1. A system for measuring clearance between a first object and a second object, comprising:
a sensor configuration to generate a first signal representative of a first sensed parameter and a second signal representative of a second sensed parameter; and
a clearance measurement unit configured to process the first and second signals based upon a ratiometric technique to calculate clearance between the first and second objects.
2. The system of claim 1, wherein the sensor configuration comprises at least one sensor disposed on the first object or the second object.
3. The system of claim 1, wherein the sensor configuration comprises a sensor disposed on the first object and a reference geometry disposed on the second object, wherein the sensor is configured to generate first and second signals representative of the first and second sensed parameters from the second object and the reference geometry.
4. The system of claim 1, wherein the sensor configuration comprises a capacitive probe and the first and second sensed parameters comprise capacitance measurements, and wherein the ratiometric measurement technique is configured to calculate the clearance as a function of a ratio of the first and second sensed parameters.
5. The system of claim 1, wherein the sensor system is configured to measure the clearance as the first object moves relative to the second object in a turbine engine.
6. The system of claim 5, wherein the first object comprises a rotatable blade and the second object comprises a casing disposed about the rotatable blade.
7. The system of claim 1, further comprising:
a phase detection module configured to detect a plurality of reflected signals to generate the first and second signals; and
a signal generator configured to supply an excitation signal to the sensor configuration for generating the first and second signals.
8. The system of claim 1, further comprising a clearance control unit coupled to the clearance measurement unit for controlling the clearance between the first and second objects based on the clearance calculated by the clearance measurement unit.
9. A system for measuring clearance between a first object and a second object, comprising:
a first sensor disposed at a first location, wherein the first sensor is configured to generate a first signal representative of a first sensed parameter;
a second sensor disposed at a second location, wherein the second sensor is configured to generate a second signal representative of a second sensed parameter; and
a clearance measurement unit configured to process the first and second signals based upon a ratiometric technique to calculate clearance between the first and second objects.
10. The system of claim 9, further comprising:
a phase detection module configured to detect a plurality of reflected signals from respective ones of the first and second sensors to generate the first and second signals;
a signal generator configured to supply excitation signals to the first and second sensors for generating the first and second signals; and
a clearance control unit coupled to the clearance measurement unit for controlling the clearance between the first and second objects based on the clearance calculated by the clearance measurement unit,
wherein the first and second sensors are capacitive probes, and the first and second sensed parameters are capacitances.
11. A system, comprising:
a reference geometry disposed on a movable object; and
a sensor disposed on a stationary object, wherein the sensor is configured to generate signals representative of respective sensed parameters from the movable object and the reference geometry; and
a clearance measurement unit configured to process the signals based upon a ratiometric technique to calculate clearance between the movable and stationary objects.
12. The system of claim 11, wherein the sensor is a capacitive probe, and the sensed parameters are capacitances.
13. The system of claim 1 1, further comprising:
a phase detection module configured to detect a plurality of reflected signals from respective ones of the movable object and the reference geometry to generate the signals representative of the sensed parameters;
a signal generator configured to supply excitation signals to the sensor for generating the first and second signals; and
a clearance control unit coupled to the clearance measurement unit for controlling the clearance between the movable and stationary objects based on the clearance calculated by the clearance measurement unit.
14. The system of claim 11, wherein the reference geometry comprises a recess disposed on the movable object.
15. A method of measuring clearance between a first object and a second object, comprising:
generating a first signal representative of a first sensed parameter from a sensor configuration proximate the first and second objects;
generating a second signal representative of a second sensed parameter from the sensor configuration; and
processing the first and second signals based upon a ratiometric technique to calculate the clearance between the first and second objects.
16. The method of claim 15, wherein generating the first and second signals comprises generating the first and second signals via first and second sensors, wherein the first and second sensors are disposed on one of the first or second objects, and wherein generating the first and second signals comprises measuring first and second capacitance values as the first and second sensed parameters.
17. The method of claim 15, wherein generating the first signal comprises generating a signal representative of the sensed parameter corresponding to a position of one of the first or second objects.
18. The method of claim 15, wherein processing the first and second signals comprises performing a plurality of phase measurements to determine a phase between each of reflected signals and the respective first and second signals.
19. The method of claim 15, further comprising controlling the clearance between the first and second objects based upon the calculated clearance.
20. A method of measuring a clearance between a first object and a second object, comprising:
generating a first signal representative of a first sensed parameter corresponding to one of the first or second objects;
generating a second signal representative of a second sensed parameter corresponding to a reference geometry disposed on the respective one of the first or second objects; and
processing the first and second signals based upon a ratiometric technique to calculate the clearance between the first and second objects.
21. The method of claim 20, wherein generating the first and second signals comprises measuring first and second capacitance values as the first and second sensed parameters.
22. The method of claim 20, wherein processing the first and second signals comprises performing a plurality of phase measurements to determine a phase between each of reflected signals and the respective first and second signals.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
1. Aromatic organosulfur functionalized 1,4-cis polybutadiene represented by the following Chemical Formula 1 or Chemical Formula 2:
where l, m, n and o respectively represent the number of repeating units of polybutadiene main chain, with I ranging from 30 to 99 weight %, m ranging from 0.05 to 5 weight %, n ranging from 0 to 50 weight %, o ranging from 0 to 50 weight %, and l+m+n+o=100 weight %, SAr represents an aromatic organosulfur compound, and R1 represents an isocyanate compound.
2. The polybutadiene as set forth in claim 1, wherein the aromatic organosulfur compound is comprised in an amount of 0.05 to 5 parts by weight based on 100 parts by weight of the 1,4-cis polybutadiene.
3. The polybutadiene as set forth in claim 1, wherein the aromatic organosulfur compound is selected from fluorothiophenol, chlorothiophenol, bromothiophenol, iodothiophenol, difluorothiophenol, dichlorothiophenol, dibromothiophenol, diiodothiophenol, trifluorothiophenol, trichlorothiophenol, tribromothiophenol, triiodothiophenol, tetrafluorothiophenol, tetrachlorothiophenol, tetrabromothiophenol, tetraiodothiophenol, pentafluorothiophenol, pentachlorothiophenol, pentabromothiophenol, pentaiodothiophenol, fluorothiopyridine, chlorothiopyridine, bromothiopyridine, iodothiopyridine, difluorothiopyridine, dichlorothiopyridine, dibromothiopyridine, diiodothiopyridine, trifluorothiopyridine, trichlorothiopyridine, tribromothiopyridine, triiodothiopyridine, tetrafluorothiopyridine, tetrachlorothiopyridine, tetrabromothiopyridine, tetraiodothiopyridine, xylylmercaptan, tetrachlorobenzenedithiol, mercaptobenzothiazole, glycidyl pentachlorothiophenyl ether, glycidyl pentafluorothiophenyl ether, dibenzamidodiphenyl disulfide and zinc pentachlorothiophenol.
4. The polybutadiene as set forth in claim 1, which has a cis content of 30 to 99% and a molecular weight ranging from 50,000 to 2,000,000.
5. A preparation method of aromatic organosulfur functionalized 1,4-cis polybutadiene comprising:
a first step of polymerizing 1,3-butadiene or butadiene derivative in the presence of an alkali metal catalyst or a catalyst comprising 1) 1 mol of a rare earth element compound or a transition metal compound, 2) 1 to 10 molar equivalents of a halogen containing compound, and 3) 10 to 100 molar equivalents of an organoaluminum compound in a nonpolar solvent to prepare 1,4-cis polybutadiene; and
a second step of polymerizing 100 parts by weight of the resultant 1,4-cis polybutadiene with 0.05 to 5 parts by weight of an aromatic organosulfur compound to prepare aromatic organosulfur functionalized 1,4-cis polybutadiene represented by the following Chemical Formula 1 or Chemical Formula 2:
where l, m, n and o represent the number of repeating units of polybutadiene main chain, with l ranging from 30 to 99 weight %, m ranging from 0.05 to 5 weight %, n ranging from 0 to 50 weight %, o ranging from 0 to 50 weight %, and l+m+n+o=100 weight %, SAr represents an aromatic organosulfur compound, and R1 represents an isocyanate compound.
6. The preparation method as set forth in claim 5, wherein the aromatic organosulfur compound is selected from fluorothiophenol, chlorothiophenol, bromothiophenol, iodothiophenol, difluorothiophenol, dichlorothiophenol, dibromothiophenol, diiodothiophenol, trifluorothiophenol, trichlorothiophenol, tribromothiophenol, triiodothiophenol, tetrafluorothiophenol, tetrachlorothiophenol, tetrabromothiophenol, tetraiodothiophenol, pentafluorothiophenol, pentachlorothiophenol, pentabromothiophenol, pentaiodothiophenol, fluorothiopyridine, chlorothiopyridine, bromothiopyridine, iodothiopyridine, difluorothiopyridine, dichlorothiopyridine, dibromothiopyridine, diiodothiopyridine, trifluorothiopyridine, trichlorothiopyridine, tribromothiopyridine, triiodothiopyridine, tetrafluorothiopyridine, tetrachlorothiopyridine, tetrabromothiopyridine, tetraiodothiopyridine, xylylmercaptan, tetrachlorobenzenedithiol, mercaptobenzothiazole, glycidyl pentachlorothiophenyl ether, glycidyl pentafluorothiophenyl ether, dibenzamidodiphenyl disulfide and zinc pentachlorothiophenol.
7. The preparation method as set forth in claim 5, wherein, in the second step, 0.05 to 2 parts by weight of an isocyanate compound represented by the Chemical Formula 3 is added based on 100 parts by weight of the polybutadiene:
R1\u2014(NCO)n \u2003\u2003Chemical Formula 3
where R1 is C4-C100 aryl or alkyl, and n is an integer from 2 to 10.
8. The preparation method as set forth in claim 7, wherein the isocyanate compound is selected from C4-C100 alkyl triisocyanate, C4-C100 alkyl tetra isocyanate, aromatic triisocyanate and aromatic tetraisocyanate.
9. The preparation method as set forth in claim 7, wherein the isocyanate compound is selected from hexyl diisocyanate, octyl diisocyanate, methylene diphenyl diisocyanate, hexyl triisocyanate, octyl triisocyanate, dodecyl tetraisocyanate, methylene triphenyl triisocyanate, naphthalene 1,2,5,7-tetraisocyanate, naphthalene 1,3,7-triisocyanate, tris-(p-isocyanatephenyl)-thiophosphate, carbodiimide-isocyanate, methylene diphenyl diisocyanate and polystyryl isocyanate.
10. The preparation method as set forth in claim 5, wherein the rare earth element compound is a carboxylate having C8-C20 saturated, unsaturated, cyclic or linear structure, selected from octoate, naphthenate, versatate and stearate.
11. The preparation method as set forth in claim 5, wherein the transition metal compound is a carboxylate having C8-C20 saturated, unsaturated, cyclic or linear structure, selected from octoate, naphthenate, versatate and stearate.
12. The preparation method as set forth in claim 5, wherein the halogen containing compound is represented by the following Chemical Formula 3:
AXnR2m \u2003\u2003Chemical Formula 4
where R2 is hydrogen, C1-C10 alkyl or C5-C10 aryl, A is aluminum or boron, n is an integer from 1 to 3, m is an integer from 0 to 2, and n+m=3.
13. The preparation method as set forth in claim 12, wherein the halogen containing compound is diethylchloroaluminum or trifluoroboron compound.
14. The preparation method as set forth in claim 5, wherein the organoaluminum compound is represented by the following Chemical Formula 5:
AlR33 \u2003\u2003Chemical Formula 5
where R3 is hydrogen, C1-C10 alkyl or C5-C10 aryl.
15. The preparation method as set forth in claim 14, wherein the organoaluminum compound is selected from trimethylaluminum, triethylaluminum, tripropylaluminum, tributylaluminum, triisobutylaluminum, trihexylaluminum and diisobutylaluminum hydride.
16. The preparation method as set forth in claim 5, wherein the alkali metal catalyst is a compound represented by the following Chemical Formula 6:
MR4 \u2003\u2003Chemical Formula 6
where M is an alkali metal selected from lithium, sodium, potassium, rhodium and cesium; and R4 is hydrogen, C1-C10 alkyl or C5-C10 aryl.
17. The preparation method as set forth in claim 5, wherein the nonpolar solvent is selected from butane, pentane, hexane, isopentane, heptane, octane, isooctane, cyclopentane, methylcyclopentane, cyclohexane, methylcyclohexane, ethylcyclohexane, benzene, toluene, ethylbenzene and xylene.
18. The preparation method as set forth in claim 5, wherein the nonpolar solvent is used in an amount of 3 to 10 parts by weight based on the total weight of the reactants of the first step.
19. The preparation method as set forth in claim 5, wherein the catalyst is used in an amount of 1\xd710\u22123 to 1\xd710\u22125 mol based on 100 g of 1,3-butadiene or butadiene derivative.