1.-27. (canceled)
28. A compound of Formula WH:
wherein:
K1 is selected from the group consisting of N, O, S, Se, Te, and CH;
S1, S2, S7, S8, S9, S12, S13, and S14 are independently selected from the group consisting of H, aryl, phenyl, cycloalkyl, alkyl, alkenyl, alkynyl, halogen, alkoxy, alkylthio, perfluoroalkyl, perfluoroaryl, pyridyl, cyano, thiocyanato, nitro, amino, alkylamino, acyl, sulfoxyl, sulfonyl, imido, amido, and carbamoyl;
and wherein from one to two of S1, S2, S7, S8, S9, S12, S13, and S14 may optionally be independently selected linking groups Q, wherein said linking groups Q are of the formula:
wherein:
n is from 0 to 10;
R3 may be present or absent;
R1, R2, and R3 are each independently selected from the group consisting of ethene, ethyne, aryl, and heteroaryl groups, which aryl and heteroaryl groups may be unsubstituted or substituted one or more times with H, aryl, phenyl, cycloalkyl, alkyl, alkenyl, alkynyl, halogen, alkoxy, alkylthio, perfluoroalkyl, perfluoroaryl, pyridyl, cyano, thiocyanato, nitro, amino, alkylamino, acyl, sulfoxyl, sulfonyl, imido, amido, and carbamoyl; and
Y is a protected or unprotected reactive substituent selected from the group consisting of hydroxy, thio, seleno, telluro, ester, carboxylic acid, boronic acid, phenol, silane, sulfonic acid, phosphonic acid, alkylthiol, formyl, halo, alkenyl, alkynyl, haloalkyl, alkyl phosphonate, alkyl sulfonate, alkyl carboxylate, and alkyl boronate groups;
subject to the proviso that S1 and S2 are not simultaneously alkyl.
29. The compound according to claim 28, subject to the proviso that S1 and S2 are not simultaneously alkyl or H.
30. The compound according to claim 28, wherein S1 is selected from the group consisting of Q, aryl, phenyl, cycloalkyl, alkenyl, alkynyl, halogen, alkoxy, alkylthio, perfluoroalkyl, perfluoroaryl, pyridyl, cyano, thiocyanato, nitro, amino, alkylamino, acyl, sulfoxyl, sulfonyl, imido, amido, and carbamoyl.
31. The compound according to claim 28, wherein S2 is selected from the group consisting of Q, aryl, phenyl, cycloalkyl, alkenyl, alkynyl, halogen, alkoxy, alkylthio, perfluoroalkyl, perfluoroaryl, pyridyl, cyano, thiocyanato, nitro, amino, alkylamino, acyl, sulfoxyl, sulfonyl, imido, amido, and carbamoyl
32. The compound according to claim 28, wherein S1 is a linking group Q.
33. The compound according to claim 28, wherein S2 is a linking group Q.
34. The compound according to claim 28, wherein K1 is selected from the group consisting of N, O, S, Se and Te.
35. The compound according to claim 28, wherein K1 is N.
36. The compound according to claim 28, wherein S1, S2, S7, S8, S9, S12, S13, and S14 are all alkyl.
37. A method of making a compound of Formula WH:
wherein:
K1 is selected from the group consisting of N, O, S, Se, Te, and CH;
S1, S2, S7, S8, S9, S12, S13, and S14 are independently selected from the group consisting of H, aryl, phenyl, cycloalkyl, alkyl, alkenyl, alkynyl, halogen, alkoxy, alkylthio, perfluoroalkyl, perfluoroaryl, pyridyl, cyano, thiocyanato, nitro, amino, alkylamino, acyl, sulfoxyl, sulfonyl, imido, amido, and carbamoyl;
and wherein from one to two of S1, S2, S7, S8, S9, S12, S13, and S14 may optionally be independently selected linking groups Q, wherein said linking groups Q are of the formula:
wherein:
n is from 0 to 10;
R3 may be present or absent;
R1, R2, and R3 are each independently selected from the group consisting of ethene, ethyne, aryl, and heteroaryl groups, which aryl and heteroaryl groups may be unsubstituted or substituted one or more times with H, aryl, phenyl, cycloalkyl, alkyl, alkenyl, alkynyl, halogen, alkoxy, alkylthio, perfluoroalkyl, perfluoroaryl, pyridyl, cyano, thiocyanato, nitro, amino, alkylamino, acyl, sulfoxyl, sulfonyl, imido, amido, and carbamoyl;
Y is a protected or unprotected reactive substituent selected from the group consisting of hydroxy, thio, seleno, telluro, ester, carboxylic acid, boronic acid, phenol, silane, sulfonic acid, phosphonic acid, alkylthiol, formyl, halo, alkenyl, alkynyl, haloalkyl, alkyl phosphonate, alkyl sulfonate, alkyl carboxylate, and alkyl boronate groups;
said method comprising reacting a compound of Formula III
\u2003in an organic solvent in the presence of Ti(0) to form the compound of Formula WH.
38. A compound according to Formula III:
wherein:
K1 is selected from the group consisting of N, O, S, Se, Te, and CH;
S1, S2, S7, S8, S9, S12, S13, and S14 are independently selected from the group consisting of H, aryl, phenyl, cycloalkyl, alkyl, alkenyl, alkynyl, halogen, alkoxy, alkylthio, perfluoroalkyl, perfluoroaryl, pyridyl, cyano, thiocyanato, nitro, amino, alkylamino, acyl, sulfoxyl, sulfonyl, imido, amido, and carbamoyl;
and wherein from one to two of S1, S2, S7, S8, S9, S12, S13, and S14 may optionally be independently selected linking groups Q, wherein said linking groups Q are of the formula:
wherein:
n is from 0 to 10;
R3 may be present or absent;
R1, R2, and R3 are each independently selected from the group consisting of ethene, ethyne, aryl, and heteroaryl groups, which aryl and heteroaryl groups may be unsubstituted or substituted one or more times with H, aryl, phenyl, cycloalkyl, alkyl, alkenyl, alkynyl, halogen, alkoxy, alkylthio, perfluoroalkyl, perfluoroaryl, pyridyl, cyano, thiocyanato, nitro, amino, alkylamino, acyl, sulfoxyl, sulfonyl, imido, amido, and carbamoyl; and
Y is a protected or unprotected reactive substituent selected from the group consisting of hydroxy, thio, seleno, telluro, ester, carboxylic acid, boronic acid, phenol, silane, sulfonic acid, phosphonic acid, alkylthiol, formyl, halo, alkenyl, alkynyl, haloalkyl, alkyl phosphonate, alkyl sulfonate, alkyl carboxylate, and alkyl boronate groups.
39. A method of making a compound of Formula III:
wherein:
K1 is selected from the group consisting of N, O, S, Se, Te, and CH;
S1, S2, S7, S8, S9, S12, S13, and S14 are independently selected from the group consisting of H, aryl, phenyl, cycloalkyl, alkyl, alkenyl, alkynyl, halogen, alkoxy, alkylthio, perfluoroalkyl, perfluoroaryl, pyridyl, cyano, thiocyanato, nitro, amino, alkylamino, acyl, sulfoxyl, sulfonyl, imido, amido, and carbamoyl;
and wherein from one to two of S1, S2, S7, S8, S9, S12, S13, and S14 may optionally be independently selected linking groups Q, wherein said linking groups Q are of the formula:
wherein:
n is from 0 to 10;
R3 may be present or absent;
R1, R2, and R3 are each independently selected from the group consisting of ethene, ethyne, aryl, and heteroaryl groups, which aryl and heteroaryl groups may be unsubstituted or substituted one or more times with H, aryl, phenyl, cycloalkyl, alkyl, alkenyl, alkynyl, halogen, alkoxy, alkylthio, perfluoroalkyl, perfluoroaryl, pyridyl, cyano, thiocyanato, nitro, amino, alkylamino, acyl, sulfoxyl, sulfonyl, imido, amido, and carbamoyl; and
Y is a protected or unprotected reactive substituent selected from the group consisting of hydroxy, thio, seleno, telluro, ester, carboxylic acid, boronic acid, phenol, shame, sulfonic acid, phosphonic acid, alkylthiol, formyl, halo, alkenyl, alkynyl, haloalkyl, alkyl phosphonate, alkyl sulfonate, alkyl carboxylate, and alkyl boronate groups;
comprising cyclizing a compound of Formula II:
in an organic solvent under reducing conditions to produce a compound of Formula III.
40. A compound of Formula II:
wherein:
K1 is selected from the group consisting of N, O, S, Se, Te, and CH;
S1, S2, S7, S8, S9, S12, S13, and S14 are independently selected from the group consisting of H, aryl, phenyl, cycloalkyl, alkyl, alkenyl, alkynyl, halogen, alkoxy, alkylthio, perfluoroalkyl, perfluoroaryl, pyridyl, cyano, thiocyanato, nitro, amino, alkylamino, acyl, sulfoxyl, sulfonyl, imido, amido, and carbamoyl;
and wherein from one to two of S1, S2, S7, S8, S9, S12, S13, and S14 may optionally be independently selected linking groups Q, wherein said linking groups Q are of the formula:
wherein:
n is from 0 to 10;
R3 may be present or absent;
R1, R2, and R3 are each independently selected from the group consisting of ethene, ethyne, aryl, and heteroaryl groups, which aryl and heteroaryl groups may be unsubstituted or substituted one or more times with H, aryl, phenyl, cycloalkyl, alkyl, alkenyl, alkynyl, halogen, alkoxy, alkylthio, perfluoroalkyl, perfluoroaryl, pyridyl, cyano, thiocyanato, nitro, amino, alkylamino, acyl, sulfoxyl, sulfonyl, imido, amido, and carbamoyl; and
Y is a protected or unprotected reactive substituent selected from the group consisting of hydroxy, thio, seleno, telluro, ester, carboxylic acid, boronic acid, phenol, silane, sulfonic acid, phosphonic acid, alkylthiol, formyl, halo, alkenyl, alkynyl, haloalkyl, alkyl phosphonate, alkyl sulfonate, alkyl carboxylate, and alkyl boronate groups.
41. A compound of Formula X:
wherein:
M is a metal selected from the group consisting of Cu, Zn, Mg, Pt, Pd, Sn and Al, or M is absent;
K1, K2 and K4 are hetero atoms independently selected from the group consisting of N, O, S, Se, Te, and CH;
K3 is N;
S1, S2, S3, S4 S5, S6, S8, S9, S10, S11, S12, and S14 are independently selected from the group consisting of H, aryl, phenyl, cycloalkyl, alkyl, alkenyl, alkynyl, halogen, alkoxy, alkylthio, perfluoroalkyl, perfluoroaryl, pyridyl, cyano, thiocyanato, nitro, amino, alkylamino, acyl, sulfoxyl, sulfonyl, imido, amido, and carbamoyl;
S7 and S13 are together \u2550O;
and wherein from one to four of S1, S2, S3, S4, S5, S6, S7, S8, S9, S10, S11, S12, S13, and S14 are independently selected linking groups Q, wherein said linking groups Q are of the formula:
wherein:
n is from 0 to 10;
R3 may be present or absent;
R1, R2, and R3 are each independently selected from the group consisting of ethene, ethyne, aryl, and heteroaryl groups, which aryl and heteroaryl groups may be unsubstituted or substituted one or more times with H, aryl, phenyl, cycloalkyl, alkyl, alkenyl, alkynyl, halogen, alkoxy, alkylthio, perfluoroalkyl, perfluoroaryl, pyridyl, cyano, thiocyanato, nitro, amino, alkylamino, acyl, sulfoxyl, sulfonyl, imido, amido, and carbamoyl; and
Y is a protected or unprotected reactive substituent selected from the group consisting of hydroxy, thio, seleno, telluro, ester, carboxylic acid, boronic acid, phenol, silane, sulfonic acid, phosphonic acid, alkylthiol, formyl, halo, alkenyl, alkynyl, haloalkyl, alkyl phosphonate, alkyl sulfonate, alkyl carboxylate, and alkyl boronate groups.
42. The compound according to claim 41, wherein S1 is a linking group Q.
43. The compound according to claim 41, wherein S1 is iodo.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
1. A method for receiving control information by a user equipment in a wireless communication system to which a carrier aggregation scheme is applied, the method comprising the steps of:
receiving a control region from a base station through one or more of a plurality of component carriers; and
performing blind decoding for the control region to acquire the control information allocated to the user equipment,
wherein the control region includes control information on the one or more component carriers or control information on the other component carriers.
2. The method according to claim 1, further comprising the step of receiving information on the one or more component carriers from the base station before receiving the control region.
3. The method according to claim 1, wherein the step of receiving control information includes performing blind decoding for the same search space corresponding to each of the one or more component carriers.
4. The method according to claim 1, wherein the control information is subjected to channel coding of one codeword basis.
5. The method according to claim 1, wherein the one or more component carriers are divided into component carriers for downlink control information and component carriers for uplink control information.
6. A user equipment in a wireless communication system to which a carrier aggregation scheme is applied, the user equipment comprising:
a receiving module receiving a control region from a base station through one or more of a plurality of component carriers; and
a processor performing blind decoding for the control region to acquire the control information allocated to the user equipment,
wherein the control region includes control information on the one or more component carriers or control information on the other component carriers.
7. The user equipment according to claim 6, wherein the receiving module receives information on the one or more component carriers from the base station.
8. The user equipment according to claim 6, wherein the processor performs blind decoding for the same search space corresponding to each of the one or more component carriers.
9. The user equipment according to claim 6, wherein the control information is subjected to channel coding of one codeword basis.
10. The user equipment according to claim 6, wherein the one or more component carriers are divided into component carriers for downlink control information and component carriers for uplink control information.