1. A method for vehicle-to-vehicle communication between a first vehicle and a second vehicle, the method comprising the acts of:
providing an interrupt point;
providing a first vehicle;
providing a second vehicle, wherein second vehicle is located behind the interrupt point;
providing a vehicle-to-vehicle communication apparatus in the first vehicle and in the second vehicle;
transmitting an interrupt request from the first vehicle to the second vehicle;
forming a network incorporating the first vehicle and the second vehicle;
receiving the interrupt request;
responding to the interrupt request;
automatically flashing an external light on the second vehicle before the interrupt point if the interrupt request is acknowledged; and
wherein the interrupt request is a request to enter a road segment, the road segment comprising a first end and a second end and lacking sufficient width to accommodate two directions of traffic, in which the first vehicle seeks to travel from the first end to the second end and the second vehicle seeks to travel from the second end to the first end.
2. The method of claim 1, wherein the vehicle-to-vehicle communication apparatus is connected to a navigation apparatus via an interface.
3. The method of claim 1, further comprising the act of displaying the interrupt request and a positional relationship between the first vehicle and the second vehicle in the second vehicle.
4. The method of claim 1, further comprising the act of displaying acknowledgement of the interrupt request and data for identifying the second vehicle in the first vehicle.
5. A vehicle-to-vehicle communication apparatus for communication between a first vehicle and a second vehicle, the apparatus comprising:
a communication unit operable to transmit a request from a first vehicle to a second vehicle and receive another request from the second vehicle to the first vehicle; and
a vehicle-to-vehicle control unit operable to form a predetermined network with the second vehicle and respond to the request after the communication unit receives the request from the second vehicle;
an automatic flashing unit operable to instruct an external light on the first vehicle to flash before an interrupt point if the request is acknowledged;
wherein the communication unit is operable to receive a request to interrupt sent from the first vehicle to the second vehicle on a main road when the second vehicle being located behind an interrupt point; and
wherein the request to interrupt is a request to enter a road segment, the road segment comprising a first end and a second end and lacking sufficient width to accommodate two directions of traffic, in which the first vehicle seeks to travel from the first end to the second end and the second vehicle seeks to travel from the second end to the first end.
6. The vehicle-to-vehicle communication apparatus of claim 5, wherein the apparatus of the second vehicle is operable to display the received interrupt request and a positional relationship between the first vehicle and the second vehicle on a display unit.
7. The vehicle-to-vehicle communication apparatus of claim 6, wherein the display unit is located in a navigation apparatus connected to the vehicle-to-vehicle communication apparatus via an interface.
8. The vehicle-to-vehicle communication apparatus of claim 7, wherein the vehicle-to-vehicle control unit of the first vehicle is operable to display acknowledgement of the interrupt request and data for identifying the second vehicle on the display unit.
9. A method for vehicle-to-vehicle communication between a first vehicle and a second vehicle, the method comprising the acts of:
providing an interrupt point;
providing a first vehicle;
providing a second vehicle, wherein second vehicle is located behind the interrupt point;
providing a vehicle-to-vehicle communication apparatus in the first vehicle and in the second vehicle;
transmitting an interrupt request from the first vehicle to the second vehicle;
forming a network incorporating the first vehicle and the second vehicle;
receiving the interrupt request; and
responding to the interrupt request;
wherein the interrupt request is a request to enter a road segment, the road segment comprising a first end and a second end and lacking sufficient width to accommodate two directions of traffic, in which the first vehicle seeks to travel from the first end to the second end and the second vehicle seeks to travel from the second end to the first end.
10. The method of claim 9 further comprising the act of automatically flashing an external light on the second vehicle before the interrupt point if the interrupt request is acknowledged.
11. The method of claim 9, wherein the vehicle-to-vehicle communication apparatus is connected to a navigation apparatus via an interface.
12. The method of claim 9, further comprising the act of displaying the interrupt request and a positional relationship between the first vehicle and the second vehicle in the second vehicle.
13. The method of claim 9, further comprising the act of displaying acknowledgement of the interrupt request and data for identifying the second vehicle in the first vehicle.
14. A vehicle-to-vehicle communication apparatus for communication between a first vehicle and a second vehicle, the apparatus comprising:
a communication unit operable to transmit a request from a first vehicle to a second vehicle and receive another request from the second vehicle to the first vehicle; and
a vehicle-to-vehicle control unit operable to form a predetermined network with the second vehicle and respond to the request after the communication unit receives the request from the second vehicle;
wherein the communication unit is operable to receive a request to interrupt sent from the first vehicle to the second vehicle on a main road when the second vehicle being located behind an interrupt point; and
wherein the request to interrupt is a request to enter a road segment, the road segment comprising a first end and a second end and lacking sufficient width to accommodate two directions of traffic, in which the first vehicle seeks to travel from the first end to the second end and the second vehicle seeks to travel from the second end to the first end.
15. The vehicle-to-vehicle communication apparatus of claim 14, wherein the apparatus of the second vehicle is operable to display the received interrupt request and a positional relationship between the first vehicle and the second vehicle on a display unit\u2014and wherein the apparatus of the second vehicle, if acknowledging the interrupt request, automatically flashes a light using an automatic light-flashing unit immediately before the interrupt point.
16. The vehicle-to-vehicle communication apparatus of claim 14, wherein the display unit is located in a navigation apparatus connected to the vehicle-to-vehicle communication apparatus via an interface.
17. The vehicle-to-vehicle communication apparatus of claim 14, wherein the vehicle-to-vehicle control unit of the first vehicle is operable to display acknowledgement of the interrupt request and data for identifying the second vehicle on the display unit.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
1. A process to produce an essentially homogeneous single liquid phase hydrocarbon-rubber cement from a polymer slurry comprising a hydrocarbon-rubber, a diluent, and unreacted monomer(s), said process comprising:
(a) following polymerization of the hydrocarbon-rubber, contacting said polymer slurry with a hydrocarbon solvent; and
(b) removing said diluent and said hydrocarbon solvent in amounts not sufficiently more than is necessary to produce said essentially homogeneous single liquid phase hydrocarbon-rubber cement wherein the mass fraction of monomer(s) in the hydrocarbon-rubber cement, based on the total amount of hydrocarbon-rubber present in the hydrocarbon-rubber cement, is less than the mass fraction of monomer(s) in the hydrocarbon-rubber slurry, based on the total amount of hydrocarbon-rubber present in the hydrocarbon-rubber slurry,
wherein said diluent comprises a hydrofluorocarbon.
2. The process of claim 1, wherein said hydrofluorocarbon comprises at least one carbon atom, and at least two fluorine atoms.
3. The process of claim 1, wherein said hydrofluorocarbon comprises 1,1-difluoroethane.
4. The process of claim 1, wherein said hydrofluorocarbon comprises 1,1,1,2-tetrafluoroethane.
5. The process of claim 1, wherein said hydrofluorocarbon consists essentially of hydrogen, carbon, and fluorine.
6. The process of claim 1, wherein the mass fraction of said unreacted monomer(s) in said hydrocarbon-cement, based on the total weight of said hydrocarbon rubber in said hydrocarbon-cement, is less than the mass fraction of said unreacted monomer(s) in said polymer slurry, based on the total weight of said hydrocarbon rubber in said polymer slurry.
7. The process of claim 1, wherein said diluent further comprises methyl chloride.
8. The process of claim 1, wherein said hydrocarbon-rubber comprises polymer(s) andor copolymer(s) of isobutylene, isoprene, para-methyl styrene, or a combination thereof.
9. The process of claim 1, wherein said diluent consists essentially of a hydrofluorocarbon.
10. The process of claim 1, wherein said polymer slurry is produced in a slurry cationic polymerization process for the production of C4-C7 isoolefin polymers.
11. The process of claim 1, wherein said polymer slurry comprises greater than or equal to about 10 vol % solids.
12. The process of claim 1, wherein said polymer slurry is at a temperature of less than or equal to about \u221220\xb0 C. when contacted with said hydrocarbon solvent.
13. The process of claim 1, wherein the mass fraction of said unreacted monomer(s) in said hydrocarbon-cement, based on the total weight of said hydrocarbon rubber in said hydrocarbon-cement, is less than 80% of the mass fraction of said unreacted monomer(s) in said polymer slurry, based on the total weight of said hydrocarbon rubber in said polymer slurry.
14. The process of claim 1, wherein said hydrocarbon-rubber cement is essentially free of unreacted monomer(s).
15. The process of claim 1, wherein said hydrofluorocarbon diluent is a gas at 25\xb0 C. and a pressure of 101.3 kPa-a.
16. The process of claim 1, wherein said hydrofluorocarbon is represented by the formula:
CxHyFz
wherein x is an integer from 1 to 10, y is greater than or equal to 1; and z is greater than or equal to 1.
17. The process of claim 1, wherein said hydrofluorocarbon is selected from the group consisting of:
fluoromethane; difluoromethane; trifluoromethane; fluoroethane; 1,1-difluoroethane; 1,2-difluoroethane; 1,1,1-trifluoroethane; 1,1,2-trifluoroethane; 1,1,1,2-tetrafluoroethane; 1,1,2,2-tetrafluoroethane; 1,1,1,2,2-pentafluoroethane; 1,1,1-trifluoropropane; 1,1,2-trifluoropropane; 1,1,3-trifluoropropane; 1,2,2-trifluoropropane; 1,2,3-trifluoropropane; 1,1,1,2-tetrafluoropropane; 1,1,1,3-tetrafluoropropane; 1,1,2,2-tetrafluoropropane; 1,1,2,3-tetrafluoropropane; 1,1,3,3-tetrafluoropropane; 1,2,2,3-tetrafluoropropane; 1,1,1,2,2-pentafluoropropane; 1,1,1,2,3-pentafluoropropane; 1,1,1,3,3-pentafluoropropane; 1,1,2,2,3-pentafluoropropane; 1,1,2,3,3-pentafluoropropane; 1,1,1,2,2,3-hexafluoropropane; 1,1,1,2,3,3-hexafluoropropane; 1,1,1,3,3,3-hexafluoropropane; 1,1,1,2,2,3,3-heptafluoropropane; 1,1,1,2,3,3,3-heptafluoropropane; 1,1,1-trifluorobutane; 1,1,2-trifluorobutane; 1,1,3-trifluorobutane; 1,1,4-trifluorobutane; 1,2,2-trifluorobutane; 1,2,3-trifluorobutane; 1,3,3-trifluorobutane; 2,2,3-trifluorobutane; 1,1,1,2-tetrafluorobutane; 1,1,1,3-tetrafluorobutane; 1,1,1,4-tetrafluorobutane; 1,1,2,2-tetrafluorobutane; 1,1,2,3-tetrafluorobutane; 1,1,2,4-tetrafluorobutane; 1,1,3,3-tetrafluorobutane; 1,1,3,4-tetrafluorobutane; 1,1,4,4-tetrafluorobutane; 1,2,2,3-tetrafluorobutane; 1,2,2,4-tetrafluorobutane; 1,2,3,3-tetrafluorobutane; 1,2,3,4-tetrafluorobutane; 2,2,3,3-tetrafluorobutane; 1,1,1,2,2-pentafluorobutane; 1,1,1,2,3-pentafluorobutane; 1,1,1,2,4-pentafluorobutane; 1,1,1,3,3-pentafluorobutane; 1,1,1,3,4-pentafluorobutane; 1,1,1,4,4-pentafluorobutane; 1,1,2,2,3-pentafluorobutane; 1,1,2,2,4-pentafluorobutane; 1,1,2,3,3-pentafluorobutane; 1,1,2,4,4-pentafluorobutane; 1,1,3,3,4-pentafluorobutane; 1,2,2,3,3-pentafluorobutane; 1,2,2,3,4-pentafluorobutane; 1,1,1,2,2,3-hexafluorobutane; 1,1,1,2,2,4-hexafluorobutane; 1,1,1,2,3,3-hexafluorobutane, 1,1,1,2,3,4-hexafluorobutane; 1,1,1,2,4,4-hexafluorobutane; 1,1,1,3,3,4-hexafluorobutane; 1,1,1,3,4,4-hexafluorobutane; 1,1,1,4,4,4-hexafluorobutane; 1,1,2,2,3,3-hexafluorobutane; 1,1,2,2,3,4-hexafluorobutane; 1,1,2,2,4,4-hexafluorobutane; 1,1,2,3,3,4-hexafluorobutane; 1,1,2,3,4,4-hexafluorobutane; 1,2,2,3,3,4-hexafluorobutane; 1,1,1,2,2,3,3-heptafluorobutane; 1,1,1,2,2,4,4-heptafluorobutane; 1,1,1,2,2,3,4-heptafluorobutane; 1,1,1,2,3,3,4-heptafluorobutane; 1,1,1,2,3,4,4-heptafluorobutane; 1,1,1,2,4,4,4-heptafluorobutane; 1,1,1,3,3,4,4-heptafluorobutane; 1,1,1,2,2,3,3,4-octafluorobutane; 1,1,1,2,2,3,4,4-octafluorobutane; 1,1,1,2,3,3,4,4-octafluorobutane; 1,1,1,2,2,4,4,4-octafluorobutane; 1,1,1,2,3,4,4,4-octafluorobutane; 1,1,1,2,2,3,3,4,4-nonafluorobutane; 1,1,1,2,2,3,4,4,4-nonafluorobutane; 1,1,1-trifluoro-2-methylpropane; 1,1,3-trifluoro-2-methylpropane; 1,1,1,3-tetrafluoro-2-methylpropane; 1,1,3,3-tetrafluoro-2-methylpropane; 1,1,3-trifluoro-2-(fluoromethyl)propane; 1,1,1,3,3-pentafluoro-2-methylpropane; 1,1,3,3-tetrafluoro-2-(fluoromethyl)propane; 1,1,1,3-tetrafluoro-2-(fluoromethyl)propane; 1,1,2-trifluorocyclobutane; 1,1,3-trifluorocyclobutane; 1,2,3-trifluorocyclobutane; 1,1,2,2-tetrafluorocyclobutane; 1,1,3,3-tetrafluorocyclobutane; 1,1,2,2,3-pentafluorocyclobutane; 1,1,2,3,3-pentafluorocyclobutane; 1,1,2,2,3,3-hexafluorocyclobutane; 1,1,2,2,3,4-hexafluorocyclobutane; 1,1,2,3,3,4-hexafluorocyclobutane; 1,1,2,2,3,3,4-heptafluorocyclobutane; 1,1,2-trifluoroethene; 1,1,2-trifluoropropene; 1,1,3-trifluoropropene; 1,2,3-trifluoropropene; 1,3,3-trifluoropropene; 2,3,3-trifluoropropene; 3,3,3-trifluoropropene; 1,1,2-trifluoro-1-butene; 1,1,3-trifluoro-1-butene; 1,1,4-trifluoro-1-butene; 1,2,3-trifluoro-1-butene; 1,2,4-trifluoro-1-butene; 1,3,3-trifluoro-1-butene; 1,3,4-trifluoro-1-butene; 1,4,4-trifluoro-1-butene; 2,3,3-trifluoro-1-butene; 2,3,4-trifluoro-1-butene; 2,4,4-trifluoro-1-butene; 3,3,4-trifluoro-1-butene; 3,4,4-trifluoro-1-butene; 4,4,4-trifluoro-1-butene; 1,1,2,3-tetrafluoro-1-butene; 1,1,2,4-tetrafluoro-1-butene; 1,1,3,3-tetrafluoro-1-butene; 1,1,3,4-tetrafluoro-1-butene; 1,1,4,4-tetrafluoro-1-butene; 1,2,3,3-tetrafluoro-1-butene; 1,2,3,4-tetrafluoro-1-butene; 1,2,4,4-tetrafluoro-1-butene; 1,3,3,4-tetrafluoro-1-butene; 1,3,4,4-tetrafluoro-1-butene; 1,4,4,4-tetrafluoro-1-butene; 2,3,3,4-tetrafluoro-1-butene; 2,3,4,4-tetrafluoro-1-butene; 2,4,4,4-tetrafluoro-1-butene; 3,3,4,4-tetrafluoro-1-butene; 3,4,4,4-tetrafluoro-1-butene; 1,1,2,3,3-pentafluoro-1-butene; 1,1,2,3,4-pentafluoro-1-butene; 1,1,2,4,4-pentafluoro-1-butene; 1,1,3,3,4-pentafluoro-1-butene; 1,1,3,4,4-pentafluoro-1-butene; 1,1,4,4,4-pentafluoro-1-butene; 1,2,3,3,4-pentafluoro-1-butene; 1,2,3,4,4-pentafluoro-1-butene; 1,2,4,4,4-pentafluoro-1-butene; 2,3,3,4,4-pentafluoro-1-butene; 2,3,4,4,4-pentafluoro-1-butene; 3,3,4,4,4-pentafluoro-1-butene; 1,1,2,3,3,4-hexafluoro-1-butene; 1,1,2,3,4,4-hexafluoro-1-butene; 1,1,2,4,4,4-hexafluoro-1-butene; 1,2,3,3,4,4-hexafluoro-1-butene; 1,2,3,4,4,4-hexafluoro-1-butene; 2,3,3,4,4,4-hexafluoro-1-butene; 1,1,2,3,3,4,4-heptafluoro-1-butene; 1,1,2,3,4,4,4-heptafluoro-1-butene; 1,1,3,3,4,4,4-heptafluoro-1-butene; 1,2,3,3,4,4,4-heptafluoro-1-butene; 1,1,1-trifluoro-2-butene; 1,1,2-trifluoro-2-butene; 1,1,3-trifluoro-2-butene; 1,1,4-trifluoro-2-butene; 1,2,3-trifluoro-2-butene; 1,2,4-trifluoro-2-butene; 1,1,1,2-tetrafluoro-2-butene; 1,1,1,3-tetrafluoro-2-butene; 1,1,1,4-tetrafluoro-2-butene; 1,1,2,3-tetrafluoro-2-butene; 1,1,2,4-tetrafluoro-2-butene; 1,2,3,4-tetrafluoro-2-butene; 1,1,1,2,3-pentafluoro-2-butene; 1,1,1,2,4-pentafluoro-2-butene; 1,1,1,3,4-pentafluoro-2-butene; 1,1,1,4,4-pentafluoro-2-butene; 1,1,2,3,4-pentafluoro-2-butene; 1,1,2,4,4-pentafluoro-2-butene; 1,1,1,2,3,4-hexafluoro-2-butene; 1,1,1,2,4,4-hexafluoro-2-butene; 1,1,1,3,4,4-hexafluoro-2-butene; 1,1,1,4,4,4-hexafluoro-2-butene; 1,1,2,3,4,4-hexafluoro-2-butene; 1,1,1,2,3,4,4-heptafluoro-2-butene; 1,1,1,2,4,4,4-heptafluoro-2-butene; and mixtures thereof.
18. The process of claim 1, wherein said hydrocarbon solvent comprises C4-C10 hydrocarbons.
19. The process of claim 1, wherein said hydrocarbon solvent comprises linear, branched, or cyclic C5-C8 hydrocarbons.
20. The process of claim 1, wherein said hydrocarbon solvent comprises a C5 to C7 alkane.
21. The process of claim 1, wherein said hydrocarbon solvent is selected from the group consisting of:
butane, cyclobutane, isobutane, n-pentane, cyclopentane, n-hexane, methylcyclopentane, isohexane, 2-methylpentane, 3-methylpentane, 2-methylbutane, 2,2-dimethylbutane, 2,3-dimethylbutane, 2-methylhexane, 3-methylhexane, 3-ethylpentane, 2,2-dimethylpentane, 2,3-dimethylpentane, 2,4-dimethylpentane, 3,3-dimethylpentane, 2-methylheptane, 3-ethylhexane, 2,5-dimethylhexane, 2,24,-trimethylpentane, octane, heptane, nonane, decane, dodecane, undecane, 1,1-dimethylcyclopentane, 1,2-dimethylcyclopentane, 1,3-dimethylcyclopentane, ethylcyclopentane, cyclohexane, methylcyclohexane, benzene, toluene, ortho-xylene, para-xylene, meta-xylene, and combinations thereof.
22. The process of claim 1, wherein said hydrocarbon solvent is a mixture of n-hexane, 2-methylpentane, 3-methylpentane, methylcyclopentane, andor cyclohexane.
23. The process of claim 1, further comprising the steps of:
(c) removing at least a portion of said hydrofluorocarbon from said polymer slurry; and
(d) recycling at least a portion of the removed hydrofluorocarbon to produce additional polymer slurry.
24. The process of claim 1, further comprising the steps of:
(c) removing at least a portion of said hydrocarbon solvent; and
(d) recycling at least a portion of the removed hydrocarbon solvent to produce additional polymer slurry.
25. The process of claim 1, further comprising the steps of:
(c) removing at least a portion of said monomer(s); and
(d) recycling at least a portion of the removed monomer(s) to produce additional hydrocarbon-rubber.
26. The process of claim 1, further comprising:
adjusting the temperature andor the pressure of said polymer slurry or the mixture of said polymer slurry and said hydrocarbon solvent.
27. The process of claim 1, further comprising:
adjusting the temperature, the pressure, the weight fraction of the hydrocarbon solvent in said resulting mixture, andor the weight fraction of the diluent in said resulting mixture so that said resulting mixture is maintained as substantially homogeneous liquid phase.
28. A process to produce an essentially homogeneous hydrocarbon-rubber cement from a polymer slurry comprising a hydrocarbon-rubber, a diluent which is essentially free of a hydrofluorocarbon diluent, and a first mass fraction of unreacted monomer(s) based on the total amount of hydrocarbon rubber present in said polymer slurry, comprising:
(a) following polymerization of said hydrocarbon-rubber, contacting said polymer slurry with a hydrofluorocarbon diluent and with a hydrocarbon solvent; and
(b) removing at least a portion of said diluent, said hydrofluorocarbon diluent, and said hydrocarbon solvent to produce said essentially homogeneous hydrocarbon-rubber cement having a second mass fraction of unreacted monomer(s) based on the total amount of hydrocarbon rubber present in said essentially homogeneous hydrocarbon rubber cement,
wherein said first mass fraction is greater than said second mass fraction.
29. The process of claim 28, wherein at least a portion of said hydrofluorocarbon diluent is added to said polymer slurry prior to the addition of said hydrocarbon solvent to said polymer slurry.
30. The process of claim 28, wherein at least a portion of said hydrofluorocarbon diluent is added to said polymer slurry after the addition of said hydrocarbon solvent to said polymer slurry.
31. The process of claim 28, wherein at least a portion of said hydrofluorocarbon diluent is added to said polymer slurry simultaneous with the addition of said hydrocarbon solvent to said polymer slurry.
32. The process of claim 28, wherein said hydrofluorocarbon diluent comprises at least two carbon atoms, and at least two fluorine atoms.
33. The process of claim 28, wherein said hydrofluorocarbon diluent comprises 1,1-difluoroethane.
34. The process of claim 28, wherein said hydrofluorocarbon diluent comprises 1,1,1,2-tetrafluoroethane.
35. The process of claim 28, wherein said hydrofluorocarbon diluent consists essentially of hydrogen, carbon, and fluorine.
36. The process of claim 28, wherein said first mass fraction is less than 80% of said second mass fraction.
37. The process of claim 28, wherein said diluent comprises methyl chloride.
38. The process of claim 28, wherein said hydrocarbon-rubber comprises polymer(s) andor copolymer(s) of isobutylene, isoprene, para-methyl styrene, or a combination thereof.
39. The process of claim 28, wherein said polymer slurry is produced in a slurry cationic polymerization process for the production of C4-C7 isoolefin polymers.
40. The process of claim 28, wherein said polymer slurry comprises greater than or equal to about 10 vol % solids.
41. The process of claim 28, wherein said polymer slurry is at a temperature of less than or equal to about \u221220\xb0 C. when contacted with said hydrocarbon solvent.
42. The process of claim 28, wherein said first mass fraction is at least ten times greater than said second mass fraction.
43. The process of claim 28, wherein said hydrocarbon-rubber cement is essentially free of unreacted monomer(s).
44. The process of claim 28, wherein said hydrofluorocarbon diluent is a gas at 25\xb0 C. and 101 kPa-a (1 atm) of pressure.
45. The process of claim 28, wherein said hydrofluorocarbon diluent is represented by the formula:
CxHyFz
wherein x is an integer from 1 to 10, y is greater than or equal to 1; and z is greater than or equal to 1.
46. The process of claim 28, wherein said hydrofluorocarbon diluent is selected from the group consisting of:
fluoromethane; difluoromethane; trifluoromethane; fluoroethane; 1,1-difluoroethane; 1,2-difluoroethane; 1,1,1-trifluoroethane; 1,1,2-trifluoroethane; 1,1,1,2-tetrafluoroethane; 1,1,2,2-tetrafluoroethane; 1,1,1,2,2-pentafluoroethane; 1,1,1-trifluoropropane; 1,1,2-trifluoropropane; 1,1,3-trifluoropropane; 1,2,2-trifluoropropane; 1,2,3-trifluoropropane; 1,1,1,2-tetrafluoropropane; 1,1,1,3-tetrafluoropropane; 1,1,2,2-tetrafluoropropane; 1,1,2,3-tetrafluoropropane; 1,1,3,3-tetrafluoropropane; 1,2,2,3-tetrafluoropropane; 1,1,1,2,2-pentafluoropropane; 1,1,1,2,3-pentafluoropropane; 1,1,1,3,3-pentafluoropropane; 1,1,2,2,3-pentafluoropropane; 1,1,2,3,3-pentafluoropropane; 1,1,1,2,2,3-hexafluoropropane; 1,1,1,2,3,3-hexafluoropropane; 1,1,1,3,3,3-hexafluoropropane; 1,1,1,2,2,3,3-heptafluoropropane; 1,1,1,2,3,3,3-heptafluoropropane; 1,1,1-trifluorobutane; 1,1,2-trifluorobutane; 1,1,3-trifluorobutane; 1,1,4-trifluorobutane; 1,2,2-trifluorobutane; 1,2,3-trifluorobutane; 1,3,3-trifluorobutane; 2,2,3-trifluorobutane; 1,1,1,2-tetrafluorobutane; 1,1,1,3-tetrafluorobutane; 1,1,1,4-tetrafluorobutane; 1,1,2,2-tetrafluorobutane; 1,1,2,3-tetrafluorobutane; 1,1,2,4-tetrafluorobutane; 1,1,3,3-tetrafluorobutane; 1,1,3,4-tetrafluorobutane; 1,1,4,4-tetrafluorobutane; 1,2,2,3-tetrafluorobutane; 1,2,2,4-tetrafluorobutane; 1,2,3,3-tetrafluorobutane; 1,2,3,4-tetrafluorobutane; 2,2,3,3-tetrafluorobutane; 1,1,1,2,2-pentafluorobutane; 1,1,1,2,3-pentafluorobutane; 1,1,1,2,4-pentafluorobutane; 1,1,1,3,3-pentafluorobutane; 1,1,1,3,4-pentafluorobutane; 1,1,1,4,4-pentafluorobutane; 1,1,2,2,3-pentafluorobutane; 1,1,2,2,4-pentafluorobutane; 1,1,2,3,3-pentafluorobutane; 1,1,2,4,4-pentafluorobutane; 1,1,3,3,4-pentafluorobutane; 1,2,2,3,3-pentafluorobutane; 1,2,2,3,4-pentafluorobutane; 1,1,1,2,2,3-hexafluorobutane; 1,1,1,2,2,4-hexafluorobutane; 1,1,1,2,3,3-hexafluorobutane, 1,1,1,2,3,4-hexafluorobutane; 1,1,1,2,4,4-hexafluorobutane; 1,1,1,3,3,4-hexafluorobutane; 1,1,1,3,4,4-hexafluorobutane; 1,1,1,4,4,4-hexafluorobutane; 1,1,2,2,3,3-hexafluorobutane; 1,1,2,2,3,4-hexafluorobutane; 1,1,2,2,4,4-hexafluorobutane; 1,1,2,3,3,4-hexafluorobutane; 1,1,2,3,4,4-hexafluorobutane; 1,2,2,3,3,4-hexafluorobutane; 1,1,1,2,2,3,3-heptafluorobutane; 1,1,1,2,2,4,4-heptafluorobutane; 1,1,1,2,2,3,4-heptafluorobutane; 1,1,1,2,3,3,4-heptafluorobutane; 1,1,1,2,3,4,4-heptafluorobutane; 1,1,1,2,4,4,4-heptafluorobutane; 1,1,1,3,3,4,4-heptafluorobutane; 1,1,1,2,2,3,3,4-octafluorobutane; 1,1,1,2,2,3,4,4-octafluorobutane; 1,1,1,2,3,3,4,4-octafluorobutane; 1,1,1,2,2,4,4,4-octafluorobutane; 1,1,1,2,3,4,4,4-octafluorobutane; 1,1,1,2,2,3,3,4,4-nonafluorobutane; 1,1,1,2,2,3,4,4,4-nonafluorobutane; 1,1,1-trifluoro-2-methylpropane; 1,1,3-trifluoro-2-methylpropane; 1,1,1,3-tetrafluoro-2-methylpropane; 1,1,3,3-tetrafluoro-2-methylpropane; 1,1,3-trifluoro-2-(fluoromethyl)propane; 1,1,1,3,3-pentafluoro-2-methylpropane; 1,1,3,3-tetrafluoro-2-(fluoromethyl)propane; 1,1,1,3-tetrafluoro-2-(fluoromethyl)propane; 1,1,2-trifluorocyclobutane; 1,1,3-trifluorocyclobutane; 1,2,3-trifluorocyclobutane; 1,1,2,2-tetrafluorocyclobutane; 1,1,3,3-tetrafluorocyclobutane; 1,1,2,2,3-pentafluorocyclobutane; 1,1,2,3,3-pentafluorocyclobutane; 1,1,2,2,3,3-hexafluorocyclobutane; 1,1,2,2,3,4-hexafluorocyclobutane; 1,1,2,3,3,4-hexafluorocyclobutane; 1,1,2,2,3,3,4-heptafluorocyclobutane; 1,1,2-trifluoroethene; 1,1,2-trifluoropropene; 1,1,3-trifluoropropene; 1,2,3-trifluoropropene; 1,3,3-trifluoropropene; 2,3,3-trifluoropropene; 3,3,3-trifluoropropene; 1,1,2-trifluoro-1-butene; 1,1,3-trifluoro-1-butene; 1,1,4-trifluoro-1-butene; 1,2,3-trifluoro-1-butene; 1,2,4-trifluoro-1-butene; 1,3,3-trifluoro-1-butene; 1,3,4-trifluoro-1-butene; 1,4,4-trifluoro-1-butene; 2,3,3-trifluoro-1-butene; 2,3,4-trifluoro-1-butene; 2,4,4-trifluoro-1-butene; 3,3,4-trifluoro-1-butene; 3,4,4-trifluoro-1-butene; 4,4,4-trifluoro-1-butene; 1,1,2,3-tetrafluoro-1-butene; 1,1,2,4-tetrafluoro-1-butene; 1,1,3,3-tetrafluoro-1-butene; 1,1,3,4-tetrafluoro-1-butene; 1,1,4,4-tetrafluoro-1-butene; 1,2,3,3-tetrafluoro-1-butene; 1,2,3,4-tetrafluoro-1-butene; 1,2,4,4-tetrafluoro-1-butene; 1,3,3,4-tetrafluoro-1-butene; 1,3,4,4-tetrafluoro-1-butene; 1,4,4,4-tetrafluoro-1-butene; 2,3,3,4-tetrafluoro-1-butene; 2,3,4,4-tetrafluoro-1-butene; 2,4,4,4-tetrafluoro-1-butene; 3,3,4,4-tetrafluoro-1-butene; 3,4,4,4-tetrafluoro-1-butene; 1,1,2,3,3-pentafluoro-1-butene; 1,1,2,3,4-pentafluoro-1-butene; 1,1,2,4,4-pentafluoro-1-butene; 1,1,3,3,4-pentafluoro-1-butene; 1,1,3,4,4-pentafluoro-1-butene; 1,1,4,4,4-pentafluoro-1-butene; 1,2,3,3,4-pentafluoro-1-butene; 1,2,3,4,4-pentafluoro-1-butene; 1,2,4,4,4-pentafluoro-1-butene; 2,3,3,4,4-pentafluoro-1-butene; 2,3,4,4,4-pentafluoro-1-butene; 3,3,4,4,4-pentafluoro-1-butene; 1,1,2,3,3,4-hexafluoro-1-butene; 1,1,2,3,4,4-hexafluoro-1-butene; 1,1,2,4,4,4-hexafluoro-1-butene; 1,2,3,3,4,4-hexafluoro-1-butene; 1,2,3,4,4,4-hexafluoro-1-butene; 2,3,3,4,4,4-hexafluoro-1-butene; 1,1,2,3,3,4,4-heptafluoro-1-butene; 1,1,2,3,4,4,4-heptafluoro-1-butene; 1,1,3,3,4,4,4-heptafluoro-1-butene; 1,2,3,3,4,4,4-heptafluoro-1-butene; 1,1,1-trifluoro-2-butene; 1,1,2-trifluoro-2-butene; 1,1,3-trifluoro-2-butene; 1,1,4-trifluoro-2-butene; 1,2,3-trifluoro-2-butene; 1,2,4-trifluoro-2-butene; 1,1,1,2-tetrafluoro-2-butene; 1,1,1,3-tetrafluoro-2-butene; 1,1,1,4-tetrafluoro-2-butene; 1,1,2,3-tetrafluoro-2-butene; 1,1,2,4-tetrafluoro-2-butene; 1,2,3,4-tetrafluoro-2-butene; 1,1,1,2,3-pentafluoro-2-butene; 1,1,1,2,4-pentafluoro-2-butene; 1,1,1,3,4-pentafluoro-2-butene; 1,1,1,4,4-pentafluoro-2-butene; 1,1,2,3,4-pentafluoro-2-butene; 1,1,2,4,4-pentafluoro-2-butene; 1,1,1,2,3,4-hexafluoro-2-butene; 1,1,1,2,4,4-hexafluoro-2-butene; 1,1,1,3,4,4-hexafluoro-2-butene; 1,1,1,4,4,4-hexafluoro-2-butene; 1,1,2,3,4,4-hexafluoro-2-butene; 1,1,1,2,3,4,4-heptafluoro-2-butene; 1,1,1,2,4,4,4-heptafluoro-2-butene; and mixtures thereof.
47. The process of claim 28, wherein said hydrocarbon solvent comprises C4-C10 hydrocarbons.
48. The process of claim 28, wherein said hydrocarbon solvent comprises linear, branched, or cyclic C5-C8 hydrocarbons.
49. The process of claim 28, wherein said hydrocarbon solvent comprises a C5 to C7 alkane.
50. The process of claim 28, wherein said hydrocarbon solvent is selected from the group consisting of:
butane, cyclobutane, isobutane, n-pentane, cyclopentane, n-hexane, methylcyclopentane, isohexane, 2-methylpentane, 3-methylpentane, 2-methylbutane, 2,2-dimethylbutane, 2,3-dimethylbutane, 2-methylhexane, 3-methylhexane, 3-ethylpentane, 2,2-dimethylpentane, 2,3-dimethylpentane, 2,4-dimethylpentane, 3,3-dimethylpentane, 2-methylheptane, 3-ethylhexane, 2,5-dimethylhexane, 2,24,-trimethylpentane, octane, heptane, nonane, decane, dodecane, undecane, 1,1-dimethylcyclopentane, 1,2-dimethylcyclopentane, 1,3-dimethylcyclopentane, ethylcyclopentane, cyclohexane, methylcyclohexane, benzene, toluene, ortho-xylene, para-xylene, meta-xylene, and combinations thereof.
51. The process of claim 28, wherein said hydrocarbon solvent is a mixture of n-hexane, 2-methylpentane, 3-methylpentane, methylcyclopentane, and cyclohexane.
52. The process of claim 28, wherein at least a portion of said diluent removed from said polymer slurry is recycled to produce at least a portion of another polymer slurry.
53. The process of claim 28, wherein at least of portion of said hydrocarbon solvent removed from said polymer slurry is recycled and contacted with another polymer slurry.
54. The process of claim 28, wherein at least a portion of said monomer(s) removed from said polymer slurry is recycled to produce additional hydrocarbon-rubber.
55. The process of claim 28, further comprising:
(c) adjusting the temperature andor the pressure of said polymer slurry or the mixture of said polymer slurry, said hydrofluorocarbon diluent, said hydrocarbon solvent, andor a combination thereof.
56. The process of claim 28, further comprising:
(c) adjusting the temperature, the pressure, the weight fraction of the hydrocarbon solvent in said resulting mixture, andor the weight fraction of the hydrofluorocarbon diluent in said resulting mixture so that said resulting mixture is maintained as substantially homogeneous liquid phase.
57. A hydrocarbon-rubber cement composition made by a process of claim 1.
58. A hydrocarbon-rubber cement composition made by a process of claim 28.
59. A process to produce a single liquid phase hydrocarbon-rubber cement from a polymer slurry comprising a hydrocarbon-rubber, a diluent, and a first mass fraction of unreacted monomer(s) in said polymer slurry based on the total weight of said hydrocarbon-rubber in said polymer slurry, said process comprising:
(a) following polymerization of said hydrocarbon-rubber, contacting said polymer slurry with a hydrocarbon solvent; and
(b) removing at least a portion of said diluent and said hydrocarbon solvent from said polymer slurry to produce said single liquid phase hydrocarbon-rubber cement having a second mass fraction of unreacted monomer(s) in said hydrocarbon-rubber cement, based on the total amount of hydrocarbon-rubber present in said hydrocarbon-rubber cement,
wherein said diluent comprises a hydrofluorocarbon and said first mass fraction is higher than the second mass fraction.
60. The process of claim 59, wherein said hydrofluorocarbon comprises 1,1-difluoroethane.
61. The process of claim 59, wherein said hydrofluorocarbon comprises 1,1,1,2-tetrafluoroethane.
62. The process of claim 59, wherein said diluent further comprises methyl chloride.
63. The process of claim 59, wherein said hydrocarbon-rubber comprises polymer(s) andor copolymer(s) of isobutylene, isoprene, para-methyl styrene, or a combination thereof.
64. The process of claim 59, wherein said polymer slurry is produced in a slurry cationic polymerization process for the production of C4-C7 isoolefin polymers.
65. The process of claim 59, wherein said polymer slurry is at a temperature of less than or equal to about \u221220\xb0 C. when contacted with said hydrocarbon solvent.
66. The process of claim 59, wherein the mass fraction of said unreacted monomer(s) in said hydrocarbon-cement, based on the total weight of said hydrocarbon rubber in said hydrocarbon-cement, is less than 80% of the mass fraction of said unreacted monomer(s) in said polymer slurry, based on the total weight of said hydrocarbon rubber in said polymer slurry.
67. The process of claim 59, wherein said hydrofluorocarbon is represented by the formula:
CxHyFz
wherein x is an integer from 1 to 10, y is greater than or equal to 1; and z is greater than or equal to 1.
68. The process of claim 59, wherein said hydrocarbon solvent comprises C4-C10 hydrocarbons.
69. The process of claim 59, wherein said hydrocarbon solvent is a mixture of n-hexane, 2-methylpentane, 3-methylpentane, methylcyclopentane, andor cyclohexane.
70. The process of claim 59, further comprising the steps of:
(c) removing at least a portion of said hydrofluorocarbon from said polymer slurry; and
(d) recycling at least a portion of the removed hydrofluorocarbon to produce additional polymer slurry.
71. The process of claim 59, further comprising the steps of:
(c) removing at least a portion of said hydrocarbon solvent; and
(d) recycling at least a portion of the removed hydrocarbon solvent to produce additional polymer slurry.
72. The process of claim 59, further comprising the steps of:
(c) removing at least a portion of said monomer(s); and
(d) recycling at least a portion of the removed monomer(s) to produce additional hydrocarbon-rubber.
73. The process of claim 59, further comprising:
adjusting the temperature andor the pressure of said polymer slurry or the mixture of said polymer slurry and said hydrocarbon solvent.
74. The process of claim 59, further comprising:
adjusting the temperature, the pressure, the weight fraction of the hydrocarbon solvent in said resulting mixture, andor the weight fraction of the diluent in said resulting mixture so that said resulting mixture is maintained as substantially homogeneous liquid phase.
75. A hydrocarbon-rubber cement composition made by a process of claim 59.