triethylphosphonate, ammonium polyphosphate, brominated diphenyl ethers and other brominated aromatic and aliphatic compounds, melamine, antimony pentoxide, antimony trioxide, zinc borates, alumina trihydrate, magnesium hydroxide, neutralcyclic phosphate and phosphonate esters, and mixtures thereof.
14. The rigid polyurethane foam according to claim 1, wherein the flame retardant comprises from about 5 wt. % to about 75 wt. %, based on the weight of the polyol component.
15. The rigid polyurethane foam according to claim 1, wherein the flame retardant comprises from about 10 wt. % to about 65 wt. %, based on the weight of the polyol component.
16. The rigid polyurethane foam according to claim 1, wherein the flame retardant comprises from about 10 wt. % to about 55 wt. %, based on the weight of the polyol component.
17. The rigid polyurethane foam according to claim 1, wherein the filler is chosen from glass fibers, glass flakes, cut fibers, mats, microspheres, mica, wollastonite, carbon fibers, carbon black, talc, calcium carbonate, barium sulfate, calcium silicate, clays, kieselguhr, whiting, mica, liquid crystal fibers and aramide fibers.
18. One of an electronic cabinet, an architectural decorative molding, and an interior transportation vehicle wall comprising the rigid polyurethane foam according to claim 1.
19. A process for making a rigid flame retardant polyurethane foam which satisfies the requirements of ASTM E-84 for a Class I foam comprising reacting:
at least one polyisocyanate; with
a polyol component comprising,
from about 2 wt % to about 35 wt. %, based on the weight of the polyol component, of at least one sucrose-based polyol,
from about 2 wt. % to about 35 wt. %, based on the weight of the polyol component, of at least one non sucrose-based isocyanate-reactive compound, and
from about 1 wt. % to about 13 wt. %, based on the weight of the foam, of at least one aromatic polyester polyol,
in the presence of water, and optionally, at least one of carbon dioxide, surfactants, flame retardants, pigments, catalysts and fillers,
with the proviso that the rigid polyurethane foam contains no trimethylolpropane-based polyols.
20. The process according to claim 19, wherein the at least one polyisocyanate is chosen from ethylene diisocyanate, 1,4-tetramethylene diisocyanate, 1,6-hexamethylene diisocyanate, 1,12-dodecane diisocyanate, cyclobutane-1,3-diisocyanate, cyclohexane-1,3-and-1,4-diisocyanate, 1-isocyanato-3,3,5-trimethyl-5-isocyanatomethyl-cyclohexane (isophorone diisocyanate), 2,4- and 2,6-hexahydrotoluene diisocyanate, dicyclohexylmethane-4,4\u2032-diisocyanate (hydrogenated MDI, or HMDI), 1,3- and 1,4-phenylene diisocyanate, 2,4- and 2,6-toluene diisocyanate (TDI), diphenylmethane-2,4\u2032- andor -4,4\u2032-diisocyanate (MDI), naphthylene-1,5-diisocyanate, triphenyl-methane-4,4\u2032,4\u2033-triisocyanate, polyphenyl-polymethylene-polyisocyanates (crude MDI), norbornane diisocyanates, m- and p-isocyanatophenyl sulfonylisocyanates, perchlorinated aryl polyisocyanates, carbodiimide-modified polyisocyanates, urethane-modified polyisocyanates, allophanate-modified polyisocyanates, isocyanurate-modified polyisocyanates, urea-modified polyisocyanates, biuret containing polyisocyanates and isocyanate-terminated prepolymers.
21. The process according to claim 19, wherein the at least one polyisocyanate is an isocyanate-terminated prepolymer.
22. The process according to claim 19, wherein the isocyanate index is from about 100 to about 400.
23. The process according to claim 19, wherein the isocyanate index is from about 105 to about 200.
24. The process according to claim 19, wherein the at least one sucrose-based polyol comprises from about 4 wt. % to about 20 wt. %, based on the weight of the polyol component.
25. The process according to claim 19, wherein the at least one non sucrose-based isocyanate-reactive compound is chosen from polyethers, polyesters, polyacetals, polycarbonates, polyesterethers, polyester carbonates, polythioethers, polyamides, polyesteramides, polysiloxanes, polybutadienes and polyacetones.
26. The process according to claim 19, wherein the at least one non sucrose-based isocyanate-reactive compound is a polyether polyol.
27. The process according to claim 19, wherein the at least one non sucrose-based isocyanate-reactive compound comprises from about 4 wt. % to about 20 wt. %, based on the weight of the polyol component.
28. The process according to claim 19, wherein the at least one aromatic polyester polyol comprises from about 5 wt. % to about 13 wt. %, based on the weight of the foam.
29. The process according to claim 19, wherein the catalyst comprises one or more chosen from triethylamine, tributylamine, triethylene diamine, N-methylmorpholine, N-ethylmorpholine, N,N,N\u2032,N\u2032-tetramethylethylene diamine, pentamethyldiethylene triamine, 1,4-diazabicyclo2.2.2octane, N-methyl-N\u2032-(dimethylaminoethyl)piperazine, bis(dimethylaminoalkyl)piperazines, N,N-dimethylbenzylamine, N,N-dimethylcyclohexylamine, N,N-diethylbenzylamine, bis(N,N-diethylaminoethyl)adipate, N,N,N\u2032,N\u2032-tetramethyl-1,3-butanediamine, N,N-dimethyl-\u03b2-phenylethylamine, amine salt of diazabicycloundecene and formic acid, 1,2-dimethylimidazole, 2-methylimidazole, monocyclic and bicyclic amidines, bis(dialkylamino)alkyl ethers, triethanolamine, triisopropanolamine, N-methyldiethanolamine, N-ethyldiethanolamine, N,N-dimethylethanolamine, dioctyl tin mercaptide, tin(II) acetate, tin(II) octoate, tin(II) ethylhexoate, tin(II) laurate, dibutyltin dilaurate, dibutyltin dichloride, dibutyltin diacetate, dibutyltin maleate, and dioctyltin diacetate, bismuth neodecanoate, bismuth versalate, bismuth carboxylates, zinc neodecanoate, zinc versalate and carboxylic acid salts containing zinc and bismuth.
30. The process according to claim 19, wherein the flame retardant is chosen from phosphonates, phosphites, phosphates, halogen-containing compounds, melamine, antimony oxides, zinc compounds, aluminum compounds, magnesium compounds, urea and mixtures thereof.
31. The process according to claim 19, wherein the flame retardant is chosen from dimethyl methylphosphonate, diethyl ethyl phosphonate, triethylphosphonate, ammonium polyphosphate, brominated diphenyl ethers and other brominated aromatic and aliphatic compounds, melamine, antimony pentoxide, antimony trioxide, zinc borates, alumina trihydrate, magnesium hydroxide, neutralcyclic phosphate and phosphonate esters, urea and mixtures thereof.
32. The process according to claim 19, wherein the flame retardant comprises from about 5 wt. % to about 75 wt. %, based on the weight of the polyol component.
33. The process according to claim 19, wherein the flame retardant comprises from about 10 wt % to about 65 wt. %, based on the weight of the polyol component.
34. The process according to claim 19, wherein the flame retardant comprises from about 10 wt. % to about 55 wt. %, based on the weight of the polyol component.
35. The process according to claim 19, wherein the filler is chosen from glass fibers, glass flakes, cut fibers, mats, microspheres, mica, wollastonite, carbon fibers, carbon black, talc, calcium carbonate, barium sulfate, calcium silicate, clays, kieselguhr, whiting, mica, liquid crystal fibers and aramide fibers.
36. The foam made by the process according to claim 19.
37. One of an electronic cabinet, an architectural decorative molding, and an interior transportation vehicle wall comprising the rigid polyurethane foam made by the process according to claim 19.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
1. An orthogonal frequency division multiplexing (OFDM) system comprising:
an oscillator which generates a carrier frequency and a sampling frequency;
a converter which samples a received signal with the generated sampling frequency;
a frequency offset estimator which estimates a carrier frequency offset using at least one pilot subcarrier of the received signal;
a fast Fourier transformer (FFT) which transforms the sampled received signal into a frequency domain; and
an offset tracker which tracks a sampling frequency offset by calculating at least one of a range and a size of a maximum likelihood estimation (MLE) search region for each OFDM symbol based on a sign of the estimated carrier frequency offset, a maximum sampling frequency offset of the OFDM system, and a resolution of MLE, and performs the MLE within the range of the MLE search region which is calculated for each OFDM symbol.
2. The OFDM system of claim 1, wherein the offset tracker comprises:
a determiner which determines a search direction of the MLE according to the sign of the estimated carrier frequency offset;
a calculator which calculates the size of the MLE search region using the maximum sampling frequency offset of the OFDM system and the resolution of the MLE, and calculates the MLE search region for each OFDM symbol based on the calculated size; and
a detector which detects the sampling frequency offset by calculating a maximum correlation between the at least one pilot subcarrier of the received signal and at least one predefined reference pilot subcarrier within the MLE search region calculated for each OFDM symbol.
3. The OFDM system of claim 2, wherein, in order to detect the sampling frequency offset, the detector detects, among the at least one pilot subcarrier, a pilot subcarrier which has the maximum correlation with the at least one predefined reference pilot subcarrier.
4. The OFDM system of claim 2, wherein, if the sign of the estimated carrier frequency offset is positive, the at least one pilot subcarrier is received before the at least one predetermined reference pilot subcarrier, and
wherein, if the sign of the estimated carrier frequency offset is negative, the at least one pilot subcarrier is received after the at least one predetermined reference pilot subcarrier.
5. The OFDM system of claim 2, wherein the range of the MLE search region for each OFDM symbol has a start point which is an end point of an MLE search region of a previous OFDM symbol, and the end point which is a value obtained by adding the calculated size of the MLE search region to the start point.
6. The OFDM system of claim 1, wherein the size of the MLE search region is calculated based on an equation:
K
=
(
1
M
\u2062
\u2062
f
s
+
\u0394
\u2062
\u2062
f
s
N
s
\u2062
\u2062
\u0394
\u2062
\u2062
f
s
–
1
)
+
A
,
where K denotes the size of the MLE search region, \u0394fs denotes the maximum sampling frequency offset of the OFDM system, Ns denotes a size of each OFDM symbol, M denotes the resolution of the MLE, fs denotes the generated sampling frequency, and A denotes a predetermined constant.
7. The OFDM system of claim 1, further comprising a phase compensator which compensates a phase distortion which is changed due to the tracked sampling frequency offset.
8. The OFDM system of claim 1, further comprising a rob and stuff section which robs or stuffs one sample from or to a location shifted by one sample which is detected based on the tracked sampling frequency offset.
9. An orthogonal frequency division multiplexing (OFDM) system comprising:
an oscillator which generates a carrier frequency and a sampling frequency;
a converter which samples a received signal with the generated sampling frequency;
a frequency offset estimator which estimates a carrier frequency offset using at least one pilot subcarrier of the received signal;
a fast Fourier transformer (FFT) which transforms the sampled received signal into a frequency domain; and
an offset tracker which tracks a sampling frequency offset by calculating correlations between at least one of a reference pilot subcarrier predefined according to a resolution of maximum likelihood estimation (MLE) and the at least one pilot subcarrier of the received signal,
wherein the calculating of the correlations is performed in a search direction of the MLE determined according to a sign of the estimated carrier frequency offset.
10. A sampling frequency offset tracking method in an orthogonal frequency division multiplexing (OFDM) system, the sampling frequency offset tracking method comprising:
determining a search direction of maximum likelihood estimation (MLE) using a carrier frequency offset which is estimated using at least one pilot subcarrier of a received signal;
calculating a size of an MLE search region using a maximum sampling frequency offset of the OFDM system and a resolution of the MLE;
calculating a range of the MLE search region for each OFDM symbol based on the calculated size of the MLE search region; and
tracking a sampling frequency offset by calculating a maximum correlation between the at least one pilot subcarrier of the received signal and at least one predefined reference pilot subcarrier within the MLE search region calculated for each OFDM symbol.
11. The sampling frequency offset tracking method of claim 10, wherein the calculating of the maximum correlation comprises detecting, among the at least one pilot subcarrier, a pilot subcarrier which has the maximum correlation with the at least one predefined reference pilot subcarrier.
12. The sampling frequency offset tracking method of claim 10, the determining of the search direction of the MLE is performed according to a sign of the carrier frequency offset.
13. The sampling frequency offset tracking method of claim 12, wherein, if the sign of the estimated carrier frequency offset is positive, the at least one pilot subcarrier is received before the at least one predetermined reference pilot subcarrier, and
wherein, if the sign of the estimated carrier frequency offset is negative, the at least one pilot subcarrier is received after the at least one predetermined reference pilot subcarrier.
14. The sampling frequency offset tracking method of claim 10, wherein the size of the MLE search region is calculated based on an equation:
K
=
(
1
M
\u2062
\u2062
f
s
+
\u0394
\u2062
\u2062
f
s
N
s
\u2062
\u2062
\u0394
\u2062
\u2062
f
s
–
1
)
+
A
where K denotes the size of the MLE search region, \u0394fs denotes the maximum sampling frequency offset of the OFDM system, Ns denotes a size of each OFDM symbol, M denotes the resolution of the MLE, fs denotes a generated sampling frequency, and A denotes a predetermined constant.
15. The sampling frequency offset tracking method of claim 10, wherein the range of the MLE search region for each OFDM symbol has a start point which is an end point of an MLE search region of a previous OFDM symbol, and the end point which is a value obtained by adding the calculated size of the MLE search region to the start point.