1. A deposition method comprising:
applying a chemical bath to a surface of a substrate, the chemical bath including a metal precursor selected from the group consisting of a hafnium compound, an aluminium compound, a titanium compound, zirconium compound, a scandium compound, a yttrium compound and a lanthanide compound;
rinsing the surface;
applying a co-reactant bath to the surface of the substrate; and
rinsing the surface.
2. The method of claim 1, wherein applying the chemical bath and applying the co-reactant bath is for a time duration until a metal oxide layer is deposited on the surface of the substrate, the metal oxide layer having a work function of at least about 21 eV.
3. The method of claim 1, wherein the metal precursor includes at least one of Al2Me6, (C4H9)C5H42HfCl2, (C5H5)Hf(CH3)2, (C5H5)HfCl2, (C5H4)(C2H5)2HfCl2, HfCl4, HfOC(CH3)34, HfBr4, Hf4O(OC2H5)14.2C2H5OH, Hfl4, HfO2, (CH3)5C5HfCl3, HfMe4, Hf(NEt2)4, Cp2Hf(CO)2, TiCl4, TiMe4, Cp2Ti(CO)2, Cp2TiCl2, Ti(NEt2)4, ZrCl4, ZrMe4, Cp2Zr(CO)2, CP2ZrCl2, Zr(NEt2)4, YCp3, Yb(FOD)3, YCl3, YBr3, Sc(acac)3, ScCp3, Sc(FOD)3, ScCl3, ScBr3, a lanthanide oxide (derived from La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb or Lu), Ln(acac)3, LnCp3, Ln(FOD)3, LnCl3, LnBr3, Ln(acac)3, Ln(thd)3, Ln(CpMe)3, Ln(tBu2amd)3, Ln(thd)4 or Ln(thd)3(phen) compounds.
4. The method of claim 1, wherein the metal precursor is dissolved in an organic solvent.
5. The method of claim 4, wherein the organic solvent includes at least one of toluene, diethyl ether, dichloromethane, chloroform, tetrahydrofuran, acetone, acrylamide, benzene, carbon disulfide, ethylene oxide, n-hexane, hydrogen sulfide, methanol, methyl mercaptan, methyl-N-butyl ketone, perchloroethene, styrene, methyl chloroform, trichloroethene, vinyl chloride, acetonitrile, dimethylformamide, dimethylsulfoxide, mesitylene, hexanes, decane, octane, nonane, diethylether, tetrahydrofuran, or xylene.
6. The method of claim 1, wherein the co-reactant bath includes an oxidizing agent.
7. The method of claim 6, wherein the oxidizing agent is dissolved in either water, or an organic solvent which includes at least one of toluene, diethyl ether, dichloromethane, chloroform, tetrahydrofuran, acetone, acrylamide, benzene, carbon disulfide, ethylene oxide, n-hexane, hydrogen sulfide, methanol, methyl mercaptan, methyl-N-butyl ketone, perchloroethene, styrene, methyl chloroform, trichloroethene, vinyl chloride, acetonitrile, dimethylformamide, dimethylsulfoxide, mesitylene, hexanes, decane, octane, nonane, diethylether, tetrahydrofuran, or xylene.
8. The method of claim 1, wherein the chemical bath is heated to a temperature between about 25\xb0 C. to about 100\xb0 C.
9. The method of claim 8, wherein applying a chemical bath to a surface of a substrate is for a time duration between about 2 seconds to about 3600 seconds.
10. The method of claim 9, wherein applying an oxidizing bath to the surface of the substrate is for a time duration between about 2 seconds to about 3600 seconds.
11. The method of claim 1, wherein applying a chemical bath and applying a co-reactant bath are by immersing the substrate into the chemical bath and the co-reactant bath respectively.
12. A chemical bath comprising:
an organic solvent; and
a metal precursor selected from the group consisting of a hafnium compound, an aluminium compound, a titanium compound, zirconium compound, a scandium compound, a yttrium compound and a lanthanide compound.
13. The chemical bath of claim 12, wherein the metal precursor includes at least one of Al2Me6, (C4H9)C5H42HfCl2, (C5H5)Hf(CH3)2, (C5H5)HfCl2, (C5H4)(C2H5)2HfCl2, HfCl4, HfOC(CH3)34, HfBr4, Hf4O(OC2H5)14.2C2H5OH, Hfl4, HfO2, (CH3)5C5HfCl3, HfMe4, Hf(NEt2)4, Cp2Hf(CO)2, TiCl4, TiMe4, Cp2Ti(CO)2, Cp2TiCl2, Ti(NEt2)4, ZrCl4, ZrMe4, Cp2Zr(CO)2, Cp2ZrCl2, Zr(NEt2)4, YCp3, Yb(FOD)3, YCl3, YBr3, Sc(acac)3, ScCp3, Sc(FOD)3, ScCl3, ScBr3, a lanthanide oxide (derived from La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb or Lu), Ln(acac)3, LnCp3, Ln(FOD)3, LnCl3, LnBr3, Ln(acac)3, Ln(thd)3, Ln(CpMe)3, Ln(tBu2amd)3, Ln(thd)4 or Ln(thd)3(phen) compounds.
14. The chemical bath of claim 12, wherein the organic solvent includes at least one of toluene, diethyl ether, dichloromethane, chloroform, tetrahydrofuran, acetone, acrylamide, benzene, carbon disulfide, ethylene oxide, n-hexane, hydrogen sulfide, methanol, methyl mercaptan, methyl-N-butyl ketone, perchloroethene, styrene, methyl chloroform, trichloroethene, vinyl chloride, acetonitrile, dimethylformamide, dimethylsulfoxide, mesitylene, hexanes, decane, octane, nonane, diethylether, tetrahydrofuran, or xylene.
15. The chemical bath of claim 12, wherein a concentration of the metal precursor in the organic solvent is between about 0.001M to about 0.1M.
The claims below are in addition to those above.
All refrences to claim(s) which appear below refer to the numbering after this setence.
1. A disconnect device for use as part of a tubing string downhole in an oil or gas well and which comprises:
a tubular body,
at least one slip held within the tubular body, and
a sleeve housed within the tubular body to hold the at least one slip in coupling engagement with a coupling component of an upper sub and a coupling component of a lower sub,
in use, the sleeve being selectively moveable relative to the at least one slip to release the at least one slip and thereby release the coupling, wherein the at least one slip includes at least one localized protrusion disposed on an inner diameter of the at least one slip which cooperatively engages with a corresponding localized depression or hole disposed on an outer diameter of at least one of the coupling component of the upper sub and the coupling component of the lower sub whereby tensile load and torque is transmitted by the coupling, that part of the device which is to be released and left downhole by releasing the coupling engagement having a fishneck configuration to enable subsequent retrieval by a fishing tool.
2. A device as claimed in claim 1, wherein the at least one protrusion is substantially convex and the at least one correspondingly shaped depression or hole is concave.
3. A device as claimed in claim 1, wherein the at least one depression or hole is substantially circular.
4. A device as claimed in claim 1, the depression or protrusion being formed by plastic deformation of the material of the coupling component or slip.
5. A device as claimed in claim 1, wherein the device has three or more protrusions and corresponding depressions or holes at circumferentially spaced intervals around the tubular body.
6. A device as claimed in claim 1, wherein the at least one slip has, at a first end thereof, at least one of the localized protrusion or depression to cooperatively engage with the corresponding localized depression or protrusion, respectively, on the upper sub coupling component and has, at a second end thereof, at least one of the localized protrusion or depression to cooperatively engage with the corresponding localized depression or protrusion, respectively, of the lower sub coupling component.
7. A device as claimed in claim 1, wherein the tubular body functions as an intermediate sub between the upper sub and the lower sub.
8. A device as claimed in claim 1, wherein the sleeve housed within the tubular body ensheathes the at least one slip.
9. A device as claimed in claim 7, wherein the sleeve is adapted to be left downhole following release of the connection and has the fishneck configuration formed therein.
10. A releasable connector for connecting a first wellbore tubular and a second wellbore tubular, comprising:
a tubular body;
a slip disposed in the tubular body and having formations for engagement with mating formations on an outside surface of the first and second wellbore tubulars; and
a sleeve disposed in the tubular body and selectively moveable between a first position and a second position, wherein the sleeve in the first position retains the formations of the slip in a coupling engagement with the mating formations thereby connecting the first wellbore tubular and the second wellbore tubular, and wherein the sleeve in the second position releases the coupling engagement, and wherein the coupling engagement transmits tensile load and torque between the first and second wellbore tubulars.
11. The releasable connector of claim 10, wherein the sleeve comprises a fishing neck.
12. The releasable connector of claim 10, wherein one of the tubulars comprises a fishing neck.
13. The releasable connector of claim 10, wherein the formations are protrusions and the mating formations are shaped recesses.
14. The releasable connector of claim 10, wherein the sleeve in the first position is disposed substantially between the slip and the tubular body.
15. A releasable connector for connecting a first tubular and a second tubular, comprising:
a tubular body;
a slip disposed in the tubular body and having formations for engagement with mating formations on an outside surface of the first and second tubulars; and
a sleeve disposed in the tubular body and selectively moveable between a first position and a second position, wherein the sleeve in the first position retains the formations of the slip in a coupling engagement with the mating formations thereby connecting the first tubular and second tubular, wherein the sleeve in the second position releases the coupling engagement, and wherein the sleeve comprises a fishing neck.
16. A releasable connector for connecting a first tubular and a second tubular, comprising:
a tubular body;
a slip disposed in the tubular body and having formations for engagement with mating formations on an outside surface of the first and second tubulars; and
a sleeve disposed in the tubular body and selectively moveable between a first position and a second position, wherein the sleeve in the first position retains the formations of the slip in a coupling engagement with the mating formations thereby connecting the first tubular and second tubular, wherein the sleeve in the second position releases the coupling engagement, and the coupling engagement transmits tensile load and torque between the first and second tubulars.
17. A disconnect device for use as part of a tubing string downhole in an oil or gas well and which comprises:
a tubular body,
at least one slip held within the tubular body, and
a sleeve housed within the tubular body to hold the at least one slip in coupling engagement with a coupling component of an upper sub and a coupling component of a lower sub,
in use, the sleeve being selectively moveable relative to the at least one slip to release the at least one slip and thereby release the coupling, wherein the at least one slip cooperatively engages with at least one of the coupling component of the upper sub and the coupling component of the lower sub using at least one localized protrusion on the at least one slip or on the coupling component extending into a correspondingly shaped local depression or hole in the other of the at least one slip and the coupling component whereby tensile load and torque is transmitted by the coupling, that part of the device which is to be released and left downhole by releasing the coupling engagement having a fishneck configuration to enable subsequent retrieval by a fishing tool, wherein the sleeve housed within the tubular body ensheathes the at least one slip.
18. A releasable connector for connecting a first wellbore tubular and a second wellbore tubular, comprising:
a tubular body;
a slip disposed in the tubular body and having formations for engagement with mating formations on an outside surface of the first and second wellbore tubulars; and
a sleeve comprising a fishing neck disposed in the tubular body and selectively moveable between a first position and a second position, wherein the sleeve in the first position retains the formations of the slip in a coupling engagement with the mating formations thereby connecting the first wellbore tubular and second wellbore tubular, and wherein the sleeve in the second position releases the coupling engagement.
19. A releasable connector for connecting a first wellbore tubular and a second wellbore tubular, comprising:
a tubular body;
a slip disposed in the tubular body and having formations for engagement with mating formations on an outside surface of the first and second wellbore tubulars; and
a sleeve disposed in the tubular body and selectively moveable between a first position and a second position, wherein the sleeve in the first position retains the formations of the slip in a coupling engagement with the mating formations thereby connecting the first wellbore tubular and second wellbore tubular, wherein the sleeve in the second position releases the coupling engagement, and wherein one of the tubulars comprises a fishing neck.