1. A catalyst composition comprising a contact product of at least one dinuclear metallocene compound and at least one activator-support,
wherein the at least one dinuclear metallocene compound has the formula:
wherein:
X1 and X2 independently are a halide or a substituted or unsubstituted aliphatic, aromatic, or cyclic group, or a combination thereof;
X3 and X4 independently are a substituted cyclopentadienyl, indenyl, or fluorenyl group, any substituents on X3 and X4 other than a bridging group independently are a hydrogen atom or a substituted or unsubstituted alkyl or alkenyl group;
A2 is a substituted bridging group connecting X3 and X4, the substituted bridging group comprising either a silicon bridging atom, a germanium bridging atom, a tin bridging atom, a carbon bridging atom, or a bridging chain of 2 to 5 carbon atoms, any substituents on A2 other than an alkenyl linking group independently are a hydrogen atom, or a substituted or unsubstituted aliphatic, aromatic, or cyclic group, or a combination thereof;
M is Zr, Hf, or Ti;
RX, RY, and RZ independently are a hydrogen atom, or a substituted or unsubstituted aliphatic, aromatic, or cyclic group, or a combination thereof; and
n is an integer in a range from 0 to 12, inclusive.
2. The catalyst composition of claim 1, wherein the at least one dinuclear metallocene compound is:
or a combination thereof; wherein Ph is an abbreviation for phenyl.
3. The catalyst composition of claim 1, wherein the at least one activator-support is fluorided alumina, chlorided alumina, bromided alumina, sulfated alumina, fluorided silica-alumina, chlorided silica-alumina, bromided silica-alumina, sulfated silica-alumina, fluorided silica-zirconia, chlorided silica-zirconia, bromided silica-zirconia, sulfated silica-zirconia, or any combination thereof.
4. The catalyst composition of claim 1, wherein the at least one activator-support comprises a solid oxide treated with an electron-withdrawing anion, wherein:
the solid oxide is silica, alumina, silica-alumina, aluminum phosphate, heteropolytungstates, titania, zirconia, magnesia, boria, zinc oxide, any mixed oxides thereof, or any mixture thereof; and
the electron-withdrawing anion is fluoride, chloride, bromide, phosphate, triflate, bisulfate, sulfate, or any combination thereof.
5. The catalyst composition of claim 1, wherein the at least one activator-support further comprises a metal or metal ion, and wherein the metal or metal ion is zinc, nickel, vanadium, silver, copper, gallium, tin, tungsten, molybdenum, or any combination thereof.
6. The catalyst composition of claim 1, wherein the at least one activator-support comprises a clay mineral, a pillared clay, an exfoliated clay, an exfoliated clay gelled into another oxide matrix, a layered silicate mineral, a non-layered silicate mineral, a layered aluminosilicate mineral, a non-layered aluminosilicate mineral, or any combination thereof.
7. The catalyst composition of claim 1, further comprising at least one organoaluminum compound having the formula:
Al(X5)m(X6)3-m;
wherein:
X5 is a hydrocarbyl;
X6 is an alkoxide or an aryloxide, a halide, or a hydride; and
m is from 1 to 3, inclusive.
8. The catalyst composition of claim 7, wherein the at least one organoaluminum compound is trimethylaluminum, triethylaluminum, tri-n-propylaluminum, diethylaluminum ethoxide, tri-n-butylaluminum, diisobutylaluminum hydride, triisobutylaluminum, diethylaluminum chloride, or any combination thereof.
9. The catalyst composition of claim 1, further comprising at least one optional co-catalyst, wherein the at least one optional co-catalyst is at least one aluminoxane compound, at least one organozinc compound, at least one organoboron or organoborate compound, at least one ionizing ionic compound, or any combination thereof.
10. The catalyst composition of claim 1, wherein in formula (I):
X1 and X2 independently are a methyl group, a phenyl group, or a chlorine atom;
X3 is a substituted cyclopentadienyl group and X4 is a substituted fluorenyl group;
A2 comprises a carbon bridging atom;
M is Zr or Hf;
RX, RY, and RZ are hydrogen atoms; and
n is 0, 1, 2, 3, or 4.
11. A catalyst composition comprising a contact product of at least one dinuclear metallocene compound and at least one compound selected from at least one aluminoxane compound, at least one organozinc compound, at least one organoboron or organoborate compound, at least one ionizing ionic compound, or any combination thereof;
wherein the at least one dinuclear metallocene compound has the formula:
wherein:
X1 and X2 independently are a halide or a substituted or unsubstituted aliphatic, aromatic, or cyclic group, or a combination thereof;
X3 and X4 independently are a substituted cyclopentadienyl, indenyl, or fluorenyl group, any substituents on X3 and X4 other than a bridging group independently are a hydrogen atom or a substituted or unsubstituted alkyl or alkenyl group;
A2 is a substituted bridging group connecting X3 and X4, the substituted bridging group comprising either a silicon bridging atom, a germanium bridging atom, a tin bridging atom, a carbon bridging atom, or a bridging chain of 2 to 5 carbon atoms, any substituents on A2 other than an alkenyl linking group independently are a hydrogen atom, or a substituted or unsubstituted aliphatic, aromatic, or cyclic group, or a combination thereof;
M is Zr, Hf, or Ti;
RX, RY, and RZ independently are a hydrogen atom, or a substituted or unsubstituted aliphatic, aromatic, or cyclic group, or a combination thereof; and
n is an integer in a range from 0 to 12, inclusive.
12. The catalyst composition of claim 11, wherein the at least one compound is at least one aluminoxane compound, and the at least one aluminoxane compound comprises:
(a) a cyclic aluminoxane having the formula:
wherein:
R is a linear or branched alkyl having from 1 to 10 carbon atoms; and
p is an integer from 3 to 20;
(b) a linear aluminoxane having the formula:
wherein:
R is a linear or branched alkyl having from 1 to 10 carbon atoms; and
q is an integer from 1 to 50;
(c) a cage aluminoxane having the formula Rt5r+\u03b1Rbr\u2212+Al4rO3r,
wherein:
Rt is a terminal linear or branched alkyl group having from 1 to 10 carbon atoms;
Rb is a bridging linear or branched alkyl group having from 1 to 10 carbon atoms;
r is 3 or 4; and
\u03b1 is equal to nAl(3)\u2212nO(2)+nO(4), wherein nAl(3) is the number of three coordinate aluminum atoms, nO(2) is the number of two coordinate oxygen atoms, and nO(4) is the number of 4 coordinate oxygen atoms; or
any combination thereof.
13. The catalyst composition of claim 11, wherein the at least one compound is at least one organoboron or organoborate compound, and the at least one organoboron or organoborate compound is N,N-dimethylanilinium tetrakis(pentafluorophenyl)borate, lithium tetrakis(pentafluorophenyl)borate, triphenylcarbenium tetrakis(pentafluorophenyl)borate, N,N-dimethylanilinium tetrakis3,5-bis(trifluoromethyl)phenylborate, triphenylcarbenium tetrakis3,5-bis(trifluoromethyl)phenylborate, tris(pentafluorophenyl)boron, tris3,5-bis(trifluoromethyl)phenylboron, or any combination thereof.
14. The catalyst composition of claim 11, wherein the at least one compound is at least one ionizing ionic compound, and the at least one ionizing ionic compound is tri(n-butyl)ammonium tetrakis(p-tolyl)borate, tri(n-butyl)ammonium tetrakis(m-tolyl)borate, tri(n-butyl)ammonium tetrakis(2,4-dimethyl)borate, tri(n-butyl)ammonium tetrakis(3,5-dimethylphenyl)borate, tri(n-butyl)ammonium tetrakis3,5-bis(trifluoromethyl)phenylborate, tri(n-butyl)ammonium tetrakis(pentafluorophenyl)borate, N,N-dimethylanilinium tetrakis(p-tolyl)borate, N,N-dimethylanilinium tetrakis(m-tolyl)borate, N,N-dimethylanilinium tetrakis(2,4-dimethylphenyl)borate, N,N-dimethylanilinium tetrakis(3,5-dimethylphenyl)borate, N,N-dimethylanilinium tetrakis3,5-bis(trifluoromethyl)phenylborate, N,N-dimethylanilinium tetrakis(pentafluorophenyl)borate, triphenylcarbenium tetrakis(p-tolyl)borate, triphenylcarbenium tetrakis(m-tolyl)borate, triphenylcarbenium tetrakis(2,4-dimethylphenyl)borate, triphenylcarbenium tetrakis(3,5-dimethylphenyl)borate, triphenylcarbenium tetrakis3,5-bis(trifluoromethyl)phenylborate, triphenylcarbenium tetrakis(pentafluorophenyl)borate, tropylium tetrakis(p-tolyl)borate, tropylium tetrakis(m-tolyl)borate, tropylium tetrakis(2,4-dimethylphenyl)borate, tropylium tetrakis(3,5-dimethylphenyl)borate, tropylium tetrakis3,5-bis(trifluoromethyl)phenylborate, tropylium tetrakis(pentafluorophenyl)borate, lithium tetrakis(pentafluorophenyl)borate, lithium tetraphenylborate, lithium tetrakis(p-tolyl)borate, lithium tetrakis(m-tolyl)borate, lithium tetrakis(2,4-dimethylphenyl)borate, lithium tetrakis(3,5-dimethylphenyl)borate, lithium tetrafluoroborate, sodium tetrakis(pentafluorophenyl)borate, sodium tetraphenylborate, sodium tetrakis(p-tolyl)borate, sodium tetrakis(m-tolyl)borate, sodium tetrakis(2,4-dimethylphenyl)borate, sodium tetrakis(3,5-dimethylphenyl)borate, sodium tetrafluoroborate, potassium tetrakis(pentafluorophenyl)borate, potassium tetraphenylborate, potassium tetrakis(p-tolyl)borate, potassium tetrakis(m-tolyl)borate, potassium tetrakis(2,4-dimethylphenyl)borate, potassium tetrakis(3,5-dimethylphenyl)borate, potassium tetrafluoro-borate, lithium tetrakis(pentafluorophenyl)aluminate, lithium tetraphenylaluminate, lithium tetrakis(p-tolyl)aluminate, lithium tetrakis(m-tolyl)aluminate, lithium tetrakis(2,4-dimethylphenyl)aluminate, lithium tetrakis(3,5-dimethylphenyl)aluminate, lithium tetrafluoroaluminate, sodium tetrakis(pentafluorophenyl)aluminate, sodium tetraphenylaluminate, sodium tetrakis(p-tolyl)aluminate, sodium tetrakis(m-tolyl)aluminate, sodium tetrakis(2,4-dimethylphenyl)aluminate, sodium tetrakis(3,5-dimethylphenyl)aluminate, sodium tetrafluoroaluminate, potassium tetrakis(pentafluorophenyl)aluminate, potassium tetraphenylaluminate, potassium tetrakis(p-tolyl)aluminate, potassium tetrakis(m-tolyl)aluminate, potassium tetrakis(2,4-dimethylphenyl)aluminate, potassium tetrakis (3,5-dimethylphenyl)aluminate, potassium tetrafluoroaluminate, or any combination thereof.
15. The catalyst composition of claim 11, wherein the at least one dinuclear metallocene compound is:
or a combination thereof; wherein Ph is an abbreviation for phenyl.
16. The catalyst composition of claim 11, wherein in formula (I):
X1 and X2 independently are a methyl group, a phenyl group, or a chlorine atom;
X3 is a substituted cyclopentadienyl group and X4 is a substituted fluorenyl group;
A2 comprises a carbon bridging atom;
M is Zr or Hf;
RX, RY, and RZ are hydrogen atoms; and
n is 0, 1, 2, 3, or 4.
17. A catalyst composition comprising a contact product of at least one dinuclear metallocene compound and at least one activator-support,
wherein the at least one dinuclear metallocene compound has the formula:
wherein:
X1 and X2 independently are a methyl group, a phenyl group, a benzyl group, or a halide;
X3 and X4 independently are a substituted cyclopentadienyl, indenyl, or fluorenyl group, any substituents on X3 and X4 other than a bridging group independently are a hydrogen atom, a methyl group, an ethyl group, a propyl group, a n-butyl group, a t-butyl group, or a hexyl group;
A2 is a substituted bridging group connecting X3 and X4, the substituted bridging group comprising either a silicon bridging atom, a carbon bridging atom, or a bridging chain of 2 to 5 carbon atoms, any substituents on A2 other than an alkenyl linking group independently are a hydrogen atom, a methyl group, a phenyl group, or a benzyl group;
M is Zr, Hf, or Ti;
RX, RY, and RZ independently are a hydrogen atom, a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group, a phenyl group, a tolyl group, or a benzyl group; and
n is an integer in a range from 0 to 7, inclusive; and
the at least one activator-support comprises a solid oxide treated with an electron-withdrawing anion, wherein:
the solid oxide is silica, alumina, silica-alumina, aluminum phosphate, heteropolytungstates, titania, zirconia, magnesia, boria, zinc oxide, any mixed oxides thereof, or any mixture thereof; and
the electron-withdrawing anion is fluoride, chloride, bromide, phosphate, triflate, bisulfate, sulfate, or any combination thereof.
18. The catalyst composition of claim 17, further comprising at least one organoaluminum compound, wherein the at least one organoaluminum compound is trimethylaluminum, triethylaluminum, tri-n-propylaluminum, diethylaluminum ethoxide, tri-n-butylaluminum, diisobutylaluminum hydride, triisobutylaluminum, diethylaluminum chloride, or any combination thereof; and
wherein the at least one activator-support is fluorided alumina, chlorided alumina, bromided alumina, sulfated alumina, fluorided silica-alumina, chlorided silica-alumina, bromided silica-alumina, sulfated silica-alumina, fluorided silica-zirconia, chlorided silica-zirconia, bromided silica-zirconia, sulfated silica-zirconia, or any combination thereof.
19. A catalyst composition comprising a contact product of at least one dinuclear metallocene compound and at least one compound selected from at least one aluminoxane compound, at least one organozinc compound, at least one organoboron or organoborate compound, at least one ionizing ionic compound, or any combination thereof;
wherein the at least one dinuclear metallocene compound has the formula:
wherein:
X1 and X2 independently are a methyl group, a phenyl group, a benzyl group, or a halide;
X3 and X4 independently are a substituted cyclopentadienyl, indenyl, or fluorenyl group, any substituents on X3 and X4 other than a bridging group independently are a hydrogen atom, a methyl group, an ethyl group, a propyl group, a n-butyl group, a t-butyl group, or a hexyl group;
A2 is a substituted bridging group connecting X3 and X4, the substituted bridging group comprising either a silicon bridging atom, a carbon bridging atom, or a bridging chain of 2 to 5 carbon atoms, any substituents on A2 other than an alkenyl linking group independently are a hydrogen atom, a methyl group, a phenyl group, or a benzyl group;
M is Zr, Hf, or Ti;
RX, RY, and RZ independently are a hydrogen atom, a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group, a phenyl group, a tolyl group, or a benzyl group; and
n is an integer in a range from 0 to 7, inclusive.
20. The catalyst composition of claim 19, wherein the at least one compound is at least one aluminoxane compound, and the at least one aluminoxane compound comprises:
(a) a cyclic aluminoxane having the formula:
wherein:
R is a linear or branched alkyl having from 1 to 10 carbon atoms; and
p is an integer from 3 to 20;
(b) a linear aluminoxane having the formula:
wherein:
R is a linear or branched alkyl having from 1 to 10 carbon atoms; and
q is an integer from 1 to 50;
(c) a cage aluminoxane having the formula Rt5r+\u03b1Rbr\u2212\u03b1Al4rO3r,
wherein:
Rt is a terminal linear or branched alkyl group having from 1 to 10 carbon atoms;
Rb is a bridging linear or branched alkyl group having from 1 to 10 carbon atoms;
r is 3 or 4; and
\u03b1 is equal to nAl(3)\u2212nO(2)+nO(4), wherein nAl(3) is the number of three coordinate aluminum atoms, nO(2) is the number of two coordinate oxygen atoms, and nO(4) is the number of 4 coordinate oxygen atoms; or
any combination thereof.
21. The catalyst composition of claim 19, wherein the at least one compound is at least one organoboron or organoborate compound, and the at least one organoboron or organoborate compound is N,N-dimethylanilinium tetrakis(pentafluorophenyl)borate, lithium tetrakis-(pentafluorophenyl)borate, triphenylcarbenium tetrakis(pentafluorophenyl)borate, N,N-dimethylanilinium tetrakis3,5-bis(trifluoromethyl)phenylborate, triphenylcarbenium tetrakis3,5-bis(trifluoromethyl)phenylborate, tris(pentafluorophenyl)boron, tris3,5-bis(trifluoromethyl)phenylboron, or any combination thereof.
22. The catalyst composition of claim 19, wherein the at least one compound is at least one ionizing ionic compound, and the at least one ionizing ionic compound is tri(n-butyl)ammonium tetrakis(p-tolyl)borate, tri(n-butyl)ammonium tetrakis(m-tolyl)borate, tri(n-butyl)ammonium tetrakis(2,4-dimethyl)borate, tri(n-butyl)ammonium tetrakis(3,5-dimethylphenyl)borate, tri(n-butyl)ammonium tetrakis3,5-bis(trifluoromethyl)phenylborate, tri(n-butyl)ammonium tetrakis(pentafluorophenyl)borate, N,N-dimethylanilinium tetrakis(p-tolyl)borate, N,N-dimethylanilinium tetrakis(m-tolyl)borate, N,N-dimethylanilinium tetrakis(2,4-dimethylphenyl)borate, N,N-dimethylanilinium tetrakis(3,5-dimethylphenyl)borate, N,N-dimethylanilinium tetrakis3,5-bis(trifluoromethyl)phenylborate, N,N-dimethylanilinium tetrakis(pentafluorophenyl)borate, triphenylcarbenium tetrakis(p-tolyl)borate, triphenylcarbenium tetrakis(m-tolyl)borate, triphenylcarbenium tetrakis(2,4-dimethylphenyl)borate, triphenylcarbenium tetrakis(3,5-dimethylphenyl)borate, triphenylcarbenium tetrakis3,5-bis(trifluoromethyl)phenylborate, triphenylcarbenium tetrakis(pentafluorophenyl)borate, tropylium tetrakis(p-tolyl)borate, tropylium tetrakis(m-tolyl)borate, tropylium tetrakis(2,4-dimethylphenyl)borate, tropylium tetrakis(3,5-dimethylphenyl)borate, tropylium tetrakis3,5-bis(trifluoromethyl)phenylborate, tropylium tetrakis(pentafluorophenyl)borate, lithium tetrakis(pentafluorophenyl)borate, lithium tetraphenylborate, lithium tetrakis(p-tolyl)borate, lithium tetrakis(m-tolyl)borate, lithium tetrakis(2,4-dimethylphenyl)borate, lithium tetrakis(3,5-dimethylphenyl)borate, lithium tetrafluoroborate, sodium tetrakis(pentafluorophenyl)borate, sodium tetraphenylborate, sodium tetrakis(p-tolyl)borate, sodium tetrakis(m-tolyl)borate, sodium tetrakis(2,4-dimethylphenyl)borate, sodium tetrakis(3,5-dimethylphenyl)borate, sodium tetrafluoroborate, potassium tetrakis(pentafluorophenyl)borate, potassium tetraphenylborate, potassium tetrakis(p-tolyl)borate, potassium tetrakis(m-tolyl)borate, potassium tetrakis(2,4-dimethylphenyl)borate, potassium tetrakis(3,5-dimethylphenyl)borate, potassium tetrafluoro-borate, lithium tetrakis(pentafluorophenyl)aluminate, lithium tetraphenylaluminate, lithium tetrakis(p-tolyl)aluminate, lithium tetrakis(m-tolyl)aluminate, lithium tetrakis(2,4-dimethylphenyl)aluminate, lithium tetrakis(3,5-dimethylphenyl)aluminate, lithium tetrafluoroaluminate, sodium tetrakis(pentafluorophenyl)aluminate, sodium tetraphenylaluminate, sodium tetrakis(p-tolyl)aluminate, sodium tetrakis(m-tolyl)aluminate, sodium tetrakis(2,4-dimethylphenyl)aluminate, sodium tetrakis(3,5-dimethylphenyl)aluminate, sodium tetrafluoroaluminate, potassium tetrakis(pentafluorophenyl)aluminate, potassium tetraphenylaluminate, potassium tetrakis(p-tolyl)aluminate, potassium tetrakis(m-tolyl)aluminate, potassium tetrakis(2,4-dimethylphenyl)aluminate, potassium tetrakis (3,5-dimethylphenyl)aluminate, potassium tetrafluoroaluminate, or any combination thereof.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
1. An inlet guide vane that is turnably installed about an axis line at a suction port into which a fluid is drawn by rotation of an impeller in order to adjust a suction amount and flow direction of the fluid, the inlet guide vane comprising:
a shaft that is turnably supported by inserting a round bar-shaped shaft main body portion thereof in a bearing sleeve; and
a plate-shaped vane main body that is joined with the shaft and projects from an inner periphery surface of the suction port to a central portion of the suction port,
the shaft including a flange portion that is provided at a distal end side in a direction of the axis line to join with the vane main body and that extends to an outside in a direction perpendicular to the axis line so as to be extended outward in a radial direction of the bearing sleeve,
wherein a width of the flange portion in the direction perpendicular to the axis line is a size of at least 1.5 times an outer diameter of the shaft main body portion andor at least \u2153 of a maximum width of the vane main body.
2. A compressor that compresses a fluid with a compression mechanism that has an impeller and a diffuser and is capable of supplying the compressed fluid to a condenser, the compressor comprising:
an inlet guide vane comprising,
a shaft that is turnably supported by inserting a round bar-shaped shaft main body portion thereof in a bearing sleeve; and
a plate-shaped vane main body that is joined with the shaft and projects from an inner periphery surface of a suction port to a central portion of the suction port,
the shaft including a flange portion that is provided at a distal end side in a direction of the axis line to join with the vane main body and that extends to an outside in a direction perpendicular to the axis line so as to be extended outward in a radial direction of the bearing sleeve,
wherein a width of the flange portion in the direction perpendicular to the axis line is a size of at least 1.5 times an outer diameter of the shaft main body portion andor at least \u2153 of a maximum width of the vane main body and
wherein the inlet guide vane is provided at the suction port into which the fluid is drawn by rotation of the impeller and wherein the inlet guide vane is turnably installed about an axis line at the suction port in order to adjust a suction amount and flow direction of the fluid.
3. A refrigerator comprising:
a condenser that cools and liquefies a compressed refrigerant;
an evaporator that takes heat of evaporation away from a cooling object to cool the cooling object by evaporating the liquefied refrigerant; and
a compressor that compresses the refrigerant evaporated by the evaporator and supplies the refrigerant to the condenser, the compressor being a compressor that compresses a fluid with a compression mechanism that has an impeller and a diffuser and is capable of supplying the compressed fluid to a condenser, the compressor comprising,
an inlet guide vane that is turnably installed about an axis line at a suction port into which a fluid is drawn by rotation of the impeller in order to adjust a suction amount and flow direction of the fluid, the inlet guide vane comprising:
a shaft that is turnably supported by inserting a round bar-shaped shaft main body portion thereof in a bearing sleeve; and
a plate-shaped vane main body that is joined with the shaft and projects from an inner periphery surface of the suction port to a central portion of the suction port,
the shaft including a flange portion that is provided at a distal end side in a direction of the axis line to join with the vane main body and that extends to an outside in a direction perpendicular to the axis line so as to be extended outward in a radial direction of the bearing sleeve.
4. The refrigerator according to claim 3, wherein a width of the flange portion in the direction perpendicular to the axis line is a size of at least 1.5 times an outer diameter of the shaft main body portion andor at least \u2153 of a maximum width of the vane main body.