1. A rotational driving apparatus comprising:
a stepping motor supported by a housing;
an output shaft rotationally supported by the housing and driven by the stepping motor;
a rotational position detecting sensor for outputting a detected voltage in response to a rotational position of the output shaft; and
a position detecting means for detecting the rotational position of the output shaft in accordance with the detected voltage from the rotational position detecting sensor,
wherein the position detecting means comprises;
a means for determining that the output shaft is in a good operational order
when a first detected voltage of the output shaft at its first detection position (Step=0) and a second detected voltage of the output shaft at its second detection position (Step=n), to which the output shaft has been rotated by the stepping motor by a predetermined number of control pulses, are respectively within a predetermined error range; and
when a deferential voltage between the first and second detected voltages corresponding to the predetermined number of control pulses between the first and second detection positions is within a certain deferential voltage span.
2. A rotational driving apparatus according to claim 1,
wherein the certain deferential voltage span means a span from a first deferential voltage to a second deferential voltage, wherein the first deferential voltage is a deferential voltage between the maximum value of a second error range at the first detection position (step: 0) and the minimum value of the second error range (E2) at the second detection position (step:n), whereas the second deferential voltage is a deferential voltage between the minimum value of the second error range at the first detection position (step: 0) and the maximum value of the second error range at the second detection position (step:n).
3. A rotational driving apparatus according to claim 2,
wherein the error ranges are error ranges covering errors possibly included the detected voltages, and the second error range is narrower than the first error range.
4. A rotational driving apparatus according to one of claims 1 to 3,
wherein the first detection position is a reference position of the output shaft and the second detection position is a position which is a maximum position to which the output shaft can be rotated.
5. A rotational driving apparatus according to claim 1, further comprising:
a position initializing means for rotating the output shaft in a reverse direction until the output shaft impinges against a stopper and then rotating the same in a forward direction by a predetermined number of steps,
wherein the determining means detects, as the first detected voltage, the output voltage from the rotational position detecting sensor at an initial position of the output shaft before it will be rotated by the position initializing means,
the determining means further detects, as the second detected voltage, the output voltage from the rotational position detecting sensor at a position of the output shaft which has been rotated by the predetermined number of control pulses by the position initializing means, and
the determining means determines whether the output shaft is positioned at its reference position by determining the deferential voltage between the first and second detected voltages is within the certain deferential voltage span as a third error range.
6. A rotational driving apparatus according to claim 5, further comprises a return initializing means for rotating the output shaft in the reverse direction until the output shaft impinges against the stopper and then rotating the same in the forward direction until the output shaft comes to the reference position, when the determining means determines that the output shaft is not positioned at its reference position after the operation of the position initialing means.
7. A rotational driving apparatus according to claim 6, wherein the return initializing means calculates
a number of steps representing the present position of the output shaft, and
a necessary number of stepping pulses for rotating the output shaft in the reverse direction from the present position to such a position where the output shaft impinges against the stopper means,
based on the detected voltage from rotational position detecting sensor and a predetermined formula between a number of steps and a minimum value of the error range for the detected voltages.
8. A rotational driving apparatus according to claim 7, wherein
the return initializing means calculates a necessary number of stepping pulses for rotating the output shaft in the reverse direction from the present position to such a position where the output shaft becomes within the reference position error range,
the return initializing means drives the output shaft to rotate the same by such number of stepping pulses at a first rotational speed, and then to rotate the output shaft at a second rotational speed slower than the first rotational speed.
9. A rotational driving apparatus according to claim 8, wherein
the return initializing means increases amounts of electric current and electric voltage to be applied to the stepping motor by a predetermined values, when the output shaft will be rotated in the reverse direction at the first rotational speed.
10. A rotational driving apparatus according to claim 1, wherein the output shaft is operatively connected to the stepping motor through a multistage speed reduction gear mechanism.
11. A rotational driving apparatus according to claim 1, further comprising a spring means for urging the output shaft in one rotational direction.
12. A rotational driving apparatus according to claim 1,
wherein the rotational driving apparatus is connected to a steering angle sensor for a steering wheel of a motor vehicle so that a steering control signal is transmitted from the steering angle sensor to the rotational driving apparatus, and
wherein the output shaft of the rotational driving apparatus is operatively connected to headlights of the motor vehicle so that an optical axis of the headlights will be moved in response to a steering angle of the steering wheel.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
What is claimed is:
1. A catalyst component which consists of the orthorhombic phase of a mixed metal oxide of the formula
AaVbNcXdOe
wherein A is at least one element selected from the group consisting of Mo and W, N is at least one element selected from the group consisting of Te and Se, and X is at least one element selected from the group consisting of Nb, Ta, Ti, Al, Zr, Cr, Mn, Fe, Ru, Co, Rh, Ni, Pt, Bi, B, In, Ce As, Ge, Sn, Li, Na, K, Rb, Cs, Fr, Be, Mg, Ca, Sr, Ba, Ra, Hf, Pb, P, Pm, Eu, Gd, Dy, Ho, Er, Tm, Yb, Lu, Au, Ag, Re, Pr, Zn, Ga, Pd, Ir, Nd, Y, Sm, Tb, Br, Cu, Sc, Cl, F and I,
wherein, when a1, b0.01 to 1, c0.01 to 1, d0.01 to 1 and e is dependent on the oxidation state of the other elements.
2. A process for preparing an orthorhombic phase mixed metal oxide catalyst, said process comprising:
(a) admixing compounds of elements A, V, N and X and at least one solvent to form a solution,
wherein A is at least one element selected from the group consisting of Mo and W, N is at least one element selected from the group consisting of Te, Se and Sb, and X is at least one element selected from the group consisting of Nb, Ta, Ti, Al, Zr, Cr, Mn, Fe, Ru, Co, Rh, Ni, Pt, Bi, B, In, Ce, As, Ge, Sn, Li, Na, K, Rb, Cs, Fr, Be, Mg, Ca, Sr, Ba, Ra, Hf, Pb, P, Pm, Eu, Gd, Dy, Ho, Er, Tm, Yb, Lu, Au, Ag, Re, Pr, Zn, Ga, Pd, Ir, Nd, Y, Sm, Tb, Br, Cu, Sc, Cl, F and I,
wherein A, V, N and X are present in such amounts that the atomic ratio of A:V:N:X is a:b:c:d, and
wherein, when a1, b0.01 to 1, c0.01 to 1 and d0.01 to 1;
(b) admixing a seeding effective amount of an orthorhombic phase mixed metal oxide seed, substantially free of hexagonal phase mixed metal oxide, with said solution to form a seeded solution,
(c) removing said at least one solvent from said seeded solution to form a catalyst precursor; and
(d) calcining said catalyst precursor to obtain said orthorhombic phase mixed metal oxide catalyst.
3. The process for preparing an orthorhombic phase mixed metal oxide catalyst according to claim 2, wherein N is at least one element selected from the group consisting of Te and Se.
4. The process for preparing an orthorhombic phase mixed metal oxide catalyst according to claim 2, wherein said orthorhombic phase mixed metal oxide seed, substantially free of hexagonal phase mixed metal oxide, is prepared by the process comprising:
(i) providing a mixed metal oxide having the empirical formula
AaVbNcXdOe
wherein A is at least one element selected from the group consisting of Mo and W, N is at least one element selected from the group consisting of Te, Se and Sb, and X is at least one element selected from the group consisting of Nb, Ta, Ti, Al, Zr, Cr, Mn, Fe, Ru, Co, Rh, Ni, Pt, Bi, B, In, Ce, As, Ge, Sn, Li, Na, K, Rb, Cs, Fr, Be, Mg, Ca, Sr, Ba, Ra, Hf, Pb, P, Pm, Eu, Gd, Dy, Ho, Er, Tm, Yb, Lu, Au, Ag, Re, Pr, Zn, Ga, Pd, Ir, Nd, Y, Sm, Tb, Br, Cu, Sc, Cl, F and I, and
wherein, when a1, b0.01 to 1, c0.01 to 1, d0.01 to 1 and e is dependent on the oxidation state of the other elements;
(ii) contacting said mixed metal oxide with a liquid contact member selected from the group consisting of organic acids, alcohols, inorganic acids and hydrogen peroxide to form a contact mixture; and
(iii) recovering insoluble material from said contact mixture to obtain said orthorhombic phase mixed metal oxide seed substantially free of hexagonal phase mixed metal oxide.
5. The process for preparing an orthorhombic phase mixed metal oxide catalyst according to claim 4, wherein said liquid contact member is an aqueous solution of oxalic acid.
6. The process for preparing an orthorhombic phase mixed metal oxide catalyst according to claim 2, wherein said orthorhombic phase mixed metal oxide seed, substantially free of hexagonal phase mixed metal oxide, is prepared by the process comprising:
(a) admixing compounds of elements A, V, N and X and at least one solvent to form a first mixture,
wherein A is at least one element selected from the group consisting of Mo and W, N is at least one element selected from the group consisting of Te, Se and Sb, and X is at least one element selected from the group consisting of Nb, Ta, Ti, Al, Zr, Cr, Mn, Fe, Ru, Co, Rh, Ni, Pt, Bi, B, In, Ce, As, Ge, Sn, Li, Na, K, Rb, Cs, Fr, Be, Mg, Ca, Sr, Ba, Ra, Hf, Pb, P, Pm, Eu, Gd, Dy, Ho, Er, Tm, Yb, Lu, Au, Ag, Re, Pr, Zn, Ga, Pd, Ir, Nd, Y, Sm, Tb, Br, Cu, Sc, Cl, F and I,
wherein A, V, M and X are present in such amounts that the atomic ratio of A:V:M:X is a:b:c:d, and
wherein, when a1, b0.01 to 1, c0.01 to 1 and d0.01 to 1;
(b) removing said at least one solvent from said first mixture to form a first precursor;
(c) calcining said first precursor to form a first calcined precursor;
(d) contacting said first calcined precursor with a liquid contact member selected from the group consisting of organic acids, alcohols, inorganic acids and hydrogen peroxide to form a contact mixture; and
(e) recovering insoluble material from said contact mixture to obtain said orthorhombic phase mixed metal oxide seed, substantially free of hexagonal phase mixed metal oxide.
7. The process for preparing an orthorhombic phase mixed metal oxide catalyst according to claim 6, wherein said liquid contact member is an aqueous solution of oxalic acid.
8. A process for producing an unsaturated carboxylic acid which comprises subjecting an alkane, or a mixture of an alkane and an alkene, to a vapor phase catalytic oxidation reaction in the presence of an orthorhombic phase mixed metal oxide catalyst, produced by the process of claim 2.
9. A process for producing an unsaturated nitrile which comprises subjecting an alkane, or a mixture of an alkane and an alkene, and ammonia to a vapor phase catalytic oxidation reaction in the presence of an orthorhombic phase mixed metal oxide catalyst, produced by the process of claim 3.