We claim:
1. A gas sensor comprising an oxygen ion-conducting solid electrolyte, having a measurement gas side and a reference gas side, the solid electrolyte separating a measurement gas space from a reference gas space, at least one measurement electrode arranged on the measurement gas side of the solid electrolyte, at least one reference electrode arranged on the reference gas side of the solid electrolyte, and a support which is gas-permeable at least in a region of the electrodes, wherein the oxygen ion-conducting solid electrolyte and the electrodes are constructed as thin layers and are arranged on the gas-permeable support.
2. The gas sensor according to claim 1, wherein the gas-permeable support is made of a material selected from the group consisting of ceramic, glass and metal.
3. The gas sensor according to claim 1, wherein the gas-permeable support comprises an open pored material.
4. The gas sensor according to claim 3, wherein the open-pored support material has pores with a diameter in a range of 0.1 m to 10 m.
5. The gas sensor according to claim 1, wherein the gas-permeable support comprises a gas-tight material provided with gas passage openings at least in an area of the electrodes.
6. The gas sensor according to claim 5, wherein the gas passage openings comprise bore holes.
7. The gas sensor according to claim 5, wherein the gas passage openings are formed by a laser.
8. The gas sensor according to claim 5, wherein the gas passage openings have a diameter in a range of 10 m to 1000 m.
9. The gas sensor according to claim 1, wherein the gas-permeable support comprises aluminum oxide.
10. The gas sensor according to claim 1, wherein the gas-permeable support is electrically conducting and is constructed as a measurement or reference electrode of the gas sensor.
11. The gas sensor according to claim 1, wherein the thin layers are formed in a thin andor thick layer technology.
12. The gas sensor according to claim 11, wherein the thin layers are made at least in part by a process selected from the group consisting of screen printing, vapor deposition, sputtering, and plasma spraying.
13. The gas sensor according to claim 1, wherein the thin layer of oxygen ion-conducting solid electrolyte has a mean layer thickness in a range of 10 m to 100 m.
14. The gas sensor according to claim 1, wherein the oxygen ion-conducting solid electrolyte comprises doped ZrO2 or CeO2.
15. A process for manufacturing a gas sensor with an oxygen ion-conducting solid electrolyte, having a measurement gas side and a reference gas side, where the solid electrolyte separates a measurement gas space from a reference gas space, at least one measurement electrode arranged on the measuring gas side of the solid electrolyte and at least one reference electrode arranged on the reference gas side of the solid electrolyte, and a support which is gas-permeable at least in an area of the electrodes, comprising the step of applying the oxygen ion-conducting solid electrolyte and the electrodes as thin layers on the gas-permeable support.
16. The process according to claim 15, wherein the thin layers are applied by a thin andor thick layer technique on the gas-permeable support.
17. The process according to claim 16, wherein the thin layers are applied by a process selected from the group consisting of screen printing, vapor deposition, sputtering, and plasma spraying.
18. The process according to claim 15, wherein the gas-permeable support is made of a material selected from the group consisting of ceramic, glass and metal.
19. The process according to claim 15, wherein the gas-permeable support is constructed with an open porosity.
20. The process according to claim 19, wherein the open porosity is constructed with pores having a diameter in a range of 0.1 m to 10 m.
21. The process according to claim 15, wherein the gas-permeable support is made of a gas-tight material provided with gas passage openings at least in an area of the electrodes.
22. The process according to claim 21, wherein the gas passage openings are produced by drilling.
23. The process according to claim 21, wherein the gas passage openings are produced by a laser.
24. The process according to claim 21, wherein the gas passage openings are produced with a diameter in a range of 10 m to 1000 m.
25. The process according to claim 15, wherein the gas-permeable support is made of aluminum oxide.
26. The process according to claim 15, wherein the gas-permeable support is constructed electrically conducting and is used as a measurement or reference electrode of the gas sensor.
27. The process according to claim 15, wherein the thin layer is made of oxygen ion-conducting solid electrolyte having a mean layer thickness in a range of 10 m to 100 m.
28. The process according to claim 15, wherein the oxygen ion-conducting solid electrolyte is made of doped ZrO2 or CeO2.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
1. A catalyst according to the formula a(La2O3).x(TiO2). y(ZnO).z(MMS), wherein a and x are each 1; y is 1-2, z is 3-4, and wherein MMS is a modified molecular sieve obtained from the type 3 \u212b, 4 \u212b, or 5 \u212b zeolite, having the general formula KnNa(12\u2212n)(AlO2)12(SiO2)12.x1H2O, Na12(AlO2)12(SiO2)12.x1H2O, or CanNa(12\u2212n)(AlO2)12(SiO2)12. x1H2O, respectively, wherein x1 has a value between 0 to 5 inclusive and n has a value between 1 to 12 inclusive, modified by replacement of at least one sodium ion within an unmodified molecular sieve with at least one metal cation, wherein the MMS has the general formula KnNa(12\u2212n)(AlO2)12(SiO2)12.x2H2O, KmCanNa{12\u2212(m+2n)}(AlO2)12(SiO2)12.x2H2O, CsnNa(12\u2212n)(AlO2)12(SiO2)12.x2H2O, or CsmCanNa{12\u2212(m+2n)}(AlO2)12(SiO2)12.x2H2O, wherein x2 has a value between 0 to 5 inclusive, and m and n independently have a value between 1 to 12 inclusive.
2. A catalyst according to the formula (Al2O3). (TiO2).(ZnO).z(MMS) wherein z is 10 and wherein MMS is a modified molecular sieve obtained from the type 3 \u212b,4 \u212b, or 5 \u212b zeolite, having the general formula KnNa(12\u2212n)(AlO2)12(SiO2)12.x1H2O, Na12(AlO2)12(SiO2)12.x1H2O, or CanNa(12\u2212n)(AlO2)12(SiO2)12.x1H2O, respectively, wherein x1 has a value between 0 to 5 inclusive and n has a value between 1 to 12 inclusive, modified by replacement of at least one sodium ion within an unmodified molecular sieve with at least one metal cation, wherein the MMS has the general formula KnNa(12\u2212n)(AlO2)12(SiO2)12.x2H2O, KmCanNa{12\u2212(m+2n)}(AlO2)12(SiO2)12.x2H2O, CsnNa(12\u2212n)(AlO2)12(SiO2)12.x2H2O, or CsmCanNa{12\u2212(m+2n)}(AlO2)12(SiO2)12.x2H2O, wherein x2 has a value between 0 to 5 inclusive, and m and n independently have a value between 1 to 12 inclusive.
3. A catalyst according to the formula p(Al2O3).q(TiO2).r(ZnO).z(MMS) wherein p, q and r independently have a value between 1 to 3 inclusive and z has a value of 1, 3-4, or 10, and wherein MMS is a modified molecular sieve obtained from the type 3 \u212b, 4 \u212b, or 5 \u212b zeolite, having the general formula KnNa(12\u2212n)(AlO2)12(SiO2)12.x1H2O, Na12(AlO2)12, x1H2O, or CanNa(12\u2212n)(AlO2)12(SiO2)12. x1H2O, respectively, wherein xl has a value between 0 to 5 inclusive and n has a value between 1 to 12 inclusive, modified by replacement of at least one sodium ion within an unmodified molecular sieve with at least one metal cation, wherein the MMS has the general formula KnNa(12\u2212n)(AlO2)f(SiO2)g.x2H2O, KmCaNNa{12\u2212(m+2n)}(AlO2)f(SiO2)g.x2H2O, CsnNa(12\u2212n)(AlO2)f(SiO2)g.x2H2O, or CsmCanNa{12\u2212(m+2n)}(AlO2)f(SiO2)g.x2H2O, wherein x2 has a value between 0 to 5 inclusive, m and n independently have a value between 1 to 12 inclusive, and f and g independently have a value between 1 to 12 inclusive.