1. A method of making a hydrophilic-hydrophobic random copolymer membrane comprising the steps of:
forming a hydrophilic-hydrophobic random copolymer comprising one or more hydrophilic monomers comprising a sulfonated polyarylsulfone monomer and a second monomer and one or more hydrophobic monomers comprising a non-sulfonated third monomer and a fourth monomer, wherein the sulfonated polyarylsulfone monomer introduce a sulfonate into the hydrophilic-hydrophobic random copolymer.
2. The method of claim 1, wherein the sulfonated polyarylsulfone monomer comprises a disulfonated-diphenylsulfone monomer, the second monomer comprises a biphenol, the non-sulfonated third monomer comprises a diphenylsulfone, and the fourth monomer comprise a biphenol.
3. The method of claim 1, wherein the sulfonated polyarylsulfone monomer comprises a disulfonated-diphenylsulfone, the second monomer comprise a biphenol, the non-sulfonated third monomer comprises a 2,6-dichloro-benzonitrile, and the fourth monomer comprise a biphenol.
4. The method of claim 1, wherein the sulfonated polyarylsulfone monomer comprises a disulfonated-diphenylsulfone, the second monomer comprise a biphenol, the non-sulfonated third monomer comprises a 4,4\u2032-difluoro-triphenyl phosphine oxide, and the fourth monomer comprise a biphenol.
5. The method of claim 1, wherein the sulfonated polyarylsulfone monomer comprises a disulfonated-diphenylsulfone, a monosulfonated-diphenylsulfone, a substituted-diphenylsulfone, or a disubstituted-diphenylsulfone.
6. The method of claim 1, wherein the second monomer comprise a biphenol, a substituted biphenol, a multiply substituted biphenyl, 2,2-bis-phenylpropane, a substituted 2,2-bis-phenylpropane, a multiply substituted 2,2-bis-phenylpropane, 1,1-di(trifluoromethane)(diphenylmethane), a substituted 1,1-di(trifluoromethane)(diphenylmethane), or a multiply substituted 1,1-di(trifluoromethane)(diphenylmethane).
7. The method of claim 1, wherein the non-sulfonated third monomer comprises a diphenylsulfone, a substituted diphenylsulfone, a multiply substituted diphenylsulfone, a 2,6-dichloro-benzonitrile, a substituted 2,6-dichloro-benzonitrile, a multiply substituted 2,6-dichloro-benzonitrile, 4,4\u2032-difluoro-triphenyl phosphine oxide a substituted 4,4\u2032-difluoro-triphenyl phosphine oxide, or a multiply substituted 4,4\u2032-difluoro-triphenyl phosphine oxide.
8. The method of claim 1, wherein the fourth monomer comprise a biphenol, a substituted biphenol, a multiply substituted biphenyl, a 2,2-bis-phenylpropane, a substituted 2,2-bis-phenylpropane, a multiply substituted 2,2-bis-phenylpropane, a 1,1-di(trifluoromethane)(diphenylmethane), a substituted 1,1-di(trifluoromethane)(diphenylmethane), or a multiply substituted 1,1-di(trifluoromethane)(diphenylmethane).
9. The method of claim 1, wherein the sulfonated polyarylsulfone monomer, the second monomer, the non-sulfonated third monomer and the fourth monomer are connected individually by an ether bond.
10. The method of claim 1, wherein the sulfonated polyarylsulfone monomer, the second monomer, the non-sulfonated third monomer and the fourth monomer are independently connected by an O, a S, a C, a F, a C(CH3)2 group, a CF3 group, a C(CF3) group, a C(CF3)2 group, a C(CF3)(C6H5) group, a C(O) group, a COO group, a S(O)2 group, and a P(O)(C6H5) group, or a carbon-carbon single bond.
11. The method of claim 1, further comprising the step of adding one or more cross-linking agents to the hydrophilic-hydrophobic random copolymer to form a cross-linked hydrophilic-hydrophobic random copolymer.
12. The method of claim 1, wherein the hydrophilic-hydrophobic random copolymer has a mole percentage between 5 and 80 percent.
13. The method of claim 1, further comprising the step of forming the hydrophilic-hydrophobic random copolymer into a hydrophilic-hydrophobic random copolymer membrane.
14. A hydrophilic-hydrophobic random copolymer membrane comprising:
one or more hydrophilic regions comprising a sulfonated polyarylsulfone monomer and a second monomer; and
one or more hydrophobic regions comprising a non-sulfonated third monomer and a fourth monomer, wherein the sulfonated polyarylsulfone monomer introduce a sulfonate into the hydrophilic-hydrophobic random copolymer.
15. The composition of claim 14, wherein the sulfonated polyarylsulfone monomer, the second monomer, the non-sulfonated third monomer and the fourth monomer are connected independently by an O, a S, a C, a F, a C(CH3)2 group, a CF3 group, a CH(CF3) group, a C(CF3)2 group, a C(CF3)(C6H5) group, a C(O) group, a COO group, a S(O)2 group, and a P(O)(C6H5) group, or a carbon-carbon single bond.
16. The composition of claim 14, wherein the sulfonated polyarylsulfone monomer comprises a disulfonated-diphenylsulfone monomer, the second monomer comprises a biphenol, the non-sulfonated third monomer comprises a diphenylsulfone, and the fourth monomer comprise a biphenol.
17. The composition of claim 14, wherein the sulfonated polyarylsulfone monomer comprises a disulfonated-diphenylsulfone, the second monomer comprises a biphenol, the non-sulfonated third monomer comprises a 2,6-dichloro-benzonitrile, and the fourth monomer comprise a biphenol.
18. The composition of claim 14, wherein the sulfonated polyarylsulfone monomer comprises a disulfonated-diphenylsulfone, the second monomer comprises a biphenol, the non-sulfonated third monomer comprises a 4,4\u2032-difluoro-triphenyl phosphine oxide, and the fourth monomer comprise a biphenol.
19. The composition of claim 14, wherein the sulfonated polyarylsulfone monomer comprises a disulfonated-diphenylsulfone, a monosulfonated-diphenylsulfone, a substituted-diphenylsulfone or a disubstituted-diphenylsulfone; the second monomer comprise a biphenol, a substituted biphenol, a multiply substituted biphenyl, a 2,2-bis-phenylpropane, a substituted 2,2-bis-phenylpropane, a multiply substituted 2,2-bis-phenylpropane, a 1,1-di(trifluoromethane)(diphenylmethane), a substituted 1,1-di(trifluoromethane)(diphenylmethane) or a multiply substituted 1,1-di(trifluoromethane)(diphenylmethane); the non-sulfonated third monomer comprises a diphenylsulfone, a substituted diphenylsulfone, a multiply substituted diphenylsulfone, a 2,6-dichloro-benzonitrile, a substituted 2,6-dichloro-benzonitrile, a multiply substituted 2,6-dichloro-benzonitrile, 4,4\u2032-difluoro-triphenyl phosphine oxide a substituted 4,4\u2032-difluoro-triphenyl phosphine oxide, or a multiply substituted 4,4\u2032-difluoro-triphenyl phosphine oxide; and the fourth monomer comprise a biphenol, a substituted biphenol, a multiply substituted biphenyl, 2,2-bis-phenylpropane, a substituted 2,2-bis-phenylpropane, a multiply substituted 2,2-bis-phenylpropane, 1,1-di(trifluoromethane)(diphenylmethane), a substituted 1,1-di(trifluoromethane)(diphenylmethane), or a multiply substituted 1,1-di(trifluoromethane)(diphenylmethane).
20. The composition of claim 14, wherein the sulfonated polyarylsulfone monomer, the second monomer, the non-sulfonated third monomer and the fourth monomer are individually connected by an ether bond.
21. The composition of claim 14, wherein the hydrophilic-hydrophobic random copolymer membrane has a mole percentage between 5 and 80 percent.
22. A method of making a chlorine tolerant hydrophilic-hydrophobic copolymer desalination membrane comprising the steps of:
forming a hydrophilic-hydrophobic random copolymer comprising one or more hydrophilic monomers comprising a sulfonated polyarylsulfone monomer and a second monomer and one or more hydrophobic monomers comprising a non-sulfonated third monomer and a fourth monomer, wherein the sulfonated polyarylsulfone monomer introduce the sulfonate into the hydrophilic-hydrophobic random copolymer; and
forming the hydrophilic-hydrophobic random copolymer into a hydrophilic-hydrophobic copolymer desalination membrane that is chlorine tolerant membrane.
23. The method of claim 22, wherein the sulfonated polyarylsulfone monomer comprises a disulfonated-diphenylsulfone monomer, the second monomer comprises a biphenol, the non-sulfonated third monomer comprises a diphenylsulfone, and the fourth monomer comprise a biphenol.
24. The method of claim 22, wherein the sulfonated polyarylsulfone monomer comprises a disulfonated-diphenylsulfone, the second monomer comprises a biphenol, the non-sulfonated third monomer comprises a 2,6-dichloro-benzonitrile, and the fourth monomer comprise a biphenol.
25. The method of claim 22, wherein the sulfonated polyarylsulfone monomer comprises a disulfonated-diphenylsulfone, the second monomer comprises a biphenol, the non-sulfonated third monomer comprises a 4,4\u2032-difluoro-triphenyl phosphine oxide, and the fourth monomer comprise a biphenol.
26. The method of claim 22, wherein the sulfonated polyarylsulfone monomer comprises a disulfonated-diphenylsulfone, a monosulfonated-diphenylsulfone, a substituted-diphenylsulfone, or a disubstituted-diphenylsulfone; the second monomer comprise a biphenol, a substituted biphenol, a multiply substituted biphenyl, 2,2-bis-phenylpropane, a substituted 2,2-bis-phenylpropane, a multiply substituted 2,2-bis-phenylpropane, 1,1-di(trifluoromethane)(diphenylmethane), a substituted 1,1-di(trifluoromethane)(diphenylmethane), or a multiply substituted 1,1-di(trifluoromethane)(diphenylmethane); the non-sulfonated third monomer comprises a diphenylsulfone, a substituted diphenylsulfone, a multiply substituted diphenylsulfone, a 2,6-dichloro-benzonitrile, a substituted 2,6-dichloro-benzonitrile, a multiply substituted 2,6-dichloro-benzonitrile, 4,4\u2032-difluoro-triphenyl phosphine oxide a substituted 4,4\u2032-difluoro-triphenyl phosphine oxide, or a multiply substituted 4,4\u2032-difluoro-triphenyl phosphine oxide; and the fourth monomer comprise a biphenol, a substituted biphenol, a multiply substituted biphenyl, 2,2-bis-phenylpropane, a substituted 2,2-bis-phenylpropane, a multiply substituted 2,2-bis-phenylpropane, 1,1-di(trifluoromethane)(diphenylmethane), a substituted 1,1-di(trifluoromethane)(diphenylmethane), or a multiply substituted 1,1-di(trifluoromethane)(diphenylmethane).
27. A water purification kit comprising:
a chlorine tolerant hydrophilic-hydrophobic copolymer desalination membrane comprising one or more hydrophilic regions comprising a sulfonated polyarylsulfone monomer and a second monomer and one or more hydrophobic regions comprising a non-sulfonated third monomer and a fourth monomer, wherein the sulfonated polyarylsulfone monomer introduce a sulfonate into the hydrophilic-hydrophobic random copolymer; and
a set of instructions.
28. A chlorine tolerant hydrophilic-hydrophobic multi-block copolymer desalination membrane comprising:
a hydrophilic random oligomer comprising a sulfonated polyarylsulfone monomer and a second monomer; and
a hydrophobic random oligomer comprising a non-sulfonated third monomer and a monomer, wherein a hydrophilic-hydrophobic multi-block copolymer desalination membrane that is chlorine tolerant and includes one or more blocks of the hydrophilic random copolymer and one or more blocks of the hydrophobic random copolymer.
29. A hydrophilic-hydrophobic random copolymer desalination membrane comprising one or more units having the structure:
wherein X, Y, Z and R independently comprise an O, a S, a C, a F, C(CH3)2 group, a CF3 group, a C(CF3) group, a C(CF3)2 group, a C(CF3)(C6H5) group, a C(O) group, a COO group, a S(O)2 group, or a P(O)(C6H5) group, or a carbon-carbon single bond and A=1\u2212B.
30. The composition of claim 28, wherein the X is an O, Y is a carbon-carbon single bond, Z is a S(O)2 group, and R is a carbon-carbon single bond.
31. The composition of claim 28, wherein the X is an O, Y is a carbon-carbon single bond, Z is a S(O)2 group, and R is a carbon-carbon single bond.
32. The composition of claim 28, wherein the X is an O, Y is a C(CF3) group, Z is a S(O)2 group, and R is a carbon-carbon single bond.
33. The composition of claim 28, wherein the X is an O, Y is a C(CH3)2 group, Z is a S(O)2 group, and R is a carbon-carbon single bond.
34. The composition of claim 28, wherein the X is an O, Y is a P(O)(C6H5) group, Z is a S(O)2 group, and R is a carbon-carbon single bond.
35. The composition of claim 28, wherein X is an O, Y is a C(CH3)2 group, Z is a S(O)2 group, and R is a carbon-carbon single bond.
36. The composition of claim 28, wherein the hydrophilic-hydrophobic random copolymer has a mole percentage between 5 and 80 mole percent.
37. A chlorine tolerant hydrophilic-hydrophobic copolymer desalination membrane containing units of the following formula:
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
1. A mounting system for a winch, said mounting system comprising:
a mounting plate having a first end and a second end,
a flex plate made from a flexible material,
said flex plate having a first end and a second end,
said second end of said flex plate may be attached to said mounting plate,
whereby said flex plate can flex with respect to said mounting plate,
a guide plate having a first end and a second end,
said second end of said guide plate being mounted to said first end of said mounting plate by a hinged connection,
whereby said guide plate can pivot with respect to said mounting plate,
a cable guide securely attached to said first end of said guide plate,
means for securely attaching said second end of said mounting plate to a fixed object.
2. The mounting system of claim 1, wherein said winch is electrically powered.
3. The mounting system of claim 2, further comprising an electrical control box attached to said mounting plate,
said electrical control box capable of receiving electrical power from an external source and transferring the electrical power to the winch.
4. The mounting system of claim 3, said electrical control box further comprising a possible separate module capable of receiving wireless control signals.
5. The mounting system of claim 1, wherein said means for attaching said second end of said mounting plate to said fixed object is a shackle.
6. The mounting system of claim 1, wherein said guide plate can pivot with respect to said mounting plate from an angle of approximately 90 degrees to an angle such that the desired orientation is achieved during operation, and
said angles being measured from a plane of said mounting plate relative to a plane of said guide plate.
7. The mounting system of claim 1, wherein said flex plate is made from high tension flexible steel.
8. The mounting system of claim 1, wherein said winch is attached to said mounting plate by means of a plurality of bolts.
9. The mounting system of claim 1, wherein said means for attaching said second end of said support plate to said mounting plate is a plurality of bolts.