1-6. (canceled)
7. A process for purifying 2-chloro-5-chloromethyl-1,3-thiazole represented by the formula (I):
which comprises:
treating a crude 2-chloro-5-chloromethyl-1,3-thiazole represented by the formula (I) with a lower alcohol, and then
distilling the treated 2-chloro-5-chloromethyl-1,3-thiazole.
8. The process for purifying 2-chloro-5-chloromethyl-1,3-thiazole according to claim 7, wherein the crude 2-chloro-5-chloromethyl-1,3-thiazole is treated with the lower alcohol by adding the lower alcohol to the crude 2-chloro-5-chloromethyl-1,3-thiazole, followed by stirring.
9. The process for purifying 2-chloro-5-chloromethyl-1,3-thiazole according to claim 7, wherein the crude 2-chloro-5-chloromethyl-1,3-thiazole is a reaction mixture obtained by reacting a 2-halogenoallyl isothiocyanate represented by the general formula (II):
wherein Hal represents a chlorine atom or a bromine atom, with a chlorinating agent in the presence of a solvent, or
wherein the crude 2-chloro-5-chloromethyl-1,3-thiazole is a residue obtained by distilling the solvent from the reaction mixture.
10. The process for purifying 2-chloro-5-chloromethyl-1,3-thiazole according to claim 9, wherein the crude 2-chloro-5-chloromethyl-1,3-thiazole is a residue obtained by distilling the solvent from the reaction mixture.
11. The process for purifying 2-chloro-5-chloromethyl-1,3-thiazole according to claim 7, wherein the lower alcohol is methanol.
12. The process for purifying 2-chloro-5-chloromethyl-1,3-thiazole according to claim 8, wherein the lower alcohol is methanol.
13. The process for purifying 2-chloro-5-chloromethyl-1,3-thiazole according to claim 9, wherein the lower alcohol is methanol.
14. The process for purifying 2-chloro-5-chloromethyl-1,3-thiazole according to claim 10, wherein the lower alcohol is methanol.
15. The process for purifying 2-chloro-5-chloromethyl-1,3-thiazole according to claim 9, wherein Hal is a chlorine atom.
16. The process for purifying 2-chloro-5-chloromethyl-1,3-thiazole according to claim 10, wherein Hal is a chlorine atom.
17. The process for purifying 2-chloro-5-chloromethyl-1,3-thiazole according to claim 13, wherein Hal is a chlorine atom.
18. The process for purifying 2-chloro-5-chloromethyl-1,3-thiazole according to claim 14, wherein Hal is a chlorine atom.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
1. A light emitting device comprising:
at least one single-die semiconductor light-emitting device coupleable with a power supply to emit visible light, the light-emitting device comprising:
a substrate; and
a plurality of layers of rare-earth doped group IV nanocrystal material (REGIVN);
wherein each layer comprises a different rare earth dopant for collectively emitting a visible light output when energized.
2. The light emitting device of claim 1 wherein the visible light is a white light.
3. The light emitting device of claim 1 wherein the REGIVN is a silicon or silicon carbide nanocrystal material.
4. The light emitting device of claim 1, wherein at least one layer comprises a respective rare earth dopant for each of red, blue and green.
5. The light emitting device of claim 1, wherein the plurality of layers comprises three layers with each layer containing a respective rare earth dopant for one of red, blue and green.
6. The light emitting device of claim 1, wherein the plurality of layers comprises three layers with each layer containing a respective rare earth dopant.
7. The light emitting device of claim 5 wherein the three layers are stacked on top of each other.
8. The light emitting device of claim 5 wherein the three layers are arranged adjacent to each other.
9. The light emitting device of claim 1, wherein said plurality of layers comprises:
a first layer doped with a group IV dopant selected from a group consisting of erbium, terbium and yttrium to provide green light;
a second layer doped with a group IV dopant selected from a group consisting of thulium and cerium to provide blue light; and
a third layer doped with a group IV dopant selected from a group consisting of europium and prasodymium to provide red light.
10. The light emitting device of claim 1, wherein said plurality of layers comprises:
a first layer doped with erbium to provide green and blue light; and
a second undoped layer of silicon nanocrystal material to provide red light.
11. The light emitting device of claim 1, wherein said plurality of layers comprises:
a first layer doped with erbium to provide green and blue light; and
a second layer doped with a group IV dopant selected from a group consisting of europium and prasodymium to provide red light.
12. The light emitting device of claim 1 further comprising a first electrode and a second transparent electrode across which a power supply signal can be applied to energize the light emitting device.
13. The light emitting device of claim 12 wherein the first electrode is a transparent conductive oxide electrode or semitransparent metal electrode.
14. The light emitting device of claim 1, wherein the substrate is a conductive substrate.
15. The light emitting device of claim 14 wherein the substrate is made of a material selected from a group consisting of SiC, GaN and ZnO.
16. The light emitting device of claim 1, wherein the substrate is a substantially non-conductive substrate.
17. The light emitting device of claim 16 wherein the substrate is made of a material selected from a group consisting of sapphire, silicon dioxide, fuse silica and AlN.
18. The light emitting device of claim 1, further comprising a housing member formed of a light-transmissive material, said housing member defining therewithin an interior volume.
19. The light emitting device of claim 18 further comprising first and second electrical contacts extending through said housing member and coupleable to a power supply which is constructed and arranged for imposing a voltage on said light emitting device, to induce emission of said white light.
20. An array of light emitting devices according to claim 1 and a user-responsive controller for selectively illuminating specific ones of said light-emitting devices.
21. A light emitting device according to claim 1 further comprising:
group II-VI or III-V nanocrystal material arranged to receive light emitted by the rare earth doped group IV nanocrystal material as a pump light source, the group II-VI or III-V nanocrystals fluorescing at a plurality of wavelengths when energized by the pump light source.
22. A light emitting device according to claim 21, comprising:
at least one layer of group II-VI or III-V nanocrystals arranged to receive light emitted by the at least one layer containing rare earth doped group IV nanocrystal material as a pump light source, the group II-VI or III-V nanocrystals fluorescing at a plurality of wavelengths when energized by the pump light source.
23. A light emitting device according to claim 22 wherein the group II-VI or III-V nanocrystals are selected from a group consisting of ZnS, CdS, ZnSe, CdSe, GaN, InP and GaP.
24. A light emitting device according to claim 22 wherein the plurality of wavelengths collectively produce white light.
25. A light emitting device according to claim 22, further comprising a top electrical contact layer wherein the layers are arranged in sequence as follows:
the substrate;
the at least one layer containing rare earth doped group IV nanocrystal material;
the top electrical contact layer; and
the at least one layer containing group II or VI nanocrystals;
wherein the at least one layer containing group II or VI nanocrystals uses photon energy to drive the nanocrystals.
26. A light emitting device according to claim 22, further comprising a top electrical contact layer, the layers arranged in sequence as follows:
the substrate;
the at least one layer containing rare earth doped group IV nanocrystal material;
the at least one layer containing group II or VI nanocrystals; and
the top electrical contact layer;
wherein the at least one layer containing group II or VI nanocrystals uses both electrical energy and photon energy to drive the nanocrystals.
27. A light-emitting device according to claim 1, wherein said device has a multi-layer structure comprising layers selected from the group consisting of nanocrystals of group IV, II-VI and III-V.
28. A light-emitting device according to claim 22, wherein primary radiation produced by the plurality of layers containing REDGIVN is down-converted by the at least one layer of group II-VI or III-V nanocrystals to at least two distinct and separable regions of red andor green andor blue light, with said at least two regions of red andor green andor blue light mixing to produce a different colored output.
29. A light-emitting device according to claim 22, wherein primary radiation produced by the plurality of layers containing REDGIVN is down-converted by the at least one layer of group II or VI nanocrystals to between 2 and 10 distinct and separable regions of white light and light of the color hue red, green or blue light.
30. A liquid crystal display comprising:
a backlight member including a multiplicity of light-emitting devices in accordance with claim 1.
31. The LCD of claim 30, further comprising:
at least one layer of group II or VI nanocrystals arranged to receive light emitted by the plurality of layers containing rare earth doped group IV nanocrystal material as a pump light source, the group II or VI nanocrystals fluorescing at a plurality of wavelengths when energized by the pump light source.
32. A display, comprising:
a viewable panel including a multiplicity of light-emitting devices, each light-emitting device comprising;
at least one single-die semiconductor light-emitting device in accordance with claim 1.
33. The display of claim 32, wherein each said at least one single-die semiconductor light-emitting device further comprises;
at least one layer of group II or VI nanocrystals arranged to receive light emitted by the plurality of layers containing rare earth doped group IV nanocrystal material as a pump light source, the group II or VI nanocrystals fluorescing at a plurality of wavelengths when energized by the pump light source.
34. A light emitting device comprising:
at least one single-die semiconductor light-emitting device coupleable with a power supply to emit visible light, the light-emitting device comprising rare-earth doped group IV nanocrystal material (REGIVN); and
at least one layer of group II-VI or III-V nanocrystals arranged to receive light emitted by the at least one layer containing rare earth doped group IV nanocrystal material as a pump light source, the group II-VI or III-V nanocrystals fluorescing at a plurality of wavelengths when energized by the pump light source;
wherein primary radiation produced by the at least one layer containing REDGIVN is down-converted by the at least one layer of group II-VI or III-V nanocrystals to at least two distinct and separable regions of red andor green andor blue light, with said at least two regions of red andor green andor blue light mixing to produce a different colored output.
35. A light emitting device comprising:
at least one single-die semiconductor light-emitting device coupleable with a power supply to emit visible light, the light-emitting device comprising rare-earth doped group IV nanocrystal material (REGIVN); and
at least one layer of group II-VI or III-V nanocrystals arranged to receive light emitted by the at least one layer containing rare earth doped group IV nanocrystal material as a pump light source, the group II-VI or III-V nanocrystals fluorescing at a plurality of wavelengths when energized by the pump light source;
wherein primary radiation produced by the at least one layer containing REDGIVN is down-converted by the at least one layer of group II or VI nanocrystals to between 2 and 10 distinct and separable regions of white light and light of the color hue red, green or blue light.