1. A lithium secondary battery comprising
a positive electrode including a high-voltage positive active material; and
a separator, wherein the separator comprises a substrate of polyethylene, polypropylene, polyvinylidene fluoride, or a multilayer thereof,
wherein the high-voltage positive active material has a discharge plateau voltage of about 4.6V to about 5.3V with respect to a Li counter electrode and the high-voltage positive active material is selected from at least one olivine-based lithium metal phosphate and a compound represented by Chemical Formula 1:
Li1+xNiyMn2-y-zMzO4+w\u2003\u2003Chemical Formula 1
wherein,
0\u2266x<0.2, 0.4\u2266y\u22660.6, 0\u2266z\u22660.2, 0\u2266w\u22660.1, and
M is selected from the group consisting of Al, Ti, Mg, Zn, and combinations thereof, and
the separator comprises a porous substrate having porosity of about 40% to about 60%; and a coating layer on at least one side of the porous substrate, wherein the coating layer comprises a polymer and a metal filler.
2. The lithium secondary battery of claim 1, wherein the metal filler comprises a component selected from the group consisting of metal oxide, metal hydroxide, metal phosphate, metal nitrate, metal carbonate, metal sulfate, metal alkoxide, metal oxide having a perovskite structure, ceramics, and combinations thereof.
3. The lithium secondary battery of claim 2, wherein the metal filler is MgCO3, BaCO3, Li2CO3, Al(OH)3.H2O, Al2(SO4)3, MgSO4, Al(OC2H5)3, YPO4, (ZrO)2P2O7, ZrP2O7, Al(NO3)3, a mixture of Al2(SO4)3 and Al(OC2H5)3, LiAlO2, LiAl5O8, Li5AlO4, MgO, MgAl2O4, BaTiO3, CoAl2O4, Li2SiO4, Li2B4O7, Li2MoO3, Al(OH)3, AlPO4, Mg(OH)2, a mixture of Al2O3 and AlPO4, Li2ZrO3, a mixture of Al2O3 and Al(OH)3, AM1O3 (A=Ca, Ba, Sr, Pb, and the like, M1 =Ti, Zr, Sn, Hf, and the like) or Al2O3.
4. The lithium secondary battery of claim 3, wherein the metal filler is Al2O3.
5. The lithium secondary battery of claim 4, wherein the porous substrate comprises polyethylene.
6. The lithium secondary battery of claim 1, wherein the polymer comprises a component selected from the group consisting of polyvinylidenefluoride (PVdF), poly(vinylidene-hexafluoropropylene) co-polymer (P(VdF-HFP)), polyethyleneoxide (PEO), polyacrylonitrile (PAN), polyimide (PI), polyamic acid (PAA), polyamideimide (PAI), and aramid.
7. The lithium secondary battery of claim 6, wherein the polymer is poly(vinylidene-hexafluoropropylene) co-polymer (P(VdF-HFP)).
8. The lithium secondary battery of claim 1, wherein the coating layer comprises about 5 wt % to about 80 wt % of a metal filler based on 100 wt % of the coating layer.
9. The lithium secondary battery of claim 1, wherein the coating layer has a thickness of about 0.05 \u03bcm to about 5 \u03bcm.
10. The lithium secondary battery of claim 1, wherein the separator has an entire thickness of about 5 \u03bcm to about 30 \u03bcm.
11. The lithium secondary battery of claim 1, wherein the lithium secondary battery further comprises a negative electrode including a negative active material selected from natural graphite, artificial graphite, soft carbon, hard carbon, a mesophase pitch carbonized product, fired coke, silicon oxide, or silicon oxide coated with conductive carbon, and combinations thereof.
12. The lithium secondary battery of claim 1, wherein the separator comprises a substrate of at least one kind of polyolefin-based monolayer or multilayer;
the lithium secondary battery further comprises a non-aqueous electrolyte; and
the non-aqueous electrolyte comprises a supporting electrolytic salt.
13. The lithium secondary battery of claim 12, wherein the supporting electrolytic salt in the non-aqueous electrolyte has a concentration of about 0.5 M to about 2 M.
14. The lithium secondary battery of claim 12, wherein the supporting electrolytic salt is LiPF6.
15. The lithium secondary battery of claim 12, wherein the non-aqueous electrolyte is a mixture of ethyl carbonate, ethylmethyl carbonate and dimethyl carbonate.
16. The lithium secondary battery of claim 1, wherein the high-voltage positive active material is LiNi0.5Mn1.5O4.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
1. A mixed positive electrode active material comprising a lithium manganese oxide represented by following Chemical Formula 1 and a second positive electrode active material represented by following Chemical Formula 2:
aLi2MnO3.(1\u2212a)LixMO2\u2003\u2003Chemical Formula 1
in Chemical Formula 1, 0<a<1, 0.9\u2266x\u22661.2, and M is at least one element selected from the group consisting of Al, Mg, Mn, Ni, Co, Cr, V and Fe,
Li4-xMn5-2x-yCo3xMyO12\u2003\u2003Chemical Formula 2
in Chemical Formula 2, 0<x<1.5, 0\u2266y<0.5, and M is at least one of transition metal elements.
2. The mixed positive electrode active material of claim 1, comprising the lithium manganese oxide represented by following Chemical Formula 1 and the second positive electrode active material represented by following Chemical Formula 2:
aLi2MnO3.(1\u2212a)LixMO2\u2003\u2003Chemical Formula 1
in Chemical Formula 1, 0<a<1, and M is at least one element selected from the group consisting of Al, Mg, Mn, Ni, Co, Cr, V and Fe,
Li4-xMn5-2x-yCo3xMyO12\u2003\u2003Chemical Formula 2
in Chemical Formula 2, 0.1\u2266x\u22660.5.
3. The mixed positive electrode active material of claim 1, wherein an amount of the second positive electrode active material is 10 to 30 parts by weight based on 100 parts by weight of a total amount of the mixed positive electrode active material.
4. The mixed positive electrode active material of claim 1, wherein the mixed positive electrode active material further comprises a conductive material and a binder besides the lithium manganese oxide and the second positive electrode active material.
5. The mixed positive electrode active material of claim 4, wherein the conductive material is graphite or conductive carbon.
6. The mixed positive electrode active material of claim 4, wherein an amount of the conductive material is 0.5 to 15 parts by weight based on 100 parts by weight of a total amount of the mixed positive electrode active material.
7. The mixed positive electrode active material of claim 5, wherein the conductive carbon comprises a carbon black selected from the group consisting of carbon black, acetylene black, ketjen black, channel black, furnace black, lamp black, and thermal black; a material having a crystalline structure of graphene or graphite; and mixture thereof.
8. The mixed positive electrode active material of claim 1, further comprising at least one lithium-containing metal oxide selected from the group consisting of lithium cobalt oxides, lithium nickel oxides, lithium manganese oxides, lithium cobalt-nickel oxides, lithium cobalt-manganese oxides, lithium manganese-nickel oxides, lithium cobalt-nickel-manganese oxides, and substituted or doped oxides thereof by other element(s).
9. The mixed positive electrode active material of claim 8, wherein the other element is at least one selected from the group consisting of Al, Mg, Ni, Co, Fe, Cr, V, Ti, Cu, B, Ca, Zn, Zr, Nb, Mo, Sr, Sb, W and Bi.
10. The mixed positive electrode active material of claim 8, wherein the lithium-containing metal oxide is comprised by 50 parts by weight or less based on 100 parts by weight of the mixed positive electrode active material.
11. A positive electrode comprising the mixed positive electrode active material according to claim 1.
12. A lithium secondary battery comprising the positive electrode of claim 11.
13. The lithium secondary battery of claim 12, wherein an output in an SOC section of 10 to 40% is 20% or over when compared with an output in an SOC section of 50%.
14. The lithium secondary battery of claim 12, wherein the lithium secondary battery is used in a plug-in hybrid electric vehicle (PHEV).
15. The lithium secondary battery of claim 12, wherein the lithium secondary battery is used in an electric vehicle (EV).